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61.
Environment-friendly electric vehicles have gained popularity and increased attention in recent years. The deployment of a network of recharging stations is essential given their limited travel range. This paper considers the problem of locating electronic replenishment stations for electric vehicles on a traffic network with flow-based demand. The objective is to optimize the network performance, for example to maximize the flow covered by a prefixed number of stations or to minimize the number of stations needed to cover traffic flows. Two integer linear programming formulations are proposed to model the problem. These models are tested on real-life traffic data collected in Denmark.  相似文献   
62.
63.
Selective lipase-catalyzed acylation of 41-desmethoxyrapamycin has been achieved with a quaternary carboxylic acid avoiding the use of vinyl ester activation. Among the acyl donors investigated, the novel butanedione-monooxime and the N-acetylhydroxamate ester proved to be the most efficient donors, comparable in reactivity to the undesired vinyl ester and allowing selective, preparative acylation on gram scale in excellent yields. These new donors are proposed as sustainable and process-friendly alternatives to the widely used vinyl ester substrate activation in lipase-catalyzed acylations of secondary alcohols.  相似文献   
64.
A high temperature superconducting cable may be based on a centrally located cylindrical support, a so-called former. If electrically conductive, the former can contribute to the AC losses through eddy current losses caused by unbalanced axial and tangential magnetic fields. With these measurements we aim at investigating the eddy current losses of commonly used former materials. A one layer cable conductor was wound on a glass fibre reinforced polymer (GFRP) former. By inserting a variety of materials into this, it was possible to measure the eddy current losses of each of the former candidates separately; for example copper tubes, stainless steel braid, copper braid, corrugated stainless steel tubes, etc. The measured data are compared with the predictions of a theoretical model. Our results show that in most cases, the losses induced by eddy currents in the former are negligible. However, for materials with a low resistivity the eddy current losses may become significant, e.g., for high purity Cu or Al.  相似文献   
65.
We report on the determination of the mineralogy of the atmospherically suspended Martian dust particles using backscattering 57Fe Mössbauer spectroscopy on dust accumulated onto the magnets onboard the Mars Exploration Rovers. The spectra can be interpreted in terms of minerals of igneous origin, and shows only limited, if any, amounts of secondary minerals that may have formed in the presence of liquid water. These findings suggest that the dust has formed in a dry environment over long time in the history of the planet.  相似文献   
66.
One of the major issues within the context of the fully automated development of chromatographic methods consists of the automated detection and identification of peaks coming from complex samples such as multi-component pharmaceutical formulations or stability studies of these formulations. The same problem can also occur with plant materials or biological matrices. This step is thus critical and time-consuming, especially when a Design of Experiments (DOE) approach is used to generate chromatograms. The use of DOE will often maximize the changes of the analytical conditions in order to explore an experimental domain. Unfortunately, this generally provides very different and “unpredictable” chromatograms which can be difficult to interpret, thus complicating peak detection and peak tracking (i.e. matching peaks among all the chromatograms). In this context, Independent Components Analysis (ICA), a new statistically based signal processing methods was investigated to solve this problem. The ICA principle assumes that the observed signal is the resultant of several phenomena (known as sources) and that all these sources are statistically independent. Under those assumptions, ICA is able to recover the sources which will have a high probability of representing the constitutive components of a chromatogram. In the present study, ICA was successfully applied for the first time to HPLC–UV-DAD chromatograms and it was shown that ICA allows differentiation of noise and artifact components from those of interest by applying clustering methods based on high-order statistics computed on these components. Furthermore, on the basis of the described numerical strategy, it was also possible to reconstruct a cleaned chromatogram with minimum influence of noise and baseline artifacts. This can present a significant advance towards the objective of providing helpful tools for the automated development of liquid chromatography (LC) methods. It seems that analytical investigations could be shortened when using this type of methodologies.  相似文献   
67.
A theoretical model for how Bloch walls occurring in in-plane magnetized ferrite garnet films can serve as efficient magnetic micromanipulators is presented. As an example, the walls' interaction with Abrikosov vortices in a superconductor in close contact with a garnet film is analyzed within the London approximation. The model explains how vortices are attracted to such walls, and excellent quantitative agreement is obtained for the resulting peaked flux profile determined experimentally in NbSe(2) using high-resolution magneto-optical imaging of vortices. In particular, this model, when generalized to include charged magnetic walls, explains the counterintuitive attraction observed between vortices and a Bloch wall of opposite polarity.  相似文献   
68.
A small library of thirty‐two 2′‐triazolyl uridine and 2′‐triazolyl‐5‐methyluridine has been synthesized by Cu(I)‐catalyzed condensation of 2′‐azido‐2′‐deoxyuridine and 2′‐azido‐2′‐deoxy‐5‐methyluridine with different alkynes and aryl propargyl ethers in almost quantitative yields. Triazolo‐nucleoside conjugates, which can be evaluated for different biological activity for suitable drug development, were unambiguously identified on the basis of 1H NMR, 13C NMR, IR, and HRMS data analysis. These compounds have been synthesized for the first time and have not been reported in the literature earlier.  相似文献   
69.
Thermodynamics is developed for a class of thermo-hypo-elastic materials. It is shown that materials of this class obey the laws of thermodynamics, but are not elastic.

Table of Symbols

Latin Letters A ijkl tensor-valued function of t ij appearing in hypo-elastic constitutive relation - B ijkl another tensor-valued function. See equation (4.2) - B the square of - d ij rate of deformation tensor - d ij deviator of rate of deformation - f, k functions of pressure, p - g, h functions of the invariant - p pressure - q i heat flux vector - s ij stress deviator - ij co-rotational derivative of stress deviator - t time - t 1 t 2 specific values of time - t ij stress tensor - t ij 0 a specific value of stress - T Temperature - T 0 a specific value of temperature - u i velocity - V(t) a material volume as a function of time, t - V 0 a material volume at a reference configuration - W work (W = work done in a deformation—section 5) Sript Letters Specific internal energy - Specific Helmholtz free energy - G Specific Gibbs function Greek Letters an invariant of the stress deviator—see eq. (2.4) - ij kroneker delta - (W = work done in a deformation—section 5) - specific entropy - hypo-elastic potential - hypo-elastic potential - mass density - 0 mass density in a reference configuration - specific volume = 1/ - a function of p - ijkl a constant tensor—see eq. (2.5) - G/ - ij rate of rotation tensor This work is dedicated to Jerald L. Ericksen, without whose influence it would not have been possible  相似文献   
70.
In this study, we have applied two different spanning protocols for obtaining the molecular conformations of L-tryptophan in aqueous solution, namely a molecular dynamics simulation and a molecular mechanics conformational search with subsequent geometry re-optimization of the stable conformers using a quantum mechanically based method. These spanning protocols represent standard ways of obtaining a set of conformations on which NMR calculations may be performed. The results stemming from the solute-solvent configurations extracted from the MD simulation at 300 K are found to be inferior to the results stemming from the conformations extracted from the MM conformational search in terms of replicating an experimental reference as well as in achieving the correct sequence of the NMR relative chemical shifts of L-tryptophan in aqueous solution. We find this to be due to missing conformations visited during the molecular dynamics run as well as inaccuracies in geometrical parameters generated from the classical molecular dynamics simulations.  相似文献   
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