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951.
M. G. Voronkov S. G. D’yachkova I. P. Lebedeva A. V. Evart L. G. Shagun 《Russian Journal of General Chemistry》2007,77(4):604-606
Alkylthiochloroacetylenes react with geminal (in ether) and vicinal (in THF) dithiols to form, respectively, functional 1,3-dithiolenes (yield 43%) or 1,3-dithiolanes (yield 34%). 相似文献
952.
The present report describes a method suitable for the indirect assay of hydroxyl radical (OH.), which is likely to be produced during reperfusion of ischemic myocardium. Isolated rat heart perfused by the Langendorff technique was subjected to 30 min of ischemia, followed by 30 min of reperfusion. Salicylic acid (2 mM) was added to the perfusion circuit to trap any OH. radical generated during the experiment. 2,5- and 2,3-dihydroxybenzoic acids (hydroxylated products of salicylic acid) were identified by authentic standards as well as by pure OH.-generating system using high-performance liquid chromatography with electrochemical detection. In addition to serving as a chemical trap for the detection of OH., salicylate attenuated myocardial reperfusion injury as evidenced by reduced formation of creatine kinase, decreased lipid peroxidation, and improved myocardial contractile functions during reperfusion. These results thus provide direct evidence for the presence of OH. in heart and link it to the myocardial reperfusion injury. 相似文献
953.
954.
955.
In a seminal paper, Martin Clark (Communications Systems and Random Process Theory, Darlington, 1977, pp. 721–734, 1978) showed how the filtered dynamics giving the optimal estimate of a Markov chain observed in Gaussian noise can be expressed
using an ordinary differential equation. These results offer substantial benefits in filtering and in control, often simplifying
the analysis and an in some settings providing numerical benefits, see, for example Malcolm et al. (J. Appl. Math. Stoch.
Anal., 2007, to appear).
Clark’s method uses a gauge transformation and, in effect, solves the Wonham-Zakai equation using variation of constants.
In this article, we consider the optimal control of a partially observed Markov chain. This problem is discussed in Elliott
et al. (Hidden Markov Models Estimation and Control, Applications of Mathematics Series, vol. 29, 1995). The innovation in our results is that the robust dynamics of Clark are used to compute forward in time dynamics for a simplified
adjoint process. A stochastic minimum principle is established. 相似文献
956.
957.
E. S. Zhukova A. S. Prokhorov I. E. Spektor V. A. Karavanskiĭ N. N. Mel’nik T. N. Zavaritskaya B. P. Gorshunov 《Physics of the Solid State》2007,49(12):2242-2250
The dielectric response (conductivity and permittivity) spectra of a series of nanoporous silicon samples prepared by anodization of low-resistivity single-crystal silicon are measured, for the first time, using terahertz and IR spectroscopy in the frequency range 7–4000 cm?1 at room temperature. The spectra obtained are analyzed in terms of the effective medium theory with a size-dependent dielectric response function of nanoinclusions and averaged dielectric characteristics of the surrounding medium. The geometric and dielectric characteristics of silicon nanoinclusions are determined. The dielectric properties of inclusions are found to be affected by nanosize effects, namely, carrier scattering at crystallite boundaries and a broadening of the band gap due to quantum confinement. The spectra of the samples prepared by adding iodine to the electrolyte exhibit a resonance at frequencies of 150–300 cm?1. The nature of the resonance can be associated with the presence of chemisorbed iodine on the surface of porous silicon. Possible mechanisms responsible for the changes in broadband conductivity and permittivity spectra of single-crystal silicon upon transformation into a nanoporous structure are discussed. 相似文献
958.
A model for the interaction of near-infrared laser pulses with metal powders in selective laser sintering 总被引:4,自引:0,他引:4
P. Fischer N. Karapatis V. Romano R. Glardon H.P. Weber 《Applied Physics A: Materials Science & Processing》2002,74(4):467-474
A thermal model of the interaction of pulsed near-infrared laser radiation from a Nd:YAG laser was made, taking the measured
powder properties such as reflectance, optical penetration depth and thermal conductivity into account. It allows an estimation
of the evolution of two different temperatures: the average temperature of the powder (taken over the grains in a volume given
by the laser beam diameter and the optical penetration depth) and the temperature distinction within a single grain. It showed
that in pulsed mode consolidation can be achieved at much lower average power as the surface of the powder particles are molten
but their cores remain at nearly room temperature. This leads to a much lower average temperature and therefore a dramatic
decrease in residual thermal stresses in the finished piece. The results of the model were experimentally tested and confirmed.
Received: 26 July 2001 / Accepted: 23 November 2001 / Published online: 23 January 2002 相似文献
959.
We propose objectives consisting of two mirrors with central holes for passage of a light beam. The optical layout ensures
multiple reflection of rays from both mirrors. We consider several approaches to calculating the design parameters for which
three and four aberrations do not occur. The objectives can be used in optical devices operating in the UV and IR regions
of the spectrum.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 2, pp. 267–270, March–April, 2007. 相似文献
960.
J. M. Criado L. A. Pérez-Maqueda M. J. Diánez P. E. Sánchez-Jiménez 《Journal of Thermal Analysis and Calorimetry》2007,87(1):297-300
The SCTA method implies to control the temperature in such a way that
the reaction rate changes with the time according to a function previously
defined by the user. Constant Rate Thermal Analysis (CRTA) is one of the most
commonly used SCTA methods and implies achieving a temperature profile at
which the reaction rate remains constant all over the process at a value previously
selected by the user. This method permits to minimize the influence of heat
and mass transfer phenomena on the forward reaction. The scope of this work
is to develop a universal CRTA temperature controller that could be adapted
to any thermoanalytical device. The thermoanalytical signal is programmed
to follow a preset linear trend by means of a conventional controller that
at the time controls a second conventional temperature programmer that forces
the temperature to change for achieving the trend programmed for the thermoanalytical
signal. Examples of the performance of this control system with a Thermobalance
and a Thermomechanical Analyser (TMA) are given. 相似文献