芴2,7位取代的9,9’-二芳基螺芴类化合物的合成及性能

设计并合成了一系列以三苯胺为核,芴衍生物为外围基团的有机蓝光小分子,该合成通过Suzuki反应在9-芳基芴的2位和(或)7位引入相同或不同取代基作为模块,并利用Friedel-Crafts反应将4-甲基三苯胺与这一系列模块结合.用NMR,MS和元素分析进行结构表征.荧光测试结果表明该类化合物溶液的荧光发射波长范围在442～466 nm之间,属蓝光发射.电化学测试显示该类材料的HOMO能级位于-5.15～-5.19 eV之间.差示扫描量热仪与热重分析得出化合物的玻璃化转变温度在166℃以上,热分解温度高于398℃,表明该类材料具有良好的热稳定性.     

SEGAL ALGEBRA $\[{A_{1,p}}(G)\]$ AND ITS MULTIPLIERS

Let G be a locally compactb abelian group and $\[{A_p}(G)\]$ the p-Fourier algeba of Herz. This pepar studies the space $\[{A_{1,p}}(G) = {L_1}(G) \cap {A_p}(G)\]$ with convolution product. It is proved that $\[{A_{1,p}}(G)\]$ is a character Segal algebra. Moreover, for the multipliers of $\[{A_{1,p}}(G)\]$ the author proves that $\[M({A_{1,p}}(G),{L_1}(G)) = M(G)\]$ and $\[M({A_{1,p}}(G),{A_{1,p}}(G)) = M(G)\]$ provided G is noncompact. If G is discrete, then $\[M({A_{1,p}}(G),{L_1}(G)) = {A_{1,p}}(G)\$ and $\[M({A_{1,p}}(G),{A_{1,p}}(G)) = {A_{1,p}}(G)\]$     

隐含风险中性分布在巨灾超额损失再保险定价中的应用

通过与标的风险相关的期权市场估计出隐含变换系数,然后以Esscher变换为工具,将巨灾损失统计分布风险中性化,从而对以该非交易风险为标的的巨灾超额损失再保险进行定价.同时,从期权定价的角度,结合Weibull极值分布和超额损失再保险的特点,给出了巨灾超额损失再保险定价的闭型表达式.     

Determining optimal lot size for a two-warehouse system with deterioration and shortages using net present value

In this paper, we develop a deterministic inventory model for deteriorating items with two warehouses by minimizing the net present value of the total cost. Deterioration rates of items in the two warehouses may be different. In addition, we allow for shortages and complete backlogging. We then prove that the optimal replenishment policy not only exists but also is unique under some condition. Further, the result reveals that the reorder interval based on the average total cost, if it exists, must be longer than that derived using net present value. Finally, we use Yang’s [H.L. Yang, European Journal of Operational Research 157 (2004) 344–356] numerical example to illustrate the model and conclude the paper with suggestions for possible future research.     

ORG500W/4.5K制冷机的改造流程设计计算及分析

介绍了带LN2预冷的二级膨胀循环的流程计算方法,并提出了优化计算的思路和计算机程序实现的方法;最后就换热器热端温差对制冷机效率的影响进行了讨论     

Nonequilibrium Thermodynamics in Biochemical Systems and Its Application

Living systems are open systems, where the laws of nonequilibrium thermodynamics play the important role. Therefore, studying living systems from a nonequilibrium thermodynamic aspect is interesting and useful. In this review, we briefly introduce the history and current development of nonequilibrium thermodynamics, especially that in biochemical systems. We first introduce historically how people realized the importance to study biological systems in the thermodynamic point of view. We then introduce the development of stochastic thermodynamics, especially three landmarks: Jarzynski equality, Crooks’ fluctuation theorem and thermodynamic uncertainty relation. We also summarize the current theoretical framework for stochastic thermodynamics in biochemical reaction networks, especially the thermodynamic concepts and instruments at nonequilibrium steady state. Finally, we show two applications and research paradigms for thermodynamic study in biological systems.