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A systematic investigation of the binding of cyclohexane derivatives to bisimidazolylcyclodextrine zinc was carried out. The basic host-guest interacti and the relative significance of polar and coordination interactions was estimated. 相似文献
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Iwao Sato 《Linear algebra and its applications》2011,435(5):943-952
Recently, Levine [9] expressed the vertex weighted complexity on spanning trees (with a fixed root) of the directed line graph of a digraph D in terms of the edge weighted complexity on spanning trees (with a fixed root) of D. We present new proofs for two Levine’s Theorems. Furthermore, we express the number of unicycles of the directed line graph of a digraph D in terms of the number of unicycles of D. 相似文献
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Masatoshi Shibuya Fabio Pichierri Masaki Tomizawa Shota Nagasawa Iwao Suzuki Yoshiharu Iwabuchi 《Tetrahedron letters》2012,53(16):2070-2073
We have developed azaadamantane-type nitroxyl radicals (AZADOs) and azabicyclo-type nitroxyl radicals (ABNOs) as highly active alcohol oxidation catalysts. Herein, the electrochemical properties of these nitroxyl radicals were investigated by measuring their formal potentials using cyclic voltammetry (CV). The redox potentials were rationalized with the aid of density functional theory (DFT) calculations. A good correlation between the experimental redox potential and the DFT-computed energy differences (ΔE) between nitroxyl radicals and oxoammonium species was obtained, which shows the effectiveness of DFT in predicting the redox potentials of nitroxyl radicals. Redox potential appears to be an important factor of catalytic activity. 相似文献
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Jordan MA Ojima I Rosas F Distefano M Wilson L Scambia G Ferlini C 《Chemistry & biology》2002,9(1):93-101
SB-T-1213 and IDN5109 are semisynthetic, orally available taxanes that are up to 400-fold more active than paclitaxel against drug-resistant cells. IDN5109 is in clinical trials. We investigated the primary target for SB-T-1213 and IDN5109 and whether the compounds interact with microtubules differently than paclitaxel. Unlike paclitaxel, at 1-10 microM both novel taxanes initiate microtubule polymerization in vitro with no lag. They enhance polymerization equally or more potently than paclitaxel. SB-T-1213 induces unusual microtubules with attached extra protofilaments or open sheets, and IDN5109 induces large protofilamentous sheets. Both inhibit HeLa cell proliferation, block mitosis at the metaphase/anaphase transition, bundle microtubules at high drug concentrations, and induce abnormal metaphase spindles and apoptosis. They target microtubules but alter their polymerization and structure differently than paclitaxel. These differences may play a role in their enhanced cytotoxicity and efficacy. 相似文献
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Kunihiko Yokoi Toru Ozeki Iwao Watanabe Shigero Ikeda 《Journal of Electroanalytical Chemistry》1982,133(1):73-78
Reduction mechanisms of polarographic reduction waves of Mo(VI) in 0.1–5 M sulfuric acid solutions are described. Three reduction waves are observed when the concentration of sulfuric acid is >3 M. From the results of coulometry and the catalytic behavior of Mo(V), it is concluded that three different reduction mechanisms of Mo(VI) to Mo(V) are present and that two separate reductions of Mo(VI) to Mo(V) and of Mo(V) to Mo(III) are involved at the potential of the third wave. The presence of three reduction mechanisms of Mo(VI) to Mo(V) in sulfuric acid α 3 M seems to indicate the existence of three different chemical species of Mo(VI). Two of these three species are different from the present in 0.1 M sulfuric acid. 相似文献