全文获取类型
收费全文 | 15902篇 |
免费 | 2464篇 |
国内免费 | 3425篇 |
专业分类
化学 | 12966篇 |
晶体学 | 387篇 |
力学 | 744篇 |
综合类 | 346篇 |
数学 | 1759篇 |
物理学 | 5589篇 |
出版年
2024年 | 44篇 |
2023年 | 205篇 |
2022年 | 524篇 |
2021年 | 536篇 |
2020年 | 559篇 |
2019年 | 612篇 |
2018年 | 495篇 |
2017年 | 580篇 |
2016年 | 683篇 |
2015年 | 823篇 |
2014年 | 1000篇 |
2013年 | 1261篇 |
2012年 | 1365篇 |
2011年 | 1445篇 |
2010年 | 1187篇 |
2009年 | 1157篇 |
2008年 | 1361篇 |
2007年 | 1118篇 |
2006年 | 1091篇 |
2005年 | 904篇 |
2004年 | 776篇 |
2003年 | 569篇 |
2002年 | 668篇 |
2001年 | 528篇 |
2000年 | 457篇 |
1999年 | 332篇 |
1998年 | 218篇 |
1997年 | 148篇 |
1996年 | 158篇 |
1995年 | 120篇 |
1994年 | 119篇 |
1993年 | 109篇 |
1992年 | 86篇 |
1991年 | 95篇 |
1990年 | 65篇 |
1989年 | 77篇 |
1988年 | 54篇 |
1987年 | 56篇 |
1986年 | 28篇 |
1985年 | 38篇 |
1984年 | 25篇 |
1983年 | 17篇 |
1982年 | 18篇 |
1981年 | 18篇 |
1980年 | 14篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1976年 | 5篇 |
1965年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Free-space quantum key distribution (QKD) has attracted considerable attention due to its lower channel loss and link flexibility. It allows two participants share theoretical unconditional secure keys, and can potentially be applied to air-to-ground quantum communication to establish a global quantum network. Free-space QKD using modulating retro-reflectors (MRR-QKD) significantly reduces the pointing requirement and simplifies the structure of the mobile terminal, therefore making it suitable for lightweight aircraft such as unmanned aerial vehicle and Cubesat, etc. Based on intensity modulation of two non-orthogonal states and the B92 protocol, we proposed a scheme to improve the previous work (Optics Express 2018, 26, 11331). Our scheme simplifies the optical structure and shows more robustness in equipment imperfection. The analysis and simulation show that the number of multiple quantum well modulators needed in our scheme decreases from eight to three with similar performance. Additionally, while the previous scheme cannot work due to low modulator extinction ratio or high optical misalignment, our scheme can still operate. 相似文献
82.
本文采用纯化的海泡石作为硅源,在不需要模板和煅烧工艺的条件下,制备出了石英相的硅纳米管(SNTs),并对获得样品进行了XRD、FTIR和SEM等表征.制得的SNTs具有40~50 nm外径,管腔直径为10~15 nm,长度为20~100 μm.此外,研究了SNTs对于Pb2+的吸附行为.结果表明,Pb2+吸附量随初始Pb2+浓度,吸附时间,温度和溶液pH值(<5)增加而增加.在溶液pH为5时,SNTs对于Pb2+的吸附平衡的吸附焓(ΔH)和熵变(ΔS)分别为6.28 kJ/mol和69.8 J/mol· K. 相似文献
83.
84.
WANG Zhi-Qiang PAN Xun LU Yan-Lei LI Ying-Yu YANG Yu-Ping XIN Xiu-Lan JIN Qiong-Hua 《结构化学》2021,40(5):615-624
Three lanthanide complexes[LnL3(H2O)]PMo12O40·CH3CN(Ln = Dy3+for 1,Ln = Ho3+for 2,Ln= Lu3+for 3,L = tetraethyl ethylenediphosphonate)have been synthesized,and c... 相似文献
85.
