全文获取类型
收费全文 | 3596篇 |
免费 | 165篇 |
国内免费 | 17篇 |
专业分类
化学 | 2713篇 |
晶体学 | 30篇 |
力学 | 95篇 |
综合类 | 1篇 |
数学 | 492篇 |
物理学 | 447篇 |
出版年
2023年 | 39篇 |
2022年 | 38篇 |
2021年 | 56篇 |
2020年 | 86篇 |
2019年 | 73篇 |
2018年 | 44篇 |
2017年 | 40篇 |
2016年 | 136篇 |
2015年 | 125篇 |
2014年 | 140篇 |
2013年 | 181篇 |
2012年 | 234篇 |
2011年 | 278篇 |
2010年 | 165篇 |
2009年 | 135篇 |
2008年 | 216篇 |
2007年 | 220篇 |
2006年 | 209篇 |
2005年 | 183篇 |
2004年 | 159篇 |
2003年 | 121篇 |
2002年 | 139篇 |
2001年 | 78篇 |
2000年 | 75篇 |
1999年 | 63篇 |
1998年 | 45篇 |
1997年 | 31篇 |
1996年 | 30篇 |
1995年 | 40篇 |
1994年 | 35篇 |
1993年 | 27篇 |
1992年 | 24篇 |
1991年 | 39篇 |
1990年 | 32篇 |
1989年 | 27篇 |
1988年 | 6篇 |
1987年 | 16篇 |
1986年 | 6篇 |
1985年 | 13篇 |
1984年 | 12篇 |
1983年 | 13篇 |
1982年 | 10篇 |
1980年 | 18篇 |
1979年 | 10篇 |
1978年 | 9篇 |
1977年 | 23篇 |
1976年 | 8篇 |
1975年 | 10篇 |
1974年 | 9篇 |
1972年 | 8篇 |
排序方式: 共有3778条查询结果,搜索用时 15 毫秒
51.
52.
Using the nonrenormalization theorem and Pohlmeyer's theorem, it is proven that there cannot be an asymptotic safety scenario for the Wess–Zumino model unless there exists a non-trivial fixed point with (i) a negative anomalous dimension (ii) a relevant direction belonging to the Kähler potential. 相似文献
53.
Soft robots are bio-inspired, highly deformable robots with the ability to interact with workpieces in a manner that complements their hard robot counterparts. To develop practical applications and reproducible designs of soft robots, new models are necessary to describe their kinematics and dynamics. In the present work, we describe experimental and numerical investigations of a popular pneumatically-actuated soft continuum arm. These works enable us to derive constitutive relations and develop a rod model for large deformations of the arm that faithfully describes its bending behavior. We show how the resulting non-classical constitutive relation can be defined either through experiments or through quasi-static finite element simulations. With the help of this relation, the resulting rod model can be used to study the dynamics of the soft robot arm in a fast and tractable manner. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
54.
55.
Andreas Petri Oliver SeidelmannUwe Eilitz Frank LeßmannStefan Reißmann Volkmar WendischAndrey Gutnov 《Tetrahedron letters》2014
Asymmetric conjugate addition of arylboronic acids to 2-nitroacrylamide in the presence of cationic palladium–Chiraphos complex proceeds with high yield and enantioselectivity (73–89% ee) using as low as 0.05–0.25 mol % of the catalyst. The adducts can be smoothly transformed into the corresponding β2-homophenylglycines in two simple steps. 相似文献
56.
57.
Peter Fechner Oliver Bleher Melanie Ewald Kathrin Freudenberger Dominik Furin Urs Hilbig Felix Kolarov Katrin Krieg Lothar Leidner Goran Markovic Günther Proll Florian Pröll Sabrina Rau Johannes Riedt Barbara Schwarz Patricia Weber Julia Widmaier 《Analytical and bioanalytical chemistry》2014,406(17):4033-4051
This review is focused on methods for detecting small molecules and, in particular, the characterisation of their interaction with natural proteins (e.g. receptors, ion channels). Because there are intrinsic advantages to using label-free methods over labelled methods (e.g. fluorescence, radioactivity), this review only covers label-free techniques. We briefly discuss available techniques and their advantages and disadvantages, especially as related to investigating the interaction between small molecules and proteins. The reviewed techniques include well-known and widely used standard analytical methods (e.g. HPLC-MS, NMR, calorimetry, and X-ray diffraction), newer and more specialised analytical methods (e.g. biosensors), biological systems (e.g. cell lines and animal models), and in-silico approaches. 相似文献
58.
Oliver Neudert Miriam Reh Hans W. Spiess Kerstin Münnemann 《Macromolecular rapid communications》2015,36(10):885-889
NMR studies of synthetic polymers and biomacromolecules, which provide insight into the conformation and dynamics of these materials, can benefit strongly from the increased sensitivity offered by dynamic nuclear polarization (DNP) and other hyperpolarizing methods. In this study 1H DNP nuclear spin hyperpolarization of two polybutadiene samples, representing a supercooled liquid and an entangled polymer melt, is demonstrated at 0.35 T magnetic field strength and at temperatures between −80 and +50 °C. Electron spin polarization transfer from the α,γ‐bisdiphenylene‐β‐phenylallyl radical to the sample nuclei is achieved by the Overhauser and solid effect. DNP signal enhancements are studied, varying the electron spin resonance offset, microwave power, and sample temperature. The influence of spin relaxation times, line widths, and molecular dynamics are discussed. The results show promising, up to 15‐fold NMR signal enhancements using noncryogenic temperatures and an inexpensive setup that is less technically demanding than current high‐field DNP setups.
59.
Dr. Jan Keuter Maria Dimitrova Dr. Oliver Janka Dr. Alexander Hepp Priv. Doz. Dr. Raphael J. F. Berger Dr. Felicitas Lips 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(45):e202201473
The silanide [Si4{N(SiMe3)Dipp}3]− ( 1 ) transforms into the anionic siliconoid cluster [Si7{N(SiMe3)Dipp}3]− ( 2 ) with four unsubstituted silicon atoms as a contact ion pair with [K([18]crown-6)] in C6D6 at room temperature within five weeks. Anion 2 was investigated by natural population analysis and visualization of intrinsic atomic orbitals. Magnetically induced current-density calculations of 2 revealed two distinct strong diatropic vortices that sum up in one direction and create a strongly shielded apical silicon atom in 2 . 相似文献
60.
We study the mode solution to the Cauchy problem of the scalar wave equation □φ = 0 in Kasner spacetimes. As a first result, we give the explicit mode solution in axisymmetric Kasner spacetimes, of which flat Kasner spacetimes are special cases. Furthermore, we give the small and large time asymptotics of the modes in general Kasner spacetimes. Generically, the modes in non-flat Kasner spacetimes grow logarithmically for small times, while the modes in flat Kasner spacetimes stay bounded for small times. For large times, however, the modes in general Kasner spacetimes oscillate with a polynomially decreasing amplitude. This gives a notion of large time frequency of the modes, which we use to model the wavelength of light rays in Kasner spacetimes. We show that the redshift one obtains in this way actually coincides with the usual cosmological redshift. 相似文献