Investigation of anode and cathode jets influence on electric arc properties with current up to 500 kA

A number of phenomena connected with the formation of electrode jets in discharges in hydrogen at a current of 10/sup 5/-10/sup 6/ A, a current growth rate of 10/sup 10/ A/s, an initial pressure 0.1-4.0 MPa, and a discharge gap length of 5-40 mm were studied. After the secondary breakdown, the jets are observed through a discharge semitransparent channel, widening with velocity (4-7) /spl middot/ 10/sup 2/ m/s. Shockwave formation was detected at the interaction of jets with the surrounding gas and the opposite electrode. Plasma vapor pressure of metal near the end of the tungsten cathode 70 /spl mu/s after initiation of a discharge was 180 MPa. Thus, magnitude of brightness temperature was 59 /spl middot/ 10/sup 3/ K, with an average charge of ions-m~=3.1, and a concentration of metal vapors n=5.3/spl middot/10/sup 19/ cm/sup -3/. While those at the end of the anode 90 /spl mu/s after initiation of discharge: m~=2.6, n=7.4/spl middot/10/sup 19/ cm/sup -3/. Probable reasons of high-voltage drops near the electrodes (the summarized magnitude of which is /spl sim/1 kV) are discussed on the basis of experimental data. For the first time, the shadow method registered symmetric ejection of material from the all-cathode surface the maximum discharge current was observed.     

Temperature jump induction of isomerization dynamics of alkali halide clusters

The time resolved dynamics of diffusionless cube → ring isomerization of the Na₄Cl₄ cluster was interrogated by constant energy molecular dynamics simulations, utilizing the first passage time method. The nonreactive isomerization induced by nonselective vibrational excitation is well accounted for in terms of the statistical RRK theory, opening avenues for experimental exploration of time-resolved cluster isomerization dynamics.     

Use of anion-exchange high-performance liquid chromatography for the study of smooth muscle myosin light-chain kinase and its catalytic domain

Avian myosin light-chain kinase from smooth muscle of the gizzard and its catalytic domain, derived from the intact enzyme by trypsin digestion, was purified within 30-40 min by both analytical and preparative anion-exchange high-performance liquid chromatography. The proteins obtained were more than 95% pure and retained their biological activity. The high-performance anion-exchange chromatography protocols represent a significant decrease in purification time when compared with conventional ion-exchange chromatography.     

The free Malcev superalgebra on one odd generator and related superalgebras

A base of the universal multiplicative envelope of the free Malcev superalgebra ℳ on one odd generator is constructed. Some corollaries for skew-symmetric functions and central elements in free Malcev and free alternative algebras are obtained. Moreover, a base of the Poisson-Malcev superalgebra of ℳ is constructed. As a corollary, a set of elements that spans the free alternative superalgebra on one odd generator is obtained. __________ Translated from Fundamentalnaya i Prikladnaya Matematika, Vol. 10, No. 4, pp. 97–106, 2004.     

Special features of magnetic susceptibility dispersion in nanocrystalline magnets

It is demonstrated theoretically that the initial (both elastic and viscous) magnetic susceptibility components for nanocrystalline magnets caused by the processes of rotations (in the region of linear response) have resonant rather than relaxation character typical already for the susceptibility component caused by displacements of domain boundaries. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 88–92, June, 2007.     

Possible spectroscopic manifestation of the angular group induced bond alteration (AGIBA) effect in toluene

The most obvious consequence of the concept of aromaticity is the common confidence that in aromatic compounds, bond lengths do not alternate and are between typical to the single and double ones. However, in 1994, performing crystal structure investigations of substituted pyridines and their salts, Krygowski and co‐workers have discovered a very surprising angular group induced bond alteration (AGIBA) effect: It appears that some angular substituents, like methoxy or nitrozo groups, can induce bond alternation in aromatic rings. Crystal studies do not allow one to operate with liquids that are more common in organic chemistry. This paper presents the first possible evidence of spectroscopic manifestations of the AGIBA effect. Raman spectra of the liquid toluene are analyzed. It is found that instead of being single, the line corresponding to the ring breathing vibrations is clearly split by 1.0–1.4 cm^?1, thus indicating the presence of two (cis‐ and trans‐) AGIBA isomers. The energy difference between these isomers estimated in temperature dependent Raman studies is found equal to 6.68 kJ mol^?1. The low‐wavenumber line therefore corresponds to the cis‐AGIBA isomer and the high‐wavenumber line to the trans‐AGIBA isomer stabilized by the AGIBA effect. Copyright © 2007 John Wiley & Sons, Ltd.     

The diameter of randomly perturbed digraphs and some applications

The central observation of this paper is that if εn random arcs are added to any n‐node strongly connected digraph with bounded degree then the resulting graph has diameter 𝒪(lnn) with high probability. We apply this to smoothed analysis of algorithms and property testing. Smoothed Analysis: Recognizing strongly connected digraphs is a basic computational task in graph theory. Even for digraphs with bounded degree, it is NL‐complete. By XORing an arbitrary bounded degree digraph with a sparse random digraph R ∼ 𝔻_n,ε/n we obtain a “smoothed” instance. We show that, with high probability, a log‐space algorithm will correctly determine if a smoothed instance is strongly connected. We also show that if NL ⫅̸ almost‐L then no heuristic can recognize similarly perturbed instances of (s,t)‐connectivity. Property Testing: A digraph is called k‐linked if, for every choice of 2k distinct vertices s₁,…,s_k,t₁,…,t_k, the graph contains k vertex disjoint paths joining s_r to t_r for r = 1,…,k. Recognizing k‐linked digraphs is NP‐complete for k ≥ 2. We describe a polynomial time algorithm for bounded degree digraphs, which accepts k‐linked graphs with high probability, and rejects all graphs that are at least εn arcs away from being k‐linked. © 2007 Wiley Periodicals, Inc. Random Struct. Alg., 2007     

Electron-beam-induced conductivity and color cathodoluminescence of natural diamond plates in scanning electron microscope

Surfaces of natural type-IIa diamond plates used in ionizing-radiation detectors are studied in a scanning electron microscope using techniques of electron-beam-induced conductivity at different bias voltages and real-color cathodoluminescence.     

Analysis of heterojunction resonant cavity-enhanced Schottky photodiodes by using two-valley transport model

The article concerns heterojunction resonant cavity-enhanced (RCE) Schottky photodiodes with GaAs in the absorption layer. The quantum efficiency and linear pulse response have thoroughly been analysed. For the first time, the response of a heterojunction photodiode has been modelled by the phenomenological model for a two-valley semiconductor. The results obtained have shown that the satellite valleys, as well as the parasitic time constant, significantly influence the response and, accordingly, have to be taken into account when analysing and optimizing RCE photodetectors.