全文获取类型
收费全文 | 326篇 |
免费 | 12篇 |
专业分类
化学 | 250篇 |
晶体学 | 13篇 |
力学 | 3篇 |
数学 | 30篇 |
物理学 | 42篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 9篇 |
2021年 | 19篇 |
2020年 | 8篇 |
2019年 | 10篇 |
2018年 | 12篇 |
2017年 | 8篇 |
2016年 | 14篇 |
2015年 | 7篇 |
2014年 | 14篇 |
2013年 | 29篇 |
2012年 | 30篇 |
2011年 | 26篇 |
2010年 | 27篇 |
2009年 | 10篇 |
2008年 | 20篇 |
2007年 | 16篇 |
2006年 | 13篇 |
2005年 | 20篇 |
2004年 | 12篇 |
2003年 | 9篇 |
2002年 | 4篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1990年 | 2篇 |
1983年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有338条查询结果,搜索用时 171 毫秒
11.
Dr. Volodymyr Sashuk Dr. Oksana Danylyuk 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(19):6528-6531
A ruthenium carbene complex bearing azobenzene functionality is reported. The complex exists in the form of two isomers differing by the size of the chelate ring. Both isomers were isolated by applying kinetic or thermodynamic control during the synthesis and characterized by X‐ray diffraction analysis. The isomerization of the complex was studied by UV/Vis spectroscopy. The stable isomer was tested as a catalyst in olefin metathesis. The complex was activated at about 100 °C to promote ring‐closing and ring‐opening polymerization metathesis reactions. The activation took place also at room temperature under middle ultraviolet radiation. 相似文献
12.
Journal of Solid State Electrochemistry - Recent scientific data in respect of the different effect of citric acid on antioxidant activity of plant polyphenols in pure solutions (no polyphenol... 相似文献
13.
The characteristics,performance and application of membrane sensors based on ion-pair Brilliant Green mefenamate are described.The sensor’s response to the mefenamate ion has the sensitivity of (86.0±2.0) mV/pC over the range of 9×10-5-1×10-2moI/Land the detection limit of 4.5×10-5mol/L at pH 8.5-12.The sensor is easily assembled at a relatively low cost and has fast response time(5-10 s).The proposed sensor displayed good selectivity for mefenamate ion in the presence of different substances.It was used to determine mefenamic acid in pharmaceuticals. 相似文献
14.
15.
Application of Non‐Stop‐Flow Differential Pulse Voltammetry at a Tubular Detector of Silver Solid Amalgam for Electrochemical Determination of Lomustine (CCNU)
下载免费PDF全文
![点击此处可从《Electroanalysis》网站下载免费的PDF全文](/ch/ext_images/free.gif)
An application of the flow differential pulse voltammetry with tubular detector based on silver solid amalgam for determination of antineoplastic drug lomustine in pharmaceutical preparations is presented. The highest sensitivity was obtained in [0.10 mol dm?3 MES; 2.00 mol dm?3 NaCl; pH 6.0]:EtOH (9 : 1) with flow rate 0.50 mL min?1, and the magnitude of the modulation amplitude ?0.070 V. The calibration dependence was linear in the range 1×10?6–1 × 10?4 mol dm?3 (R2=0.999). The limit of detection was 1.5×10?7 mol dm?3. This method was successfully used for determination of lomustine in real samples of chemotherapy drug CeeNU Lomustine 40 mg. 相似文献
16.
Electrochemical Biosensors Based on Enzymatic Reactor of Silver Solid Amalgam Powder for Measurements in Flow Systems
下载免费PDF全文
![点击此处可从《Electroanalysis》网站下载免费的PDF全文](/ch/ext_images/free.gif)
An enzymatic reactor based on silver solid amalgam powder was suggested as the main part of biosensors in flow systems for the first time. Biosensors were tested with following enzymes: ascorbate oxidase, glucose oxidase, catalase, tyrosinase and laccase. The current response of each biosensor was optimized with respect to the detection potential, flow rate, the injection and reactor volume. Relative standard deviation for detection with the studied enzymes was found to be in the range of 0.81–2.1 %. The biosensor with the ascorbate oxidase reactor was used for determination of ascorbic acid in the vitamin tablets Celaskon. 相似文献
17.
Ruslan I. Vaskevych Alla I. Vaskevych Eduard B. Rusanov Oksana Ya. Mel'nyk Mykhailo V. Vovk 《Journal of heterocyclic chemistry》2020,57(8):3202-3212
Selective iodocyclization of 6-(alkenylamino)-1-allylpyrazolo[3,4-d]pyrimidines provided hydrogenated derivatives of 1-allyl-8(9)-iodomethylimidazo(pyrimido)[1,2-a]pyrazolo[4,3-e]pyrimidines which were further reacted with NaN3 at 75°С to 80°С to give a series of new-type 1,3,6-triazocines annulated with the pyrazole, pyrimidine, imidazole (or pyrimidine), and 1,2,3-triazole rings. The compounds synthesized were structurally characterized by analytical, spectral (IR, 1H and 13C NMR, HPLC-mass), and X-ray diffraction data. 相似文献
18.
Mohammad Yasir Peng Liu Jens C. Markwart Oksana Suraeva Frederik R. Wurm Jansie Smart Marco Lattuada Andreas F. M. Kilbinger 《Angewandte Chemie (International ed. in English)》2020,59(32):13597-13601
Using a one‐step synthetic route for block copolymers avoids the repeated addition of monomers to the polymerization mixture, which can easily lead to contamination and, therefore, to the unwanted termination of chain growth. For this purpose, monomers ( M1 – M5 ) with different steric hindrances and different propagation rates are explored. Copolymerization of M1 (propagating rapidly) with M2 (propagating slowly), M1 with M3 (propagating extremely slowly) and M4 (propagating rapidly) with M5 (propagating slowly) yielded diblock‐like copolymers using Grubbs’ first ( G1 ) or third generation catalyst ( G3 ). The monomer consumption was followed by 1H NMR spectroscopy, which revealed vastly different reactivity ratios for M1 and M2 . In the case of M1 and M3 , we observed the highest difference in reactivity ratios (r1=324 and r2=0.003) ever reported for a copolymerization method. A triblock‐like copolymer was also synthesized using G3 by first allowing the consumption of the mixture of M1 and M2 and then adding M1 again. In addition, in order to measure the fast reaction rates of the G3 catalyst with M1 , we report a novel retardation technique based on an unusual reversible G3 Fischer‐carbene to G3 benzylidene/alkylidene transformation. 相似文献
19.
Christopher G. Hamaker Oksana S. Maryashina Dana K. Daley Andrew L. Wadler 《Journal of chemical crystallography》2010,40(1):34-39
Abstract
The crystal structures of the new compounds 5-bromo-N-[2-(methylthio)-phenyl]salicylaldimine (1), and 3,5-dichloro-N-[2-(methylthio)phenyl]salicylaldimine (2) were obtained by single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic space group P21/c with a = 14.1479(14) ?, b = 5.3058(3) ?, c = 19.104(3) ?; β = 106.218(10)°; and Z = 4. Compound 2 crystallizes in the triclinic space group $ P\bar{1} $ P\bar{1} with a = 11.2249(10) ?, b = 13.863(2) ?, c = 13.9055(9) ?; and α = 99.378(15)°, β = 102.866(7)°, γ = 91.375(11)°; and Z = 6. Details of the synthesis, structures, and spectroscopic properties of the new compounds are discussed. 相似文献20.