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81.
de Namor AF Chahine S Castellano EE Piro OE Jenkins HD 《Chemical communications (Cambridge, England)》2005,(30):3844-3846
An additive thermodynamic contribution of pendant arms to the complexation of calixarene derivatives with mercury(II) in acetonitrile is for the first time demonstrated. 相似文献
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Oscar H. Will III Natalie A. Newland Kaylan L. Blelville 《Photochemistry and photobiology》1985,41(3):283-287
Abstract— Exposure of variously pigmented strains of Ustilago violacea to high intensity incandescent radiation resulted in the generation of three types of survival curves. High carotene, low cytochrome c containing strains of U. violacea were generally characterized by linear type I survival curves with slopes approximately equal to zero. Strains which lacked carotenes were characterized by exponential decay type II survival curves. A third survival curve, type III was observed with carotene accumulating strains which also contained large amounts of cytochrome c. The type III curves are characterized by an initial loss of viability, similar to the type II curves, followed by a recovery period, with eventual stability in survival. The survival curve type appears to be dependent on the relative mg quantities of cytochrome c and carotenes in the cells. Strains with carotene/cytochromec ratios of0–1 × 10-1 ,3–15× 10-1 and l6 × 10-1 and above had type II, type III and type I survival curves, respectively. 相似文献
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The use of electrothermal vaporisation (ETV) from a graphite furnace as a means of sample introduction in inductively coupled plasma mass spectrometry (ICP-MS) permits the direct analysis of solid samples. A multi-step furnace temperature programme is used to separate the vaporisation of the target element(s) and of the matrix components from one another. Sometimes, a chemical modifier is used to enable a higher thermal pre-treatment temperature, by avoiding premature analyte losses (stabilisation) or promoting the selective volatilisation of matrix components. In almost all instances, accurate results can be obtained via external calibration or single standard addition using an aqueous standard solution. Absolute limits of detection are typically ~1 pg, which corresponds to 1 ng/g for a typical sample mass of 1 mg. Real-life applications carried out in the author's lab are used to illustrate the utility of this approach. These applications aim at trace element determination in industrial and environmental materials. The industrial materials analysed include different types of plastics - Carilon, polyethylene, poly(ethyleneterephtalate) and polyamide - and photo- and thermographic materials. As samples from environmental origin, plant material, animal tissue and sediments were investigated. Some applications aimed at a multi-element determination, while in other, the content of a single, but often challenging, element (e.g., Si or S) had to be measured. ETV-ICP-MS was also used in elemental speciation studies. Separation of Se-containing proteins was accomplished using polyacrylamide gel electrophoresis (PAGE). Subsequent quantification of the Se content in the protein spots was carried out using ETV-ICP-MS. As the volatilisation of methylmercury and inorganic mercury could be separated from one another with respect to time, no chromatographic or electrophoretic separation procedure was required, but ETV-ICP-MS as such sufficed for Hg speciation in fish tissue. 相似文献
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A completely automated method to determine the most common parameters in cured meat products is proposed. The approach to full automation is based on the coupling of a robotic station for development of preliminary operations (namely weighing of the sample, grinding, leaching, filtration and transport to the aspiration zone) and a continuous unsegmented manifold for derivatisation and spectrophotometric monitoring of the reaction coloured products. This assembly works in an unattended fashion thus eliminating the bottleneck produced by the determination of these parameters in routine laboratories. The good agreement between results obtained by the proposed method and those from conventional methods for target analytes confirms its excellent performance and usefulness. 相似文献