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11.
The stoichiometric reactions of trimethylaluminum with 2,6‐(MeOCH2)2C6H3OH (LH) revealed compounds L3Al ( 1 ) and L2AlMe ( 2 ). On the other hand reaction of 1 equiv. of LH with trimethylaluminum did not lead to the formation of complex LAlMe2 ( 3 ), rather 2 together with Me3Al were observed as a result of a disproportionation of 3 . Compounds 1 and 2 were characterized by elemental analysis, 1H and 13C NMR spectroscopy and in the case of 1 by X‐ray diffraction. Derivative 2 underwent transmetalation with Ph3SnOH, giving LSnPh3 ( 4 ) as the result of a migration of ligand L from the aluminum to the tin atom. The identity of 4 was established by elemental analysis, 1H, 13C and 119Sn NMR spectroscopy and 1H, 119Sn HMBC experiments. The system 2 and B(C6F5)3 in a 1:1 molar ratio was shown to be active in the polymerization of propylene oxide and ε‐caprolactone. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
12.
I. R. Gulamov A. A. Karakhodzhaev A. M. Mukhamedzhanov G. K. Nie E. A. Pak R. Yarmukhamedov V. Burjan J. Cejpek V. Kroha J. Křemének M. Kurka 《Czechoslovak Journal of Physics》1990,40(8):875-894
The angular distributions of the (p, d), (d, t) and(3He, ) reactions on13C have been analysed within the framework of DWBA in which additional information on nuclear vertex constants was introduced. Although all these reactions seem to be similar single nucleon transfer, their mechanism is shown to be quite different and so is the information extracted thereof. While from the (p, d) reactions spectroscopic factors may be extracted unambiguously, from the (d, t) reactions it is possible to obtain directly the values of vertex constants only, which in turn are consistent with those determined by extrapolation of the experimental cross sections of the (p, d) reactions to the pole.In the case of (3He, ) reactions, however, the analysis indicates inadequacy of the DWBA concerning the calculations of central partial amplitudes. For a more reliable extraction of structural information, besides the correct normalization of peripheral amplitudes, a contribution of more complex mechanisms must be taken into account. 相似文献
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Mariano Giaquinta Giuseppe Modica Jiří souček 《Archive for Rational Mechanics and Analysis》1989,106(2):97-159
Summary In this paper we introduce some new classes of functions, among these a class of weak diffeomorphisms. In these classes we prove by direct methods the existence of minimizers for several kinds of variational integrals. In particular, we prove the existence of one-to-one orientation-preserving maps that minimize suitable energies associated with hyperelastic materials. The minimizers are also proved to satisfy equilibrium equations. Finally radial deformations are discussed in connection with cavitation. 相似文献
15.
Linear mode conversion of waves near the maxima or minima of the density in a warm magnetized plasma
Behaviour of the h. f. electrostatic waves near the plasma or upper hybrid resonances was studied in the case that these resonances are situated at the maxima or minima of the plasma density. Supposing the parabolic density profile in these regions we obtained the connection formulae for the WKB solutions. In a weakly inhomogeneous magnetoplasma the effect of the parabolic profile manifests itself only in narrow frequency band centred at the resonance frequency corresponding to the extreme value of the density. The whole process can be then described by only two coefficients, viz. the power conversion and power transmission coefficients. 相似文献
16.
S. Vepřek 《Plasma Chemistry and Plasma Processing》1992,12(3):219-235
Impurity release from the first wall and components facing the hot plasma in Tokamak devices for controlled fusion research and the concomitant pollution of the plasma lead to enhanced energy losses and deuterium-tritium luel dilution. Both these effects can prevent reaching the ignition conditions. The recently developed technique for large areain situ deposition of boron carbide protective coatings by means of plasma-induced chemical vapor deposition enables one to significantly improve the purity of the fusion plasma. The prospects of approaching the scientific break-even in the large machines of the Tokarnak type has been increased.Extended version of an invited paper presented at the 10th International Symposium on Boron, Borides, and Related Compounds, Albuquerque, New Mexico, August 1990.The term Tokarnak is an abbreviation of the Russian name toroidal magnetic chamber. 相似文献
17.
The service life of ABS polymer, stabilized by 2-(3,5-di-tert-butyl-4-hydroxyanilino)-4,6-bis(octylthio)-1,3,5-triazine and containing 50% of a modifying rubber component, was estimated from oxidative induction times measured by DSC in isothermal mode in the temperature interval 140–170°C. The lifetime of ABS powder at the actual temperature of drying was predicted by linear extrapolation according to Arrhenius. However, the extrapolated value was much longer than the real lifetime determined from the long-term oven aging tests at 70 and 90°C, simulating the industrial drying process. The effect of changes in the apparent activation energy of oxidation due to antioxidant consumption during polymer aging is discussed. 相似文献
18.
The stochastic theory of the crystal growth is compared with the solution of the Stefan problem in the case of Sn solidification. It is shown that the stochastic theory gives the same results as the solution of the Stefan problem if kinetic processes at the solidification front are very rapid. 相似文献
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