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131.
Bauer RE Enkelmann V Wiesler UM Berresheim AJ Müllen K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(17):3858-3864
A series of first-generation polyphenylene dendrimers based on three different cores were prepared by Diels-Alder cycloaddition and their single-crystal structures were determined. Consisting exclusively of interlocked, twisted phenyl rings, these polyphenylene nanostructures have exciting structural and dynamic properties. Single crystals of dendrimers, suitable for X-ray structure analysis, were grown from different solvent mixtures by slow evaporation at room temperature. It should be pointed out that one of the described polyphenylene dendrimers represents up to now the biggest oligophenylene nanostructure from which crystallographic data is available. 相似文献
132.
The attachment of single ions to putative adsorption sites in the tails of collagen fibers is investigated by means of molecular dynamics simulations and discussed with respect to the very early steps of apatite/collagen biomineral formation. Our studies clearly demonstrate an increased flexibility of the tails of the triple‐helical collagen protein. Apart from the termini of the backbone, several side chains were also observed to be freely accessible to ion attachment from aqueous solution. The teleopeptide was systematically scanned for suitable adsorption sites for calcium, phosphate and fluoride ions. Association of these ions was then explored from potential of mean force calculations. The resulting energy profiles reveal a variety of favorable protein‐ion bonds and hint at the suitability of the collagen tails to promote apatite aggregation. 相似文献
133.
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135.
An infrared spectral investigation of a number of pyrimidine and pyrimidone hexachloroantimonates is reported. Typical aromatic absorption bands found in pyrimidinium salts were absent in the pyrimidone cations. 2-And 4-Pyrimidone hexachloroantimonates, as well as their N-methyl- and N,N'-dimethyl derivatives, exhibit intense carbonyl absorption bands between 1720–1729 cm?1 (solid state) which corroborates N-protonation of pyrimidones. 相似文献
136.
H. Bauer 《Fresenius' Journal of Analytical Chemistry》1962,191(3):205
Ohne Zusammenfassung 相似文献
137.
Joachim Angelkort Sander van Smaalen Prof. Dr. Sven Oliver Hauber Mark Niemeyer 《无机化学与普通化学杂志》2007,633(7):1031-1035
Single crystal X‐ray diffraction of Eu(SC36H49)2 has revealed a first order phase transition at a temperature of 119 K, that involves a reduction of the specific volume by 1 %. The transition corresponds to a doubling of the unit cell, as it is the result from reorientations of isopropyl groups that appear at peripheral sites of the organic ligands. It is argued that a denser packing is achieved at the expense of a less favourable conformation of one of the two crystallographically‐independent complexes in the low‐temperature phase. The Bond‐Valence method is used to show that interactions of equal strengths are present between europium and both sulphur atoms and both coordinating phenyl rings. 相似文献
138.
Maurer HH Tenberken O Kratzsch C Weber AA Peters FT 《Journal of chromatography. A》2004,1058(1-2):169-181
A liquid chromatographic-mass spectrometric assay with atmospheric pressure chemical ionization (LC-APCI-MS) is presented for screening for, library-assisted identification (both in scan mode) and quantification (selected-ion mode) of the beta-blockers acebutolol, diacetolol, alprenolol, atenolol, betaxolol, bisoprolol, bupranolol, carazolol, carteolol, carvedilol, celiprolol, esmolol, labetalol, metoprolol, nadolol, nebivolol, oxprenolol, penbutolol, propranolol, sotalol, talinolol and timolol in blood plasma after mixed-mode (HCX) solid-phase extraction (SPE) and separation by reverse-phase liquid chromatography with gradient elution. The validation data were within the required limits. The assay was successfully applied to authentic plasma samples allowing confirmation of diagnosis of overdose situations as well as monitoring of patients' compliance. 相似文献
139.
The complexing ligand EDTA can be determined as its complex with bismuth by indirect anodic stripping voltammetry down to 0.1 μg/L without a concentration step. Interfering copper and excess bismuth have to be removed by cation exchange, although in presence of these metals EDTA can be determined down to 0.5 μg/L only. If NTA, EDTA, and DTPA are present simultaneously, the accumulation curves for the corresponding bismuth-complexes can overlap, preventing a separate determination of the three chelons. Due to the interaction of NTA and DTPA with soil normally only EDTA is present in ground-waters. Similarly, EDTA also dominates in surface-waters. Thus it seems to be sufficient to determine the sum of the three chelons as EDTA (index of bismuth-complexation) using suitable electrochemical conditions. 相似文献
140.
Molt O Rübeling D Schäfer G Schrader T 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(17):4225-4232
Host molecule 1 displays a high affinity in water towards catecholamines and especially related structures such as beta-blockers with extended aromatic pi-faces (up to 7x10(3) M(-1) for each single complexation step or 5x10(7) M(-2) for both steps). The amphiphilic structural design leads to an extensive self-association of host molecules through their aromatic flanks. Above a cmc (critical micelle concentration) of 3x10(-4) M, host 1 forms micelles that produce a favorable microenvironment for hydrophobic interactions with the included guest molecules. Electrostatic attraction of the ammonium alcohol by the phosphonate anions is thus combined with hydrophobic contributions between the aromatic moieties. Ionic hydrogen bonds with polar OH or NH groups of the guest enforce the non-covalent interactions, and finally lead to increased specificity. Both its affinity and its selectivity towards adrenergic receptor substrates are greatly enhanced if the receptor molecule 1 is transferred from water into a lipid monolayer. Catecholamines and beta-blockers lead to drastically different effects at concentrations approaching the micromolar regime. Especially beta-blockers with minute structural changes can be easily distinguished from each other. In both cases, extensive hydrophobic interactions with a self-associated and/or self-organized microenvironment are largely responsible for the observed high efficiency and specificity. 相似文献