首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   334篇
  免费   9篇
化学   258篇
晶体学   2篇
力学   2篇
数学   56篇
物理学   25篇
  2024年   1篇
  2023年   3篇
  2022年   16篇
  2021年   24篇
  2020年   15篇
  2019年   14篇
  2018年   10篇
  2017年   9篇
  2016年   9篇
  2015年   15篇
  2014年   13篇
  2013年   14篇
  2012年   24篇
  2011年   19篇
  2010年   11篇
  2009年   15篇
  2008年   14篇
  2007年   28篇
  2006年   17篇
  2005年   15篇
  2004年   12篇
  2003年   7篇
  2002年   9篇
  2001年   2篇
  2000年   1篇
  1999年   3篇
  1998年   4篇
  1997年   1篇
  1996年   2篇
  1995年   2篇
  1994年   2篇
  1992年   2篇
  1990年   2篇
  1985年   1篇
  1980年   1篇
  1979年   2篇
  1977年   1篇
  1976年   1篇
  1974年   1篇
  1965年   1篇
排序方式: 共有343条查询结果,搜索用时 0 毫秒
51.
Financial advisers have developed standardized payout strategies to help Baby Boomers manage their money in their golden years. Prominent among these are phased withdrawal plans offered by mutual funds including the “self-annuitization” or default rules encouraged under US tax law, and fixed payout annuities offered by insurers. Using a utility-based framework, and taking account of stochastic capital markets and uncertain lifetimes, we first evaluate these rules on a stand-alone basis for a wide range of risk aversion. Next, we permit the consumer to integrate these standardized payout strategies at retirement and compare the results. We show that integrated strategies can enhance retirees’ well-being by 25%-50% for low/moderate levels of risk aversion when compared to full annuitization at retirement. Finally, we examine how welfare changes if the consumer is permitted to switch to a fixed annuity at an optimal point after retirement. This affords the retiree the chance to benefit from the equity premium when younger, and exploit the mortality credit in later life. For moderately risk-averse retirees, the optimal switching age lies between 80 and 85.  相似文献   
52.
We present a topos-theoretic interpretation of (a categorical generalization of) Fraïssé’s construction in Model Theory, with applications to homogeneous models and countably categorical theories.  相似文献   
53.
We establish a general method for generating reflections between categories. We then apply our technique to generate adjunctions starting from geometric morphisms between Grothendieck toposes; as particular cases, we recover various well-known Stone-type adjunctions and establish several new ones.  相似文献   
54.
Journal of Solid State Electrochemistry - The aim of this work was to study the effect of a RuO2 support on the activity of Pd nanoparticles for formic acid oxidation, comparing the results with...  相似文献   
55.
56.
In 2007, Andrews and Paule introduced the notion of broken k-diamond partitions. Let \(\Delta _k(n)\) denote the number of broken k-diamond partitions of n for a fixed positive integer k. Recently, Paule and Radu presented some conjectures on congruences modulo 7 for \(\Delta _3(n)\) which were proved by Jameson and Xiong based on the theory of modular forms. Very recently, Xia proved several infinite families of congruences modulo 7 for \(\Delta _3(n)\) using theta function identities. In this paper, many new infinite families of congruences modulo 7 for \(\Delta _3(n)\) are derived based on an identity of Newman and the (pk)-parametrization of theta functions due to Alaca, Alaca and Williams. In particular, some non-standard congruences modulo 7 for \(\Delta _3(n)\) are deduced. For example, we prove that for \(\alpha \ge 0\), \(\Delta _3\left( \frac{14\times 757^{\alpha }+1}{3}\right) \equiv 6 -\alpha \ (\mathrm{mod}\ 7)\).  相似文献   
57.
Similarities and differences of halogen and hydrogen bonding were explored via UV–Vis and 1H NMR measurements, X-ray crystallography and computational analysis of the associations of CHX3 (X=I, Br, Cl) with aromatic (tetramethyl-p-phenylenediamine) and aliphatic (4-diazabicyclo[2,2,2]octane) amines. When the polarization of haloforms was taken into account, the strengths of these complexes followed the same correlation with the electrostatic potentials on the surfaces of the interacting atoms. However, their spectral properties were quite distinct. While the halogen-bonded complexes showed new intense absorption bands in the UV–Vis spectra, the absorptions of their hydrogen-bonded analogues were close to the superposition of the absorption of reactants. Additionally, halogen bonding led to a shift in the NMR signal of haloform protons to lower ppm values compared with the individual haloforms, whereas hydrogen bonding of CHX3 with aliphatic amines resulted in a shift in the opposite direction. The effects of hydrogen bonding with aromatic amines on the NMR spectra of haloforms were ambivalent. Titration of all CHX3 with these nucleophiles produced consistent shifts in their protons’ signals to lower ppm values, whereas calculations of these pairs produced multiple hydrogen-bonded minima with similar structures and energies, but opposite directions of the NMR signals’ shifts. Experimental and computational data were used for the evaluation of formation constants of some halogen- and hydrogen-bonded complexes between haloforms and amines co-existing in solutions.  相似文献   
58.
Let \(\mathcal {U}=\{U(t,s)\}_{t\ge s\ge 0}\) be a strongly continuous and exponentially bounded evolution family acting on a complex Banach space X and let \(\mathcal {X}\) be a certain Banach function space of X-valued functions. We prove that the growth bound of the family \(\mathcal {U}\) is less than or equal to \(-\frac{1}{c(\mathcal {U}, \mathcal {X})}\) provided that the convolution operator \(f\mapsto \mathcal {U}*f\) acts on \(\mathcal {X}.\) It is well known that under the latter assumption, the convolution operator is bounded and then \(c(\mathcal {U}, \mathcal {X})\) denotes (ad-hoc) its norm in \(\mathcal {L}(\mathcal {X}).\) As a consequence, we prove that if \(\sup \nolimits _{s\ge 0}\int \nolimits _{s}^\infty \Vert U(t,s)\Vert dt=u_1(\mathcal {U})<\infty ,\) then \(\omega _0(\mathcal {U})u_1(\mathcal {U})\le -1.\) Finally, we give an example showing that the accuracy of the estimates may be quite accurate.  相似文献   
59.
In order to preserve and restore the Imperial Gates from the Petrindu wooden church, Salaj County, Romania, (map location—latitude, longitude: 46.97, 23.19), the scientific investigation of the wooden support and painting materials (ground and pigments) was performed, employing Fourier‐transform infrared spectroscopy (FTIR), X‐ray fluorescence spectroscopy, and 3D scanning. FTIR spectroscopy offered information about the wooden degradation stage, whereas X‐ray fluorescence and FTIR spectroscopic methods were employed for structural painting materials characterization. The structural data can be correlated with the artistic, theological, and historical analysis of this religious patrimony object. After obtaining information about the wooden support and painting materials, the Imperial Gates were 3D digitized using state of the art laser scanning technology. The digital 3D model obtained was restored in a virtual environment and converted into an interactive 3D model that can be used for Romanian cultural heritage digital dissemination.  相似文献   
60.
In this paper, we show that the strong perfect graph conjecture holds for a new class of graphs which we call diamonded odd cycle-free graphs. The class of diamonded odd cycle-free graphs contains the classes of threshold graphs and K4\e-free graphs.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号