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Colm Browne Tanya K. Ronson Jonathan R. Nitschke 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(40):10877-10881
The reaction of 2,6‐diformylpyridine with diverse amines and PdII ions gave rise to a variety of metallosupramolecular species, in which the PdII ion is observed to template a tridentate bis(imino)pyridine ligand. These species included a mononuclear complex as well as [2+2] and [3+3] macrocycles. The addition of pyridine‐containing macrocyclic capping ligands allows for topological complexity to arise, thereby enabling the straightforward preparation of structures that include a [2]catenane, a [2]rotaxane, and a doubly threaded [3]rotaxane. 相似文献
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Wilkinson PN Henstock DR Browne IW Polatidis AG Augusto P Readhead AC Pearson TJ Xu W Taylor GB Vermeulen RC 《Physical review letters》2001,86(4):584-587
Using very long baseline interferometry we have searched a sample of 300 compact radio sources for examples of multiple imaging produced by gravitational lensing; no multiple images were found with separations in the angular range 1.5--50 milliarcsec. This null result allows us to place a limit on the cosmological abundance of intergalactic supermassive compact objects in the mass range approximately 10(6)M( middle dot in circle) to approximately 10(8)M( middle dot in circle); such objects cannot make up more than approximately 1% of the closure density ( 95% confidence). A uniformly distributed population of supermassive black holes forming soon after the big bang does not, therefore, contribute significantly to the dark matter content of the Universe. 相似文献
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The synthesis, spectroscopic, electrochemical and photophysical characterization of a series of dinuclear ruthenium(II) complexes of the type [(bpy)2Ru(NnN)2RuCl(bpy)2](PF6)3, where NnN = 4,4′‐bipyridyl (N0N), 1,2‐bis(4‐pyridyl)ethylene (NEN), 1,2‐bis(4‐pyridyl)ethane (N2N), and 4,4′‐trimethylenedipyridine (N3N) are reported. The photophysical and electrochemical properties are discussed with particular emphasis on the ability of the bridging ligands to support intercomponent interaction. 相似文献
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One of the most striking nonclassical features of quantum mechanics is in the correlations it predicts between spatially separated measurements. In local hidden variable theories, correlations are constrained by Bell inequalities, but quantum correlations violate these. However, experimental imperfections lead to loopholes whereby LHV correlations are no longer constrained by Bell inequalities, and violations can be described by LHV theories. For example, loopholes can emerge through selective detection of events. In this Letter, we introduce a clean, operational picture of multiparty Bell tests, and show that there exists a nontrivial form of loophole-free postselection. Surprisingly, the same postselection can enhance quantum correlations, and unlock a connection between nonclassical correlations and nonclassical computation. 相似文献
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D. H. Browne 《Fresenius' Journal of Analytical Chemistry》1890,29(1):591
Ohne Zusammenfassung 相似文献
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