脉冲热能沉积薄板中热弹性弯曲运动的分析

研究脉冲热能沉积薄板中,由于板厚方向的温度梯度和空间径向温度Gauss分布状态,所产生的辐射热能引起的弯曲运动效应。文章从非耦合的经典的Bernoulli—Euler理论出发,得到热弯曲动力学方程,求解初值问题,利用Laplace变换和Hankel变换,针对短脉冲和连续热辐射进行了分析,并给出热弹性弯曲波的数值计算结果。与文献[8]的实验结果比较,二者是相符的。     

氧碘化学激光器的红光发射体CuCl2

通过测量、分析CuCl_2的激光诱导荧光并与氧碘化学激光器光腔中红光辐射的傅里叶变换光谱比较,认为红光辐射体是CuCl_2。     

信号照相数字化系统在曙光—Ⅰ的诊断应用

介绍一种信号照相数字化系统及其在曙光-Ⅰ的自由电子激光试验中的诊断应用。主要由微通道板示波器、数字化相机和计算机构成的信号照相数字化系统,是一种新发展的、高性能价格比的多路单次瞬变信号的采集与处理系统。     

转镜式高速相机在爆炸实验中的某些应用

本文介绍了转镜式高速相机在爆炸实验中的应用情况。阐明了这些相机使用时配备的各种主要附加装置,并举例说明了所得到的实验结果。     

Dissipative processes at forward angles in the28Si+natSi Reaction at 12.4 MeV/Nucleon

High resolution positron spectroscopy in U-U collisions at bombarding energies of 5.6 MeV/u, the lowest energy studied until now as well as of 5.9 MeV/u, reveals similar multiple structures between 220 keV and 385 keV superimposed on the induced and nuclear continua.     

电磁脉冲作用人体的数值模拟和分析

 建立色散介质3维真实人体模型，用色散介质时域有限差分（（FD）2TD）方法计算了强电磁脉冲（EMP）对人体的作用。结果表明，电磁脉冲对人体的透入主要决定于脉冲前沿，受脉冲宽度的影响较小；透入体内的脉冲，相对辐照脉冲显著变窄；人体吸收的电磁能没有明显受到辐照脉冲能注量的影响；虽然人体从单个脉冲吸收的能量远低于用比吸收能定义的安全标准，但这种剂量的照射在离体培养的人肝细胞（L-02）上却产生了明显的生物学效应，这意味着比吸收能难以作为人员安全评估标准。     

泵浦靶辐射X射线特性研究

为探索和研究新的X光激光泵浦机制,我们研究了泵浦靶辐射X射线特性。先后在“星光”和“神光”激光装置上开展了该项工作。主要介绍“神光”装置上的实验工作。实验所用泵浦靶材料为Na/F和Cu。实验给出了Na/F和Cu靶辐射X射线谱(波长范围分别为1.1～1.5nm,1.1～1.3nm);给出了X射线相对强度随激光功率密度及靶厚度的变化情况。并比较了靶前、后X射线相对强度。同时,实验还给出了线状泵浦源辐射X射线的空间分布。     

离子交换纤维对亚硫酸法糖汁脱色性能研究

研究了强碱性阴离子交换纤维对亚硫酸法清净糖汁的脱色性能.对沉清工段清汁的脱色效果和影响因素进行了研究.结果表明,阴离子交换纤维对沉清汁的脱色效果明显,脱色后清汁色值低于30 oSt.再生液洗脱再生反复使用90次后,脱色效果达84%.与717强碱性苯乙烯系阴离子交换树脂相比具有脱色容量高、脱色速度快、再生速度快和抗污染能力强等优点.通过离子交换纤维的脱色处理,亚硫酸法清净糖汁可以达到制备优质糖的要求.     

