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排序方式: 共有189条查询结果,搜索用时 15 毫秒
181.
Ovidiu Oprea Oana Ciocirlan Alina Badanoiu Eugeniu Vasile 《Central European Journal of Chemistry》2014,12(7):749-756
ZnO nanoparticles were synthesized in mixtures of ionic liquids based on imidazolium cation with organic solvents (dimethyl sulfoxide and ethylene glycol) by a simple, one-step solution route at low temperature. The effect of these mixtures on the morphology, size and properties of as obtained ZnO nanopowders was investigated. The obtained nanopowders have been characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), UV-Vis absorption spectroscopy (UV-Vis) and photoluminescence (PL). The effect of the ionic liquid mixture on the photocatalytic degradation of methylene blue has been analysed. The XRD studies confirmed the hexagonal wurtzite structure of the obtained ZnO powder. The UV-Vis absorption spectra present the typical shape for ZnO, with a broad band situated in the UV region, with the maximum around 360 nm. The calculated band-gap energy is in interval 3.25–3.28 eV. The synthesized ZnO nanopowders have high photocatalytic activity against methylene blue, the best results being obtained when 1-ethyl-3-methylimidazolium tetrafluoroborate was used as the solvent.
相似文献
182.
Florea I Ersen O Arenal R Ihiawakrim D Messaoudi C Chizari K Janowska I Pham-Huu C 《Journal of the American Chemical Society》2012,134(23):9672-9680
We present here the application of the energy-filtered transmission electron microscopy (EFTEM) in the tomographic mode to determine the precise 3D distribution of nitrogen within nitrogen-doped carbon nanotubes (N-CNTs). Several tilt series of energy-filtered images were acquired on the K ionization edges of carbon and nitrogen on a multiwalled N-CNT containing a high amount of nitrogen. Two tilt series of carbon and nitrogen 2D maps were then calculated from the corresponding energy-filtered images by using a proper extraction procedure of the chemical signals. Applying iterative reconstruction algorithms provided two spatially correlated C and N elemental-selective volumes, which were then simultaneously analyzed with the shape-sensitive reconstruction deduced from Zero-Loss recordings. With respect to the previous findings, crucial information obtained by analyzing the 3D chemical maps was that, among the two different kind of arches formed in these nanotubes (transversal or rounded ones depending on their morphology), the transversal arches contain more nitrogen than do the round ones. In addition, a detailed analysis of the shape-sensitive volume allowed the observation of an unexpected change in morphology along the tube axis: close to the round arches (with less N), the tube is roughly cylindrical, whereas near the transversal ones (with more N), its shape changes to a prism. This relatively new technique is very powerful in the material science because it combines the ability of the classical electron tomography to solve 3D structures and the chemical selectivity of the EFTEM imaging. 相似文献
183.
Summary During bioconcentration, chemical pollutants from water are absorbed by aquatic animals via the skin or a respiratory surface, while the entry routes of chemicals during bioaccumulation are both directly from the
environment (skin or a respiratory surface) and indirectly from food. The bioconcentration factor (BCF) and the bioaccumulation
factor (BAF) for a particular chemical compound are defined as the ratio of the concentration of a chemical inside an organism
to the concentration in the surrounding environment. Because the experimental determination of BAF and BCF is time-consuming
and expensive, it is efficacious to develop models to provide reliable activity predictions for a large number of chemical
compounds. Polychlorinated biphenyls (PCBs) released from industrial activities are persistent pollutants of the environment
that produce widespread contamination of water and soil. PCBs can bioaccumulate in the food chain, constituting a potential
source of exposure for the general population. To predict the bioconcentration and bioaccumulation factors for PCBs we make
use of the biphenyl substitution-reaction network for the sequential substitution of H-atoms by Cl-atoms. Each PCB structure
then occurs as a node of this reaction network, which is some sort of super-structure, turning out mathematically to be a
partially ordered set (poset). Rather than dealing with the molecular structure via ordinary QSAR we use only this poset,
making different quantitative super-structure/activity relationships (QSSAR). Thence we developed cluster expansion and splinoid
QSSARs for PCB bioconcentration and bioaccumulation factors. The predictive ability of the BAF and BCF models generated for
20 data sets (representing different conditions and fish species) was evaluated with the leave-one-out cross-validation, which
shows that the splinoid QSSAR (r between 0.903 and 0.935) are better than models computed with the cluster expansion (r between 0.745 and 0.887). The splinoid QSSAR models for BAF and BCF yield predictions for the missing PCBs in the investigated
data sets. 相似文献
184.
Meyer C Pascui O Reichert D Sander LC Wise SA Albert K 《Journal of separation science》2006,29(6):820-828
A polymer-based RP sorbent was prepared by immobilizing a poly(ethylene-co-acrylic acid) copolymer with an acid mass fraction of 5% on silica by using a 3-glycidoxypropyl linkage. 13C cross-polarization/magic angle spinning NMR spectroscopy of the sorbent, either in the dry state or suspended in the mobile phase, showed an increase in mobility at elevated temperatures. Alkyl chain segments with gauche conformations were more mobile than chain segments with trans conformations. The strength of the 13C-1H dipolar couplings in the alkyl chains was measured using the constant time dipolar and chemical shift pulse sequence, revealing less molecular motion for the trans conformation. Non-linear van't Hoff plots were observed for separations of shape-constrained solutes (such as geometric beta-carotene isomers and polycyclic aromatic hydrocarbons). At higher temperatures, the retention behavior was similar to that of monomeric C18 sorbents, whereas at ambient and lower temperatures, enhanced shape-selective properties were exhibited similar to those of polymeric C30 sorbents. 相似文献
185.
Ovidiu Calin Der-Chen Chang Haitao Fan 《Journal of Fourier Analysis and Applications》2009,15(6):816-838
There are two parts of this article. We first find explicit formulas for the heat kernel of the sub-elliptic operators $\frac{1}{2}\partial_{x}^{2}-x^{m}\partial_{y}$ with m=0,1,2. We also find the heat kernel for the sub-elliptic operator $\frac{1}{2}\sum_{j=1}^{n}\partial_{x_{j}}^{2}+(\sum_{j=1}^{n}a_{j}x_{j})\partial_{y}$ , with a i constants. In the second part of this paper, we apply results from the first part to construct a close form formula for pricing Asian options on a geometric moving average. 相似文献
186.
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188.
We introduce a recently developed class of SolidState NMR experiments for the investigation of slow dynamic processes in organic solids. These 1D-MAS exchange experiments do not require selective isotopic labeling and can be performed with standard solid-state NMR hardware. The data are easy to analyze and provide selective information about the correlation times as well as about the topology (jump angles etc.) of dynamic processes in different sub-units of the molecules. We present data for Poly(n-butylmethacrylate), PBMA, between the glass transition temperature Tg and the αβ splitting temperature, in order to demonstrate the advantages of these 1D-MAS methods. 相似文献
189.