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991.
The structural fluctuation of the orientational arrangement of buckled dimers on a Ge(0 0 1) surface near the transition temperature of the order-disorder phase transition is investigated by time-resolving dynamical Monte Carlo simulations. STM images averaged in a finite period are derived from the simulation. The coexistence of the c(4 × 2) and the apparent (2 × 1) domains in the STM images observed by experiments is reproduced in the simulated STM images. We show that the coexistence on the Ge(0 0 1) surface can be attributed to the critical slowing down near the transition temperature. 相似文献
992.
Jun-ichi Nishizawa Ken Suto Tetsuo Sasaki Tadao Tanabe Takenori Tanno Yutaka Oyama Fumikazu Sato 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2006,82(9):353-358
One of the most important uses of THz spectrometry is to detect defects in molecular structure or in crystals efficiently. We applied GaP Raman THz (GRT) spectrometer to detect and evaluate defects in inorganic and organic materials. High THz-wave absorption due to high defect density of GaSe crystal lowered the efficiency of THz wave generation, when the crystal is used as nonlinear material for DFG (Difference Frequency Generation). Defects in organic molecules could be observed as changes in frequency, intensities of the absorption, and broadenings of the spectra. 相似文献
993.
Osamu Sakurada Yasutake Kato Noriyoshi Kito Keiichi Kameyama Toshiaki Hattori Minoru Hashiba 《Analytical sciences》2004,20(2):311-314
Zirconium oxy-salts were hydrolyzed to form positively charged polymer or cluster species in acidic solutions. The zirconium hydrolyzed polymer was found to react with a negatively charged polyelectrolyte, such as poly(vinyl sulfate), and to form a stoichiometric polyion complex. Thus, colloidal titration with poly(vinyl sulfate) was applied to measure the zirconium concentration in an acidic solution by using a Toluidine Blue selective plasticized poly(vinyl chloride) membrane electrode as a potentiometric end-point detecting device. The determination could be performed with 1% of the relative standard deviation. The colloidal titration stoichiometry at pH < or = 2 was one mol of zirconium per equivalent mol of poly(vinyl sulfate). 相似文献
994.
Masato Mikami Kazuhiro Yamamoto Osamu Moriue Naoya Kojima 《Proceedings of the Combustion Institute》2005,30(2):2021-2028
Gas turbines, liquid rocket motors, and oil-fired furnaces utilize the spray combustion of continuously injected liquid fuels. In most cases, the liquid spray is mixed with an oxidizer prior to combustion, and further oxidizer is supplied from the outside of the spray to complete diffusion combustion. This rich premixed spray is called “partially premixed spray.” Partially premixed sprays have not been studied systematically although they are of practical importance. In the present study, the burning behavior of partially premixed sprays was experimentally studied with a newly developed spray burner. A fuel spray and an oxidizer, diluted with nitrogen, was injected into the air. The overall equivalence ratio of the spray jet was set larger than unity to establish partially premixed spray combustion. In the present burner, the mean droplet diameter of the atomized liquid fuel could be varied without varying the overall equivalence ratio of the spray jet. Two combustion modes with and without an internal flame were observed. As the mean droplet diameter was increased or the overall equivalence ratio of the spray jet was decreased, the transition from spray combustion only with an external group flame to that with the internal premixed flame occurred. The results suggest that the internal flame was supported by flammable mixture through the vaporization of fine droplets, and the passage of droplet clusters deformed the internal flame and caused internal flame oscillation. The existence of the internal premixed flame enhanced the vaporization of droplets in the post-premixed-flame zone within the external diffusion flame. 相似文献
995.
A novel strategy to construct a fibroblast scaffold on substrates has been demonstrated via top-down photolithography and the subsequent bottom-up processes of molecular self-assembly and molecular recognition. 3-Aminopropyltrimethoxysilane (APS) self-assembled monolayer was micropatterned by photolithography. An anionic polysaccharide heparin was adsorbed selectively on the cationic APS region of the micropatterned substrate. Basic fibroblast growth factor (bFGF) was selectively bound to the displayed heparin region and then micropatterned cultivation of fibroblast cells was successful on the bFGF-heparin-APS substrate. 相似文献
996.
Tsuneo Fujii Shozi Mishima Nobuaki Tanaka Osamu Kawauchi Kazuhiko Kodaira Hiromasa Nishikiori Yoshinobu Kawai 《Research on Chemical Intermediates》1997,23(9):829-839
The absorption, fluorescence, and fluorescence-excitation spectra of 9-anthrol (and/or anthrone) have been observed in various
solvents, one of which includes a silicon-aluminium ester (diisobutoxyaluminium triethyl silane[(OBu)2−Al−O−Si−(OEt)3 SAE]). The fluorescence spectra of 9-anthrol shows peak wavelengths at 442 nm in benzene, 454 nm in methanol, 539 nm in triethylamine,
and 550 nm in basic solution, which can be assigned to a neutral, a hydrogen-bonded neutral, an ion pair, and an anionic species
of 9-anthrol, respectively. In ethanol solution including SAE, on the other hand, a new fluorescence peak appears at 473 nm.
This new band originates from a complex formed between 9-anthrol and SAE. The excited-state ion pair is formed through the
hydrogen-bonded form in water and the complex form in triethylamine. CNDO/S calculations support the experimental results. 相似文献
997.
