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61.
Flavin K Mullowney J Murphy B Owens E Kirwan P Murphy K Hughes H McLoughlin P 《The Analyst》2007,132(3):224-229
The ability to prepare and develop novel pre-concentration media by the sol-gel process, and their integration with mid-infrared transparent waveguides has been demonstrated. This research approach resulted in a mid-infrared sensing methodology in which the properties (porosity, functionality, polarity, etc.) of the recognition layer could be tailored by variation of the sol-gel precursors and processing conditions. Cross-linker type and concentration notably influenced p-xylene absorption and diffusion rate. Unreacted silanol groups appeared to be the dominant factor in the hydrophobicity of sol-gel layers. Variation of sol-gel precursors and thermal treatment altered both film cross-link density and polarity, as demonstrated by variation in the rate of analyte diffusion and equilibrium analyte concentration. The use of a novel 1 : 1 PTMOS : DPDMS material as pre-concentration medium in this analytical sensing approach was validated through the determination of p-nitrochlorobenzene in an aqueous environment. The response demonstrated linearity between 0-30 mg L(-1) with a correlation coefficient of 0.989 and a limit of detection of 0.7 mg L(-1). Sensing times for p-nitrochlorobenzene were also reduced from several hours to 24 minutes, without loss of measurement accuracy or sensitivity, by a 10 degrees C increase in the sensing temperature and the use of a predictive Fickian model previously developed by this research group. 相似文献
62.
Centonza Angelo; Owens Thomas J.; Cosmas John; Song Yong-Hua 《IMA Journal of Management Mathematics》2007,18(3):245-267
Email: angelo.centonza{at}brunel.ac.uk Corresponding author. Email: thomas.owens{at}brunel.ac.uk Email: john.cosmas{at}brunel.ac.uk¶ Email: y.h.song{at}brunel.ac.uk
Received on 26 November 2005. Accepted on 20 March 2007. The evolution of wireless systems has led recently to the deploymentof cooperative network infrastructures where networks basedon different technologies cooperate together to offer innovativeservices which the networks individually could not offer. Cooperativenetwork infrastructures are hybrid systems. Examples of hybridsystems are already in use in areas as diverse power systemsand locomotion systems. It is very important to apply efficientsystem management techniques to hybrid systems that produceadvantageous business case scenarios for each participatingsystem and efficient use of the available resources. In thispaper, scenarios are investigated where cooperation betweenan integrated project (IP)-based broadcast network and an IP-basedmobile telecommunications network has the potential to allowservices to be provided to mobile users which would not be economicalto offer over either an IP-based broadcast network or an IP-basedmobile telecommunications network alone. The paper presentsa novel technique for determining which network to use to deliversuch services at a given point in time. The application of thistechnique in appropriate scenarios has the potential to generateadditional income for both the IP-based broadcast network operatorand the IP-based mobile telecommunications network operatorin an infrastructure where the operators cooperate to offerinnovative services. The paper explains the construction ofutility functions for cooperative IP-based broadcast and mobiletelecommunications networks. These utility functions are thenused to provide results that enable the efficiency of the managementof the network to be assessed in terms of the utility volumegenerated by the innovative services provided. 相似文献
63.
The chick-a-dee call of chickadee species (genus Poecile) has been the focus of much research. A great deal is known about the structural complexity and the meaning of variation in notes making up calls in these species. However, little is known about the likely homologous "chick-a-dee" call of the closely related tufted titmouse, Baeolophus bicolor. Tufted titmice are a prime candidate for comparative analyses of the call, because their vocal and social systems share many characteristics with those of chickadees. To address the paucity of data on the structure of chick-a-dee calls of tufted titmice, we recorded birds in field and aviary settings. Four main note types were identified in the call: Z, A, D(h), and D notes. Several acoustic parameters of each note type were measured, and statistical analyses revealed that the note types are acoustically distinct from one another. Furthermore, note types vary in the extent of individual distinctiveness reflected in their acoustic parameters. This first step towards understanding the chick-a-dee call of tufted titmice indicates that the call is comparable in structure and complexity to the calls of chickadees. 相似文献
64.
