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91.
Pavlova SV To HL Chan ES Li HW Mak TC Lee HK Chan SI 《Dalton transactions (Cambridge, England : 2003)》2006,(18):2232-2243
The air-sensitive bis(micro-iodo)dicopper(I) complex 1 supported by [N-(3,5-di-tert-butyl-2-hydroxybenzyl)-N,N-di-(2-pyridylmethyl)]amine (L) has been prepared by treating copper(I) iodide with L in anhydrous THF. Compound 1 crystallizes as a dimer in space group C2/c. Each copper(I) center has distorted tetrahedral N2I2 coordination geometry with Cu-N(pyridyl) distances 2.061(3) and 2.063(3) A, Cu-I distances 2.6162(5) and 2.7817(5) and a Cu...Cu distance of 2.9086(8) A. Complex 1 is rapidly oxidized by dioxygen in CH2Cl2 with a 1 : 1 stoichiometry giving the bis(micro-iodo)peroxodicopper(II) complex [Cu(L)(micro-I)]2O2 (2). The reaction of 1 with dioxygen has been characterized by UV-vis, mass spectrometry, EPR and Cu K-edge X-ray absorption spectroscopy at low temperature (193 K) and above. The mass spectrometry and low temperature EPR measurements suggested an equilibrium between the bis(micro-iodo)peroxodicopper(II) complex 2 and its dimer, namely, the tetranuclear (peroxodicopper(II))2 complex [Cu(L)(micro-I)]4O4 (2'). Complex 2 undergoes an effective oxo-transfer reaction converting PPh3 into O=PPh3 under anaerobic conditions. At sufficiently high concentration of PPh3, the oxygen atom transfer from 2 to PPh3 was followed by the formation of [Cu(PPh3)3I]. The dioxygen reactivity of 1 was compared with that known for other halo(amine)copper(I) dimers. 相似文献
92.
Chen HQ Wang L Liu Y Wu WL Liang AN Zhang XL 《Analytical and bioanalytical chemistry》2006,385(8):1457-1461
A new fluorescence method for the detection of proteins with novel composite nanoparticles (CdS/PPA) has been developed. The
composite nanoparticles have been prepared through an in-situ polymerization method under ultrasonic irradiation. The surface
of the composite nanoparticles was covered with functional groups (-COOH). These groups may play a major role in the improving
the water solubility and biocompatibility of the nanoparticles. The composite particles is combined with proteins in NaAc-HCl
buffer solution (pH=1.99), which can result in strong fluorescence, and the response is linearly proportional to the concentration
of proteins. In λem/λex=650 nm/365 nm place (the stoke’ shift is 285 nm), its fluorescent strength reaches the maximum. Under
the optimum conditions, the linear range is 0.10–20.0 μg·ml−1 with the detection limit of 41 ng·ml−1 for HSA, and 0.10–15.0 μg·ml−1 with the detection limit of 35 ng·ml−1 for Human γ-IgG . The method has been applied to the determination of the total protein in human serum samples collected
from the hospital and the results are satisfactory. 相似文献
93.
94.
Let p be a prime and let b be a positive integer. If a (v, k, λ, n) difference set D of order n = p b exists in an abelian group with cyclic Sylow p-subgroup S, then \({p\in\{2,3\}}\) and |S| = p. Furthermore, either p = 2 and v ≡ λ ≡ 2 (mod 4) or the parameters of D belong to one of four families explicitly determined in our main theorem. 相似文献
95.
对肝脏组织的弹性应力分析在肝纤维化程度的精确定量评价方面是非常关键的,因此从弹性力学角度结合磁共振成像技术的磁共振弹性成像研究在肝脏疾病的早期诊断和治疗方面将具有重要意义和广泛应用. 该文针对弹性磁共振成像技术的理论与技术进行了全面的研究,开发了磁共振弹性图研究平台,主要包括:组织生物力学模型分析与建模,剪切波激励装置的开发,弹性成像序列的设计,弹性拟合算法研究与实现4个方面的工作. 基于上述工作,进行了相关体模和离体猪肝以及志愿者在体肝脏实验,实验结果表明,研究平台基本可以满足肝脏弹性成像研究的需要. 相似文献
96.
In this paper, we study the asymptotics and fast computation of the one-sided oscillatory Hilbert transforms of the form $$\begin{aligned} H^{+}(f(t)e^{i\omega t})(x)=-\!\!\!\!\!\!\int \nolimits _{\!\!\!0}^{\infty }e^{i\omega t}\frac{f(t)}{t-x}\,dt,\quad \omega >0,\quad x\ge 0, \end{aligned}$$ where the bar indicates the Cauchy principal value and $f$ is a real-valued function with analytic continuation in the first quadrant, except possibly a branch point of algebraic type at the origin. When $x=0$ , the integral is interpreted as a Hadamard finite-part integral, provided it is divergent. Asymptotic expansions in inverse powers of $\omega $ are derived for each fixed $x\ge 0$ , which clarify the large $\omega $ behavior of this transform. We then present efficient and affordable approaches for numerical evaluation of such oscillatory transforms. Depending on the position of $x$ , we classify our discussion into three regimes, namely, $x=\mathcal O (1)$ or $x\gg 1$ , $0<x\ll 1$ and $x=0$ . Numerical experiments show that the convergence of the proposed methods greatly improve when the frequency $\omega $ increases. Some extensions to oscillatory Hilbert transforms with Bessel oscillators are briefly discussed as well. 相似文献
97.
Analysis of a bi-piezoelectric ceramic layer with an interfacial crack subjected to anti-plane shear and in-plane electric loading 总被引:1,自引:0,他引:1
The behaviour of a bi-piezoelectric ceramic layer with a centre interfacial crack subjected to anti-plane shear and in-plane electric loading has been studied. The dislocation density functions and the Fourier integral transform method have been employed to eliminate the problem of singular integral equations. The normalized energy release rate, stress and electrical displacement intensity factors, G/G0,KIII/KIII0 and KD/KD0, respectively, were determined for different geometric and property parameters by use of two different crack surface electric boundary conditions, i.e. impermeable and permeable. It has been shown that the effects of the thickness and material constants of the piezoelectric layer on all the three parameters, i.e. G/G0,KIII/KIII0 and KD/KD0 were significant. 相似文献
98.
不确定性是复杂工程系统的内在属性,在决策依赖不确定条件下对工程系统的投资决策需考虑不确定性与决策过程之间的交互作用,使得投资决策问题的求解非常困难.提出了决策依赖不确定条件下复合实物期权估值的最小二乘模拟算法,方法较好地解决了在决策依赖不确定条件下由于不同期权价值相互耦合所带来的计算复杂性,进一步拓展了最小二乘模拟算法在期权估值中的应用,基于该方法,可以比较方便地解决决策依赖不确定条件下工程系统投资决策问题. 相似文献
99.
The pressure-induced phase transitions of PbCO3 are studied using synchrotron radiation in a diamond anvil cell at room temperature. The XRD measurement indicates that PbCO3 with an initial phase of aragonite-type structure undergoes two phase transitions at ~7.8GPa and ~15.7GPa respectively. The higher-pressure phase appearing at ~ 15.7GPa is stable up to 51.8GPa. The two phase transitions are further confirmed by Raman scattering up to 23.3GPa. During the decompression process, the high-pressure phases of PbCO3 are gradually recovered to the starting aragonite-type structure, but exhibit some hysteresis. The bulk modulus B0 of the aragonite-type structure is obtained to be 63±(3) GPa by fitting the volume-pressure data to the Birch-Murnaghan equation of states with B0 fixed to 4. 相似文献
100.