Miwa Goto Hideyuki Takedani Osamu Nitta Kennosuke Kawama 《Physical Therapy Research》2015,18(1):15-22
Background: The Arnold-Hilgartner classification is one of the most popular evaluation systems for the progression hemophilic arthropathy. A previous study reported an association between arthropathy severity and arc range of motion (ROM). However, associations between arthropathy severity and angular ROM and muscle strength remain unclear. AIM: The purpose of this study was to clarify the association between joint function and arthropathy severity in hemophilia. Methods: We studied the knee, ankle, and elbow joints of 31 patients with hemophilia (PWH). The condition of the affected joints was evaluated on the basis of the interview data, joint function measurements, and roentgenography of the affected joints. In assessment of joint function, we evaluated knee strength (flexor, extensor) and grip strength as well as the passive ROM of the elbow, knee, and ankle. During the interview, all patients were asked about the history of intra-articular bleeding over the past year and pain. Results: As arthropathy severity worsened, knee flexor strength, knee extensor strength, grip strength, and ROM (elbow flexion, elbow extension, knee flexion, knee extension, and ankle extension) significantly decreased. Even patients with mild arthropathies experienced knee extensor weakness and extension limitation. In addition, joint function of severe ankle arthropathy was significantly related to the history of intra-articular bleeding and pain. Conclusion: Our results suggest that physical therapy is necessary to improve joint function in PWH and mild or no arthropathy. Pain control and prophylactic hematological management are necessary for patients with severe arthropathy because intra-articular bleeding and pain significantly decrease joint function. 相似文献
998.
Ravi Devraj Kaushik Nag Prasant Nahak Kausik Manna Mauricia Fritzen-Garcia David W. Thompson Kimiko Makino Hiroyuki Ohshima Hiromichi Nakahara Osamu Shibata Amiya Kumar Panda 《Colloid and polymer science》2014,292(11):2765-2774
Lung surfactant (LS), a lipid–protein mixture responsible for alveolar stability, is inhibited by serum proteins leaked into the lungs in disease. Interaction of bovine lipid extract surfactant (BLES), a clinical replacement lung surfactant, with serum protein fibrinogen (Fbg) was studied employing various structural and biophysical techniques in adsorbed films and bulk bilayer dispersions. Surface tension area isotherms of the adsorbed films revealed the suppression of interfacial activity of BLES by Fbg (adsorption and surface tension reduction). Fbg, predominantly associated with the fluid phase of BLES films, resulted in the aggregation of the gel lipid domains as evidenced by atomic force microscopy. BLES bilayer dispersion showed phase transition from a diffused gel to liquid–crystalline phase in the temperature range 10–35 °C as studied by differential scanning calorimetry (DSC). Fbg resulted in the shift of peak to a higher transition temperature for the maximal heat flow (T max) of BLES dispersions. Combined Raman and FTIR spectral studies of the BLES/Fbg dispersions revealed that Fbg altered the –CH2–, –CH3, and –PO4 ? vibrational modes of the phospholipids present in BLES, suggesting the condensing and dehydrating effect of the protein on surfactant. Studies suggest that Fbg, by directly interacting with the gel lipids in LS in bulk dispersions, alter the packing of the films formed at the interface, and can be used as a specific model for lung disease. 相似文献
999.
Jingjuan Liu Yi Zhou Zhen Xie Yang Li Dr. Yunpeng Liu Prof. Jie Sun Prof. Yanhang Ma Prof. Osamu Terasaki Prof. Long Chen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(3):1097-1102
A conjugated copper(II) catecholate based metal–organic framework (namely Cu-DBC) was prepared using a D2-symmetric redox-active ligand in a copper bis(dihydroxy) coordination geometry. The π-d conjugated framework exhibits typical semiconducting behavior with a high electrical conductivity of ca. 1.0 S m−1 at room temperature. Benefiting from the good electrical conductivity and the excellent redox reversibility of both ligand and copper centers, Cu-DBC electrode features superior capacitor performances with gravimetric capacitance up to 479 F g−1 at a discharge rate of 0.2 A g−1. Moreover, the symmetric solid-state supercapacitor of Cu-DBC exhibits high areal (879 mF cm−2) and volumetric (22 F cm−3) capacitances, as well as good rate capability. These metrics are superior to most reported MOF-based supercapacitors, demonstrating promising applications in energy-storage devices. 相似文献
1000.
A Novel Type of Luciferin from the Siberian Luminous Earthworm Fridericia heliota: Structure Elucidation by Spectral Studies and Total Synthesis 下载免费PDF全文
Valentin N. Petushkov Maxim A. Dubinnyi Aleksandra S. Tsarkova Natalja S. Rodionova Mikhail S. Baranov Vadim S. Kublitski Osamu Shimomura Ilia V. Yampolsky 《Angewandte Chemie (International ed. in English)》2014,53(22):5566-5568
The structure elucidation and synthesis of the luciferin from the recently discovered luminous earthworm Fridericia heliota is reported. This luciferin is a key component of a novel ATP‐dependent bioluminescence system. UV, fluorescence, NMR, and HRMS spectroscopy studies were performed on 0.005 mg of the isolated substance and revealed four isomeric structures that conform to spectral data. These isomers were chemically synthesized and one of them was found to produce light when reacted with a protein extract from F. heliota. The novel luciferin was found to have an unusual extensively modified peptidic nature, thus implying an unprecedented mechanism of action. 相似文献