Hanzhong Zhang Jeff Owens Enke Wang Xin-Nian Wang 《The European Physical Journal C - Particles and Fields》2009,61(4):825-828
High-p
T photon–hadron correlations are studied within the next-to-leading order (NLO) perturbative QCD parton model with modified
parton-jet fragmentation functions due to jet quenching in high-energy A+A collisions. In central A+A collisions, the away-side hadrons with large z
T=p
T
h
/p
T
γ
are controlled mainly by the surface emission of the gamma-jet events, while a small z
T region will be volume emission bias. In other words, gamma jets for a small-z
T region probe the dense matter deeper than those gamma jets for a large-z
T region, so the small-z
T gamma jets are found to be slightly more sensitive to the properties of the dense matter than the large-z
T gamma jets. 相似文献
65.
Neil W. Owens Adrian Lee Kirk Marat Dr. Frank Schweizer Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(40):10649-10657
The conformations of peptides and proteins are often influenced by glycans O‐linked to serine (Ser) or threonine (Thr). (2S,4R)‐4‐Hydroxyproline (Hyp), together with L ‐proline (Pro), are interesting targets for O‐glycosylation because they have a unique influence on peptide and protein conformation. In previous work we found that glycosylation of Hyp does not affect the N‐terminal amide trans/cis ratios (Ktrans/cis) or the rates of amide isomerization in model amides. The stereoisomer of Hyp—(2S,4S)‐4‐hydroxyproline (hyp)—is rarely found in nature, and has a different influence both on the conformation of the pyrrolidine ring and on Ktrans/cis. Glycans attached to hyp would be expected to be projected from the opposite face of the prolyl side chain relative to Hyp; the impact this would have on Ktrans/cis was unknown. Measurements of 3J coupling constants indicate that the glycan has little impact on the Cγ‐endo conformation produced by hyp. As a result, it was found that the D ‐galactose residue extending from a Cγ‐endo pucker affects both Ktrans/cis and the rate of isomerization, which is not found to occur when it is projected from a Cγ‐exo pucker; this reflects the different environments delineated by the proline side chain. The enthalpic contributions to the stabilization of the trans amide isomer may be due to disruption of intramolecular interactions present in hyp; the change in enthalpy is balanced by a decrease in entropy incurred upon glycosylation. Because the different stereoisomers—Hyp and hyp—project the O‐linked carbohydrates in opposite spatial orientations, these glycosylated amino acids may be useful for understanding of how the projection of a glycan from the peptide or protein backbone exerts its influence. 相似文献
66.
Valentine KG Pometun MS Kielec JM Baigelman RE Staub JK Owens KL Wand AJ 《Journal of the American Chemical Society》2006,128(50):15930-15931
Proteins encapsulated within the aqueous core of reverse micelles are found to partially align in a magnetic field. The degree of alignment is sufficient to result in sizable residual 15N-1H dipolar couplings that can be easily measured. It is found that the magnetic susceptibility of the reverse micelle particle is not dominated by the encapsulated protein. The residual dipolar couplings are found to be structurally meaningful. 相似文献
67.
