Structure elucidation and synthesis of (2s)-4-oxo-1-azabicyclo[3.3.0]octa-5,7-diehe-2-carboxylic acid,a new metabolite isolated ercm stheptomyces oliyacbjs

The structure of a new metabolite isolated from $\text{Streptomyces}$$\text{olivaceus}$ has been shown to be (2S)-4-oxo-1-azabicyclo[3.3.0]octa-5,7-diene-2-carboxylic acid by means of its spectroscopic properties and total synthesis.     

Striking contrasts in stereoselectivities of spiro-claisen rearrangements of pyranosides versus carbocycles.

Structurally equivalent derivatives of pyranosides and cyclohexanes undergo the spiro-Claisen rearrangement with different stereochemical results. A rationalization for the course observed with the pyranosides is suggested, which invokes interaction of the oxygen lone pair with a (developing) electron deficient centre at the spiro carbon.     

Magnetic elastic electron scattering from 3Be and 13C

Elastic scattering through 180° from ⁹Be, ¹²C and ¹³C targets has been observed for electrons of 35 to 90 MeV. Magnetic scattering cross sections for ⁹Be and ¹³C have been obtained by subtracting charge scattering as deduced from the scattering from the spin-zero nucleus ¹²C. Theoretical shell model predictions for the magnetic cross sections are derived for (1s)⁴(1p)^A?4 configurations and various coupling schemes. Both harmonic oscillator and Woods-Saxon radial wave functions are used. A comparison of our results with magnetic cross sections calculated in DWBA yields magnetic rms radii $\text{〈r}{}^2\text{〉}{}_{\mathrm{<mtext>M</mtext>}}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 3.2 ± 0.3}\text{fm}$ and $\text{〈r}{}^2\text{〉}{}_{\mathrm{<mtext>M</mtext>}}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 3.3 ± 0.3}\text{fm}$ for ⁹Be and ¹³C. For ¹³C a combined flt to our low-q data and to earlier high-q data, yields $\text{〈r}{}^2\text{〉}{}_{\mathrm{<mtext>M</mtext>}}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 3.4 ± 0.1}\text{fm}$ and a strong preference for intermediate coupling (IC) wave functions. Magnetic dipole scattering from ⁹Be is also close to the IC prediction, as deduced from a fit to our data and earlier high-q data. The fitted value of the octupole moment $\text{Ω = 5±1 μ}{}_{\mathrm{<mtext>N</mtext><mtext>fm</mtext>}}{}^1$ can only be explained by a deformation of the average nuclear potential. The radial size $\text{〈r}{}^2\text{〉}{}_{\mathrm{<mtext>1</mtext><mtext>p</mtext>}}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 2.85 ± 0.05}\text{fm}$ for the 1p radial wave function is in agreement with both the ⁹Be and ¹³C data.     

二次型复折射率介质中的光导现象

本文讨论了n(z,r)=n_0(z)+n_2(z)r~2/r_e~2型复折射率介质中的激光传输问题,给出了激光传输参数(光束半径和波阵面曲率)的演化公式。指出只要存在一定大小的n_(21),在传输过一段特征距离z_c之后,将出现完全光导(即自相似模的传播),而且自相似模是激光体系的特征模式。其传输参数只与n_2有关,而与激光初始参数无关。自相似模必定是高斯球面波,而不是高斯平面波。     

Systematic studies on α-decay half-lives for super heavy nuclei

Radioactive decay of super heavy nuclei via the emission of α-particles has been studied theoretically in the preformed cluster model （PCM）. The nucleus-nucleus （NN） potential is obtained by double folding the density distributions of the α-particle and the daughter nucleus with a realistic effective interaction. The M3Y effective interaction, supplemented by a zero-range pseudo-potential for exchange term, is used to calculate the NN potential. The α decay half-lives for 317 nuclei at Z=102 120 are performed in the PCM framework with the theoretical Q values extracted from the MSller-Nix-Kratz and Liran-Marinov-Zeldes mass tables and are compared with the experimental data. The calculated results are also compared with those obtained by using Q values from the Muntian-Hofmann-Patyk-Sobiczewski and Myers-Swiatecki mass estimates.     

合肥光源直流流强检测器系统的磁屏蔽

分析和测试了合肥光源杂散场对直流流强检测器系统的影响。给出了合肥光源ＤＣＣＴ系统的磁屏蔽的计算、设计和测量结果。屏蔽后,由杂散场引起的ＤＣＣＴ零漂由１ｍＡ降至１０μＡ以下。     

用薄层处理法模拟有源共焦非稳

 采用FFT方法和增益介质近腔镜簿层处理法研究了非稳腔下具有非均匀流动介质的高功率气体激光器的光束特性和光束质量,证实了该方法在小扰动、低放大率、低增益器件的腔型中是适用的。     

环形孔径高斯光束的远场特性

 讨论了环形孔径高斯光束的远场光斑能量分布,并给出了拟合表达式。首先推导了光束没有抖动时远场光斑的光能分布表达式,然后研究了各种不同中心遮拦和不同光束截断比, 在有以及没有激光束抖动的情况下,对高斯光束的远场环围能量的分布变化的影响。     

膜催化研究IV: 钯-氧化铝/陶瓷复合膜

本文在无机氧化铝膜的基础上掺入钯, 用sol-gel法制得钯-氧化铝/陶瓷复合膜, 将该膜用于乙醇脱氢制乙醛反应, 分别考察了反应温度、乙醇进样量以及内管惰性气体吹扫气流对乙醛产率的影响, 并在相同条件下比较了常规反应器及单纯氧化铝膜反应器的结果。实验数据表明, 氧化铝膜中掺入钯后可显著提高乙醛产率。本文测定了该复合膜的H2/Ar分离系数、孔径分布, 并利用电子显微镜、X射线衍射等手段对其进行了表征。     

激光差拍波等离子体加速装置中约束磁场的计算研究

通过对等离子体发生器建立三维模型,计算得到磁场在该装置中的分布情况。所得结果与实际测量基本一致,从而说明所建模型的合理性。通过调节一些参数,对该模型进一步搞清了导致等离子体发生器中真实磁场较实验设计要求偏低的主要原因,并提出了相应的改进方案。