Studies on the Synthesis of a Natural Product—Piceatannol and its Analogs

Piceatannol,(E)-3,3′,4,5′-tetrahydroxy stilbene, a natural polyhydroxy stibene, possesses many biological activities, its synthesis has been reported. We designed another route of its synthesis, which can be controlled more easily. The synthetic product was characterized by elemental analysis,IR,MS and ^1H-NMR. Its analogs were synthesized by the similar method.     

Studies on the Synthesis of Pyridine Analogs of the Natural Product3,5,4''''-Trimethoxystilbene

3,5,4'-Trimethoxystilbene is the methoxy precursor of a natural product 3,5,4'-trihydro- xystilbene (resveratrol)1 , which was reported to have many biological activities2. 3,5,4'-trimethoxystilbene itself is also a natural product2. We have synthesized 3,5,4'-trimethoxystilbene. In the screening of its anti-tumor activity using three different human cancer cell lines, 3,5,4'-trimethoxystilbene was found to have an IC50 5.91 mol/L for KB, 5.82 mol/L for A2780, 7.08 mol/L for HCT-8, respe…     

Total Synthesis of the Natural Product-Pinosylvin and its Analog

Polyhydroxy stilbenes were proved to have many biological activitiesl'2. 'We havereported the total synthesis of tWo natural products-resveratrol (3,5,4'-tTihydroxylstilbene) and isorhapontigenin 3'4 which were first found in a traditional Chinese herb,G.Parvghlium by M. Lins et al. Herein,we want to present the total synthesis of anothernatural hydroxyl stilbene, pinosylvin (3,5-dihydroxy stilbene,10) isolated from this plantand its analog (3,5,3',5'-tetfahydroxy stilbene,9 ). In the synth…     

Pseudo almost periodic solutions for the systems of differential equations with piecewise constant argument

In this paper, we investigate the existence and uniqueness of new almost periodic type solutions, so-called pseudo almost periodic solutions for the systems of differential equations with piecewise constant argument by means of introducing the notion of pseudo almost periodic vector sequences.     

Modeling Photovoltaic Performances of BTBPD-PC61BM System via Density Functional Theory Calculations

Designing and fabricating high-performance photovoltaic devices have remained a major challenge in organic solar cell technologies.In this work,the photovoltaic performances of BTBPD-PC₆₁BM system were theoretically investigated by means of density functional theory calculations coupled with the Marcus charge transfer model in order to seek novel photovoltaic systems.Moreover,the hole-transfer properties of BTBPD thin-film were also studied by an amorphous cell with 100 BTBPD molecules.Results revealed that the BTBPDPC₆₁BM system possessed a middle-sized open-circuit voltage of 0.70 V,large short-circuit current density of 16.874 mA/cm²,large fill factor of 0.846,and high power conversion efficiency of 10%.With the Marcus model,the charge-dissociation rate constant was predicted to be as fast as 3.079×10¹³ s^-1 in the BTBPD-PC₆₁BM interface,which was as 3-5 orders of magnitude large as the decay (radiative and non-radiative) rate constant (10⁸-10¹⁰ s^-1),indicating very high charge-dissociation efficiency (～100%) in the BTBPD-PC₆₁BM system.Furthermore,by the molecular dynamics simulation,the hole mobility for BTBPD thin-film was predicted to be as high as 3.970×10^-3 cm²V^-1s^-1,which can be attributed to its tight packing in solid state.     

全捷联激光半主动导引头线性视场研究

针对全捷联半主动导引头大线性视场的要求,分析了四象限光电系统线性视场与目标距离的关系。首先根据系统参数计算不同能见度、不同目标反射率下的目标距离与导引头接收光功率关系;通过建立光学系统的仿真模型,利用光线追迹方法获得不同视场对应的探测器光敏面光斑功率分布;最后结合探测器灵敏度阈值,得到线性视场与接收激光功率的关系:随着目标距离减小,线性视场从0°增大到光学设计理论值。实验测试结果表明,线性视场随着接收功率增大,从0°增大到±9°,与理论分析一致。因此,全捷联半主动激光制导系统设计应该考虑导引头线性视场变化规律。     

FC-空间上的不动点定理和相交定理及其应用

介绍了没有凸结构和线性结构的有限连续拓扑空间(简称为FC-空间);得到了若干个非紧的FC-空间上不动点定理的开[闭]表现形式并建立了FC-空间上的连续选择定理.应用以上结果,在非常弱的假设下得出若干的相交定理和重合点定理,改进和推广了文献中的相应结果.     

类W-KKM(X,Y,Z),几乎不动点定理和不动点定理

引进了相对弱$R$-子集和类($W$-)KKM$(X,Y,Z)$的概念,给出了相对KKM映射与相对弱$R$-子集之间的等价关系以及$W$-KKM$(X,Y,Z)$的一个性质,然后给出了两个连续选择定理并得到不动点定理和重合点定理, 最后,在一致拓扑空间上得到具有弱-KKM性质的映射的几乎不动点,不动点和重合点的存在定理.     

威客电子商务作弊评价模型及算法研究

威客模式是一种新型电子商务模式,有助于知识、智慧、经验、技能体现经济价值,是电子商务应用领域的一个热点.在介绍威客电子商务模式的基础上,重点研究了影响威客电子商务发展的作弊问题,建立了作弊评价模型.利用威客的历史信息和对设计方案相似性的评价,设计了一种基于定量和定性指标的作弊可能性计算算法.根据威客电子商务的特点,探讨了基于任务金额、结合作弊评价结果的威客信用评价体系.以猪八戒威客网站两个作弊争议案例为例进行了实证分析,说明了作弊评价算法的有效性.     

聚醚醚酮／聚醚砜嵌段共聚物的动态力学行为

本文以聚醚醚酮和聚醚砜两种齐聚物为原料合成了聚醚醚酮／聚醚砜嵌段共聚物，用动态力学谱仪对其进行了动态力学性能研究。从无定形共聚物样品对数减量－温度谱图中观察到清晰而完全分离的玻璃化转变内耗峰和非晶态向结晶态转变（α＇转变）内耗峰，确认α＇转变发生在冷结晶初期而后很快减弱。