The solvent varying technique (SVT) provides a simple method for the production of uniform batches of silica nanoparticles (SNPs) of a target average diameter. SNPs synthesized using the SVT have been observed to agglomerate over increasing storage times leading to an increase in average particle diameter. Since the particle diameters of the SNPs produced using the SVT may vary over increasing storage durations, the previous model, suggested by Gao et al., which is based on the diameter of the original SNPs, is unreliable when predicting a target particle diameter using the initial volume of ethanol. A centrifuge and replacement of solvent method has been applied in this investigation to the SNP solutions created using the SV technique. This reduces the amount of unused reactants in the centrifuged colloidal suspensions, which further improves the quality of the SNPs and hence any subsequent photonic crystals. Post centrifuge and replace, the morphology of the centrifuged particles is more uniform than that of the original particles, which has been evaluated using SEM micrographs. The face-centered cubic (FCC) structures observed on the surface of the photonic crystal films have also been imaged using a SEM. A linear equation for the prediction of the SNP diameters for a given initial amount of ethanol is proposed based on the centrifuged SNP diameters. The particle diameter measurements for the new equation were recorded using a DLS instrument. The dispersion of the SNPs was also recorded using DLS. The morphology of the surface of the particles has been confirmed using TEM micrographs. 相似文献
68.
Evaluation of methods aimed at complete removal of template from molecularly imprinted polymers. 总被引:1,自引:0,他引:1
A Ellwanger C Berggren S Bayoudh C Crecenzi L Karlsson P K Owens K Ensing P Cormack D Sherrington B Sellergren 《The Analyst》2001,126(6):784-792
Polymers imprinted with clenbuterol were used to study the influence of various post-polymerization treatments [e.g., thermal annealing, microwave assisted extraction (MAE), Soxhlet extraction and supercritical fluid template desorption] on the bleeding of residual template. The aim of the study was to reduce the bleeding to levels that would allow the use of the materials as affinity phases for extraction of clenbuterol from bovine urine at concentrations below 1 ng ml-1. After treatment, the clenbuterol imprinted polymers were packed into solid-phase extraction columns and the bleeding was estimated by quantifying the amount of template released in 10 ml of methanol-acetic acid (9 + 1 v/v). This was followed by an assessment of selectivity and recovery in comparison with non-treated material. The lowest bleeding level was found after MAE using 100% trifluoroacetic acid for 3 x 20 min at 100 degrees C. The collected eluate contained in this case 3 ng ml-1 of clenbuterol. The same material was subsequently used for the extraction of clenbuterol from spiked bovine urine. The resulting selectivity and recovery were lower compared with those obtained using the untreated material. A milder but still efficient method to reduce the bleeding level was found to be MAE with formic acid. In this case a bleeding level of 14 ng ml-1 was found after only a 1 h extraction time. In a second model system, using a polymer imprinted with L-phenylalanine anilide, the bleeding was reduced to a similar level by extensive on-line washing in good swelling solvents containing acid or base additives and after thermal annealing of the polymers in the dry state. 相似文献
69.
Hydrogen gas is burned in air to raise and maintain the stagnation temperature of a supersonic combustion test facility to
a desired setpoint. In order to reach the desired operating conditions for stagnation temperature, there are three phases
to the hydrogen control; H2 ignition at facility start-up, H2 ramp-up while the facility is ramped-up, and H2 iteration to achieve the desired temperature setpoint. Each phase incorporates a different type of control. Fuzzy logic is
used to design a computer based supervisory controller that recognizes the different phases of operation and chooses the appropriate
control method.
Received: 28 November 1999/Accepted: 2 November 2000 相似文献
70.
Peter Bougeard Christopher J. Cooksey Michael D. Johnson Melanie J. Lewin Stewart Mitchell Paul A. Owens 《Journal of organometallic chemistry》1985,288(3):349-358
Under irradiation by tungsten light in pyridine solution, several substituted alkylcobaloximes undergo rearrangement to more stable substituted alkyl- or alkenyl-cobaloximes. When the same reactions are carried out in the presence of carbon tetrachloride or chloroform, no rearranged organocobaloximes are obtained, but a variety of organic products are obtained derived from the interception of transient organic radicals by the halogenated solvent. The rearrangements are rationalised in terms of a reversible homolysis of the carbon-cobalt bond, rearrangement of the organic radical and recapture by the cobalt(II) fragment to give complexes that are more stable to irradiation than their precursors. 相似文献