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991.
Numerical Algorithms - The circumcentered Douglas–Rachford method (C–DRM), introduced by Behling, Bello Cruz and Santos, iterates by taking the circumcenter of associated successive... 相似文献
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Dr. Yuebin Lian Dr. Wenjuan Yang Chufeng Zhang Hao Sun Prof. Zhao Deng Dr. Wenjie Xu Prof. Li Song Prof. Zhongwen Ouyang Prof. Zhenxing Wang Prof. Jun Guo Prof. Yang Peng 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(1):292-300
Reversible oxygen conversion is important for various green energy technologies. Herein we synthesize a series of bimetallic coordination polymers by varying the Ni/Co ratio and using HITP (HITP=2,3,6,7,10,11-hexaiminotriphenylene) as the ligand, to interrogate the role of metal centres in modulating the activity of the oxygen reduction reaction (ORR). Co3HITP2 and Ni3HITP2 are compared. Unpaired 3d electrons in Co3HITP2 result in less coplanarity but more radical character. Thus, despite of a reduced crystallinity and conductivity, the best ORR activity, comparable to 20 % Pt/C, is obtained for Co3HITP2, showing the 3d orbital configuration of the metal centre promotes ORR. Experimental and DFT studies show a transition of ORR pathway from four-electron for Co3HITP2 to two-electron for Ni3HITP2. Rechargeable zinc–air batteries using Co3HITP2 as the air cathode catalyst demonstrate excellent energy efficiency and stability. 相似文献
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AbstractIn this study, antitumor activity and composition analysis of the core of Camellia osmantha fruit were investigated. The cores were extracted by 80% ethanol to obtain the crude extract (TF), which was successively distributed by different concentrations of ethanol with MCI resin to obtain three different parts (Frs 1 to 3). Cytotoxicity activities showed that TF, Fr-2, and Fr-3 exhibited good inhibition against T-24 with IC50 values of 6.7 ± 1.3, 6.9 ± 0.9, and 6.7 ± 1.7 μg/mL, respectively. Fr-3 has a strong inhibitory activity on T-24 cells, mainly due to effectively increasing the release of intracellular calcium ions and reactive oxygen species. In addition, Fr-3 can inhibit T-24 cells migration and invasion. Further composition analysis on Fr-3 was detected by LC-Q-TOFMS implying the main components to be ellagic acid and its derivatives. 相似文献
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Meccanica - This paper investigates the effects of tangential harmonic excitation on the friction-induced-vibration in multi-degree-of-freedom systems that are coupled in the tangential and normal... 相似文献
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Haidong Xia Suli Kan Zhenjiang Li Jia Chen Saide Cui Wenzhuo Wu Pingkai Ouyang Kai Guo 《Journal of polymer science. Part A, Polymer chemistry》2014,52(16):2306-2315
An organocatalytic approach to controlled/living ring‐opening polymerizations (ROPs) of O‐carboxyanhydrides (OCAs) using N‐heterocyclic carbenes (NHCs) as nucleophilic catalysts has been investigated. NHCs with different structures were used in order to compare the catalytic performances in the ROP of OCA of l ‐lactic acid. 1H NMR, SEC, and MALDI‐TOF MS measurements of the products clearly indicated a controlled/living manner of the polymerization. The controlled/living nature was further confirmed by kinetic and chain extension experiments. Additionally, polylol initiators were used to produce α,ω‐dihydroxy telechelic, 3‐, and 4‐armed star‐shaped polymers. Moreover, star‐shaped diblock copolymer, bearing methyl and phenyl side groups, has been successfully synthesized with OCA/NHC system. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 . 52, 2306–2315 相似文献
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