The synthesis, structure and reactivity of aldehyde substituted η-allylic complexes of molybdenum

Reaction of cis-[Mo(NCMe)₂(CO)₂(η⁵-L)][BF₄] (L=C₅H₅ or C₅Me₅) with 1-acetoxybuta-1,3-diene gives the cationic complexes [Mo{η⁴-syn-s-cis-CH₂CHCHCH(OAc)}(CO)₂(η⁵-L)][BF₄], which, on reaction with aqueous NaHCO₃/CH₂Cl₂, afford good yields of the anti-aldehyde substituted complexes [Mo{η³-exo-anti-CH₂CHCH(CHO)}(CO)₂(η⁵-L)] 2 (L=C₅Me₅), 4 (L=C₅H₅)]. The corresponding η⁵-indenyl substituted complex 5 was prepared by protonation (HBF₄·OEt₂) of [Mo(η³-C₃H₅)(CO)₂(η⁵-C₉H₇)] followed by addition of CH₂=CHCH=CH(OAc) and hydrolysis (aq. NaHCO₃/CH₂Cl₂). An X-ray crystallographic study of complex 2 confirmed the structure and showed that there is a contribution from a zwitterionic form involving donation of electron density from the molybdenum to the aldehyde carbonyl group. Treatment of 2 and 4, in methanol solution, with NaBH₄ afforded the alcohols [Mo{η³-exo-anti-CH₂CHCHCH₂(OH)}(CO)₂(η⁵-L)] [6 (L=C₅H₅), 8 (L=C₅Me₅)]; however, prolonged (30 h) reaction with NaBH₄/MeOH surprisingly gave good yields of the methoxy-substituted complexes [Mo{η³-exo-anti-CH₂CHCHCH₂(OMe)}(CO)₂(η⁵-L)] [7 (L=C₅H₅), 9 (L=C₅Me₅)], the structure of 7 being confirmed by single crystal X-ray crystallography. This methoxylation reaction can be explained by coordination of the hydroxyl group present in 6 and 8 onto B₂H₆ to form the potential leaving group HOBH₃⁻, which on ionisation affords [Mo(η⁴-exo-buta-1-3-diene)(CO)₂(η⁵-L)]⁺ which is captured by reaction with OMe⁻. Complex 8 is also formed in good yield on reaction of 2 with HBF₄·OEt₂ followed by treatment of the resulting cation [Mo{η⁴-exo-s-cis-syn-CH₂CHCHCH(OH)}(CO)₂(η⁵-C₅Me₅)][BF₄] with Na[BH₃CN]. Reaction of 4 with the Grignard reagents MeMgI, EtMgBr or PhMgCl afforded moderate yields of the alcohols [Mo{η³-exo-anti-CH₂CHCHCH(OH)R}(CO)₂(η⁵-C₅H₅)] [11 (R=Me), 12 (R=Et), 13 (R=Ph)]. Similarly, treatment of 2 with MeLi gave the corresponding alcohol 14. An attempt to carry out the Oppenauer oxidation [Al(OPr′)₃/Me₂CO] of 11 resulted in an elimination reaction and the formation of the η³-s-pentadienyl complex [Mo{η³-exo-anti-CH₂CHCH(CHCH₂)}(CO)₂(η⁵-C₅H₅)], which was structurally identified by X-ray crystallography. Interestingly, oxidation of 6 with [Bu₄ⁿN][RuO₄]/morpholine-N-oxide affords the aldehyde complex, 4 in good yield. Finally, reaction of 11 with [NO][BF₄] followed by addition of Na₂CO₃ affords the fur-3-ene complex [Mo{η²-

(H)Me}(CO)(NO)(η⁵-C₅H₅)].     

An efficient route to unsymmetrical bis(azolium) salts: CCC-NHC pincer ligand complex precursors

The coupling of N-heterocyclic azoles (imidazoles, benzimidazoles, triazoles) to bromobenzenes (1,2-; 1,3-; or 1,4) in a step-wise, sequential manner was accomplished by manipulation of reaction time and stoichiometry, which provided straight-forward access to unsymmetrical bis(azolium) salts in only three isolation steps from commercially-available starting materials. Eight mono(azole) substituted bromobenzenes, four mono(azolium)bromobenzene salts, twelve unsymmetrical bis(azole)benzenes, and fourteen unsymmetrical bis(azolium) salts, which are precursors for pincer ligand complexes, are reported.