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131.
Physical and chemical properties of bio-oils from microwave pyrolysis of corn stover 总被引:4,自引:0,他引:4
Yu F Deng S Chen P Liu Y Wan Y Olson A Kittelson D Ruan R 《Applied biochemistry and biotechnology》2007,137(1-12):957-970
This study was aimed to understand the physical and chemical properties of pyrolytic bio-oils produced from microwave pyrolysis of corn stover regarding their potential use as gas turbine and home heating fuels. The ash content, solids content, pH, heating value, minerals, elemental ratio, moisture content, and viscosity of the bio-oils were determined. The water content was approx 15.2 wt%, solids content 0.22 wt%, alkali metal content 12 parts per million, dynamic viscosity 185 mPa.s at 40 degrees C, and gross high heating value 17.5 MJ/kg for a typical bio-oil produced. Our aging tests showed that the viscosity and water content increased and phase separation occurred during the storage at different temperatures. Adding methanol and/or ethanol to the bio-oils reduced the viscosity and slowed down the increase in viscosity and water content during the storage. Blending of methanol or ethanol with the bio-oils may be a simple and cost-effective approach to making the pyrolytic bio-oils into a stable gas turbine or home heating fuels. 相似文献
132.
The ring-opening reactions of the radical cations of hexamethyl Dewar benzene (1) and Dewar benzene have been studied using density functional theory (DFT) and complete active-space self-consistent field (CASSCF) calculations. Compound 1 is known to undergo photoinitiated ring opening by a radical cation chain mechanism, termed "quantum amplified isomerization" (QAI), which is due to the high quantum yield. Why QAI is efficient for 1 but not other reactions is explained computationally. Two radical cation minima of 1 and transition states located near avoided crossings are identified. The state crossings are characterized by conical intersections corresponding to degeneracy between doublet surfaces. Ring opening occurs by formation of the radical cation followed by a decrease in the flap dihedral angle. A rate-limiting Cs transition state leads to a second stable radical cation with an elongated transannular C-C bond and an increased flap dihedral. This structure proceeds through a conrotatory-like pathway of Cs symmetry to give the benzene radical cation. The role of electron transfer was investigated by evaluating oxidation of various systems using adiabatic ionization energies and electron affinities calculated from neutral and cation geometries. Electron-transfer theory was applied to 1 to investigate the limiting effects of back-electron transfer as it is related to the unusual stability of the two radical cations. Expected changes in optical properties between reactants and products of Dewar benzene compounds and other systems known to undergo QAI were characterized by computing frequency-dependent indices of refraction from isotropic polarizabilities. In particular, the reaction of 1 shows greater contrast in index of refraction than that of the Dewar benzene parent system. 相似文献
133.
An important step in predicting the effects of future increases in UV radiation (UVR) is to evaluate the mechanisms that organisms use to prevent and repair DNA damage and determine how those mechanisms influence UVR sensitivity. Damage is prevented to varying degrees through photoprotection and repaired via two main pathways: nucleotide excision repair and photoenzymatic repair. At present, little is known about the generality or similarity of these defenses among temperate freshwater fishes. We used laboratory experiments to compare UVR defense mechanisms among five freshwater fish species representing four families and three orders. Purified DNA, freeze-killed larvae and live larvae were exposed to UVB radiation for 12 h in the presence or absence of photorepair radiation. After exposure, we quantified frequencies of cyclobutane pyrimidine dimers in each exposure treatment. All five species used photoprotection and proportional decreases in dimer frequency were similar for all species. Evidence of excision repair was also found for all species but proportional decreases in photoproduct frequencies varied among species. Finally, evidence of photoenzymatic repair was found for only two of the five species. 相似文献
134.
A parallel algorithm for solving the coupled-perturbed MCSCF (CPMCSCF) equations and analytic nuclear second derivatives of CASSCF wave functions is presented. A parallel scheme for evaluating derivative integrals and their subsequent use in constructing other derivative quantities is described. The task of solving the CPMCSCF equations is approached using a parallelization scheme that partitions the electronic hessian matrix over all processors as opposed to simple partitioning of the 3 N solution vectors among the processors. The scalability of the current algorithm, up to 128 processors, is demonstrated. Using three test cases, results indicate that the parallelization of derivative integral evaluation through a simple scheme is highly effective regardless of the size of the basis set employed in the CASSCF energy calculation. Parallelization of the construction of the MCSCF electronic hessian during solution of the CPMCSCF equations varies quantitatively depending on the nature of the hessian itself, but is highly scalable in all cases. 相似文献
135.
High-fidelity large eddy simulation (LES) of a low-Atwood number (A = 0.05) Rayleigh–Taylor mixing layer is performed using the 10th-order compact difference code Miranda. An initial multimode perturbation spectrum is specified in Fourier space as a function of mesh resolution such that a database of results is obtained in which each successive level of increased grid resolution corresponds approximately to one additional doubling of the mixing layer width, or generation. The database is then analysed to determine approximate requirements for self-similarity, and a new metric is proposed to quantify how far a given simulation is from the limit of self-similarity. It is determined that mixing layer growth reaches a high degree of self-similarity after approximately 4.5 generations. Statistical convergence errors and boundary effects at late time, however, make it impossible to draw similar conclusions regarding the self-similar growth of more sensitive turbulence parameters. Finally, self-similar turbulence profiles from the LES database are compared with one-dimensional simulations using the k-L-a and BHR-2 Reynolds-averaged Navier–Stokes models. The k-L-a model, which is calibrated to reproduce a quadratic turbulence kinetic energy profile for a self-similar mixing layer, is found to be in better agreement with the LES than BHR-2 results. 相似文献
136.