Jian Jiao Min Chen Shengxin Sun Weijie Si Xiaobin Wang Weijie Ding Xincan Fu An Wang Chunlong Yang 《中国化学》2021,(2):323-329
To screen novel antifungal agents targeting the succinate dehydrogenase(SDH),a series of pyrazole-4-carbohydrazides were rationally designed,synthesized,and characterized under the guidance of the structures of succinate dehydrogenase inhibitors(SDHIs).Bioassay results in vitro indicated that most of the target compounds exhibited excellent activity against Rhizoctonia solani(R.solani),Fusarium graminearum(F.graminearum),Botrytis cinerea(B.cinerea)and Colletotrichum capsica(C.cinerea).Compounds 7d,7l,7t and 7x were identified as the most promoting candidates,and their anti-F.graminearum EC50 values were as low as 0.56,0.47,0.46 and 0.49μg/mL,respectively,presenting the similar antifungal activity as that of the commonly used fungicide carbendazim(0.43μg/mL).The 3D-QSAR models were built for a systematic structure-activity relationship profile to explore more potent pyrazole-4-carbohydrazides as novel fungicides.Molecular docking of 7d,7l and 7r with SDH was performed to reveal the binding modes in active pocket and analyze the interactions between the molecules and the SDH protein. 相似文献
86.
建立了同时测定头发中10种蛋白同化激素液相色谱-串联质谱(LC/MS/MS)分析方法。头发样品经NaOH消解、戊烷液液提取后,用反相液相色谱分离,电喷雾正离子源进行离子化,用多反应监测方式(MRM)对这10种蛋白同化激素的母离子及子离子进行监测,三重四极杆质谱测定。10种蛋白同化激素的检出限为1~20ng/g;相对标准偏差(RSD)为1.72%~13.77%;回收率为38.20%~110.38%;线性回归系数(R2)为0.9958~0.9999。本方法简便快速、灵敏度高、专属性强,可满足在兴奋剂检测或毒物分析中对毛发中蛋白同化激素测定的要求。 相似文献
87.
采用基于密度泛函理论的第一性原理研究了钪(Sc)、氧空位(OV)单/共掺杂锐钛矿相TiO2,对晶体结构、形成能以及电子结构进行了对比分析.研究结果表明,Sc-TiO2在富氧环境下缺陷形成能为负值,富钛环境下缺陷形成能为正值,表明Sc-TiO2只能在富氧环境下制备;OV-TiO2、Sc-OV-TiO2在富氧或富钛环境下缺陷形成能均为负值,但富氧环境下形成能更低;OV-TiO2的0/1-缺陷电荷转变能级为深能级,而Sc-TiO2的0/1-缺陷电荷转变能级则属于相对较浅能级;与纯锐钛矿相TiO2相比,Sc-TiO2的禁带宽度略有减小,但OV-TiO2、Sc-OV-TiO2禁带宽度变宽. 相似文献
88.
LI Qian-rong PAN Zhen YIN Hao WANG Wei 《高等学校化学研究》2007,23(4):421-425
4β-Azido-4-demethyl-4'-O-demethyl-epipodophyllotoxin reacted with phenyliodonium diacetate in MeOH at room temperature to synthesize a novel podophyllotoxin derivative containing a cyclohexadienone group with the original configurations of C2 and C4,which are required for the antitumor activities.The component and structure of the pro-duct were confirmed using elemental analysis,high-resolution mass spectrum,1H and 13C NMR spectra,and infrared spectrum.Furthermore,the fragmentation routes of the product were fully assigned with electron-impact time-of-flight mass spectrometry(EI-TOF MS),which can also be used for the structural elucidation based on the molecular ion at m/z 455(16%)and three novel characteristic fragment ions at m/z 183(37%),425(7%),and 199(5%).The cyclohexadienone product is sensitive to acidic media.When it is treated with a trace of acid,another novel derivative containing an orthoquinone moiety is formed,which links with the metabolism of the cancer inhibitors. 相似文献
89.
提出了高效耗能黏弹性阻尼器,研究了该阻尼器对框架结构的减震机理。首先给出了高效耗能黏弹性阻尼器的结构构造,推导了小震、大震与巨震作用下的阻尼放大系数计算公式,由此分析了该放大系数的变化规律。此外,还推导了设置高效耗能黏弹性阻尼框架结构的等效阻尼比。分析表明,框架结构设置高效耗能黏弹性阻尼器在阻尼等效前后顶部位移反应时程曲线相差不超过10%。 相似文献
90.