Groenewold GS Appelhans AD Gresham GL Olson JE Jeffery M Weibel M 《Journal of the American Society for Mass Spectrometry》2000,11(1):69-77
The nerve agent VX (O-ethyl S-2-diisopropylaminoethyl methyl phosphonothiolate) was analyzed on the surface of concrete samples using an ion trap secondary ion mass spectrometer (IT-SIMS). It was found that VX could be detected down to an absolute quantity of 5 ng on a concrete chip, or to a surface coverage of 0.0004 monolayers on crushed concrete. To achieve these levels of detection, the m/z 268-->128 ion fragmentation was measured using MS2, where m/z 268 corresponds to [VX + H]+, and 128 corresponds to a diisopropylvinylammonium isomer, that is formed by the elimination of the phosphonothiolate moiety. Detection at these levels was accomplished by analyzing samples that had been recently exposed to VX, i.e., within an hour. When the VX-exposed concrete samples were aged, the SIMS signature for intact VX had disappeared, which signaled the degradation of the compound on the concrete surface. The VX signature was replaced by ions which are interpreted in terms of VX degradation products, which appear to be somewhat long lived on the concrete surface. These compounds include ethylmethylphosphonic acid (EMPA), diisopropyl taurine (DIPT), diisopropylaminoethanethiol (DESH), bis(diisopropylaminoethane) disulfide [(DES)2], and a particularly tenacious compound that may correspond to diisopropylvinylamine (DIVA), or an isomer thereof. It was found that the thiolamine-derived degradation products DIPT, DESH, and (DES)2 were removed with isopropyl alcohol extraction. However, the DIVA-related degradation product was observed to strongly adhere to the concrete surface for longer than one week. Although quantitation was not possible in this set of experiments, the results clearly show the rapid degradation of VX on concrete, as well as the surface sensitivity of the IT-SIMS for intact VX and its adsorptive degradation products. 相似文献
137.
Lucas BS Fisher B McGee LR Olson SH Medina JC Cheung E 《Journal of the American Chemical Society》2012,134(30):12855-12860
The development of the structurally complex MDM2/p53 inhibitor AM-8553 was impeded by the low yield of the initial synthesis. A second generation synthesis is described that features a Noyori dynamic kinetic resolution, a highly diastereoselective allylation, and a novel oxazoline-assisted piperidinone forming reaction to provide AM-8553 in 35.6% yield and 11 steps. 相似文献
138.
Randilynn Christensen Jennifer Byer Garrett Olson Steve W. Martin 《Journal of Non》2012,358(3):583-589
The mixed glass former effect (MGFE) is defined as a non-linear and non-additive change in the ionic conductivity with changing glass former fraction at constant modifier composition between two binary glass forming compositions. In this study, mixed glass former (MGF) sodium borophosphate glasses, 0.35 Na2O + 0.65 [xB2O3 + (1 ? x)P2O5], 0 ≤ x ≤ 1, which have been shown to have a strong positive MGFE, have been prepared and their physical properties, density and molar volume, have been examined as predictors of structural change. The density exhibits a strong positive non-linear and non-additive change in the density with x and a corresponding negative non-linear and non-additive change in the molar volume. In order to understand the structural origins of these changes, a model of the molar volume was created and best-fit to the experimentally determined molar volumes in order to determine the volumes of the short range order (SRO) structural units in these glasses, how these volume change from the molar volumes of the binary glasses, and how these volumes change across the range of x in the ternary glasses. The best-fit model was defined as the model that required the smallest changes in the volumes of the ternary phosphate and borate SRO structural groups from their values determined by the densities of the binary sodium phosphate and sodium borate glasses. In this best-fit molar volume model, it was found that the volumes of the various phosphate and borate SRO structural groups decreased by values ranging from a minimum value of ~ 1% for x = 0.1 and 0.9 to a maximum value of ~ 6% for the phosphate and ~ 9% for the borate SRO groups at the minimum in molar volume at x = 0.4. The free volume was found to have a negative deviation from linear which is unexpected given the positive deviation in ionic conductivity. 相似文献
139.
Randilynn Christensen Jennifer Byer Garrett Olson Steve W. Martin 《Journal of Non》2012,358(4):826-831
The mixed glass former effect (MGFE) is defined as the non-linear and non-additive change in the ionic conductivity with changing glass former fraction at constant modifier composition between two binary glass former compositions. In this study, sodium borophosphate glasses, 0.35Na2O + 0.65[xB2O3 + (1 ? x)P2O5] with 0 ≤ x ≤ 1, have been prepared and their glass transition temperatures (Tg) have been examined as an alternative indicator of the MGFE and as an indicator of changes in the short range order (SRO) structural network units that could cause or contribute to the MGFE. The changes in Tg show a positive non-additive and non-linear trend over the changing glass former fraction, x. The increase in Tg is related to the increasing number of bridging oxygens (BO) in the glass samples, which is caused by the increase in the number of tetrahedral boron, B4, units in the SRO structure. 相似文献
140.
Edison Osorio Dr. Jared K. Olson Prof. William Tiznado Prof. Alexander I. Boldyrev 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(31):9677-9681
We performed global minimum searches for the BnHn+2 (n=2‐5) series and found that classical structures composed of 2c–2e B? H and B? B bonds become progressively less stable along the series. Relative energies increase from 2.9 kcal mol?1 in B2H4 to 62.3 kcal mol?1 in B5H7. We believe this occurs because boron atoms in the studied molecules are trying to avoid sp2 hybridization and trigonal structure at the boron atoms, as in that case one 2p‐AO is empty, which is highly unfavorable. This affinity of boron to have some electron density on all 2p‐AOs and avoiding having one 2p‐AO empty is a main reason why classical structures are not the most stable configurations and why multicenter bonding is so important for the studied boron–hydride clusters as well as for pure boron clusters and boron compounds in general. 相似文献