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171.
We have developed a new solid-media apparatus for performing rheological investigations at multi-gigapascal pressures. The pressure cell consists of a simple belt design and fits in a modified 250 tonne Paris–Edinburgh press. Elastic strains are measured by neutron diffraction, on the ENGIN-X experimental station at ISIS. Stresses are estimated from the measured strains in combination with published values of the elastic moduli. As an exemplair of the method, we present data from initial deformation experiments on pyrope garnet at 1.5 GPa and 873 K. Data collection times are as short as 60 min and the elastic strain resolution is better than 10?4. We anticipate, however, that by interrupted testing, strain rates as low as 10?9/s, or lower, will be measurable. 相似文献
172.
Georges Sauvet Witold Fortuniak Krzysztof Kazmierski Julian Chojnowski 《Journal of polymer science. Part A, Polymer chemistry》2003,41(19):2939-2948
Statistical and block all‐siloxane copolymers containing quaternary ammonium salt (QAS) groups with biocidal activity as lateral substituents were synthesized as models for the study of the effect of the arrangement of the QAS groups in the copolymer chain on their antimicrobial activity. The bioactive siloxane unit was [3‐n‐octyldimethylammoniopropyl]methylsiloxane, and the neutral unit was dimethylsiloxane. The copolymers also contained siloxane units with unreacted precursor 3‐chloropropyl or 3‐bromopropyl groups. A small number of units containing highly hydrophilic 3‐(3‐hydroxypropyl‐dimethylammonio)propyl groups were introduced to increase the solubility of the copolymers in water. The bioactive and bioneutral units were arranged in the polymer chain either in blocks or in statistical order. The block copolymers differed in the number and length of segments. The copolymers were obtained by the quaternization of tertiary amines by chloropropyl or bromopropyl groups attached to polysiloxane chains. The arrangement of the bioactive groups was controlled by the arrangement of the halogenopropyl groups in the bioactive copolymer precursor. All model siloxane copolymers showed high bactericidal activity in a water solution toward the gram‐negative bacteria Escherichia coli and the gram‐positive bacteria Staphylococcus aureus. However, no essential differences in the activities of the copolymers with block and statistical arrangements of units were detected. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2939–2948, 2003 相似文献
173.
n-C3H7ONO was photolyzed with 366 nm radiation at ?26, ?3, 23, 55, 88, and 120°C in a static system in the presence of NO, O2, and N2. The quantum yields of C2H5CHO, C2H5ONO, and CH3CHO were measured as a function of reaction conditions. The primary photochemical act is and it proceeds with a quantum yield ?1 = 0.38 ± 0.04 independent of temperature. The n-C3H7O radicals can react with NO by two routes The n-C3H7O radical can decompose via or react with O2 via Values of k4/k2 ? k4b/k2 were determined to be (2.0 ± 0.2) × 1014, (3.1 ± 0.6) × 1014, and (1.4 ± 0.1) × 1015 molec/cm3 at 55, 88, and 120°C, respectively, at 150-torr total pressure of N2. Values of k6/k2 were determined from ?26 to 88°C. They fit the Arrhenius expression: For k2 ? 4.4 × 10?11 cm3/s, k6 becomes (2.9 ± 1.7) × 10?13 exp{?(879 ± 117)/T} cm3/s. The reaction scheme also provides k4b/k6 = 1.58 × 1018 molec/cm3 at 120°C and k8a/k8 = 0.56 ± 0.24 independent of temperature, where 相似文献
174.
175.
The Casimir stress on a perfectly conducting uncharged sphere, due to occurrence of fluctuations in the electromagnetic field, is calculated using a source theory formulation. Two independent methods are employed: we compute (1) the total Casimir energy inside and outside the sphere, and (2) the radial component of the stress tensor on the surface. It is necessary to exercise care in allowing the field points to overlap; a correct limiting procedure supplies a “cutoff” in the frequency integration. In spite of numerous technical improvements, the result of Boyer, that the self-stress is repulsive (and not attractive as Casimir hoped), is confirmed unambiguously. The magnitude of the Casimir energy of a sphere of radius a is found, by numerical and analytic techniques, to be , also in agreement with the very recent result of Balian and Duplantier. 相似文献
176.
177.
178.
Vinylacetylene was pyrolyzed at 300–450°C in a packed and an unpacked static reactor with a pinhole bleed to a quadrupole mass spectrometer. The reactant and C8H8 products were monitored continuously during a reaction by mass spectrometry. In some runs, the products were also analyzed by gas chromatography after the run. In these runs CH4, C2H6, C3H6, and C2H4 were also detected. The reaction for vinylacetylene removal and C8H8 formation is homogeneous, second order in reactant, and independent of the presence of a large excess of N2 or He. However, C8H8 formation is about half-suppressed by the addition of the free-radical scavengers NO or O2. The rate coefficient for total vinylacetylene removal is 1.7 × 106 exp(?79 ± 13 kJ/mol RT) L/mol · s. The major reaction for C4H4 removal is polymerization. In addition four C8H8 isomers, carbon, and small hydrocarbons are formed. The three major C8H8 isomers are styrene, cyclooctatetraene (COT), and 1,5? dihydropentalene (DHP). The C8H8 compounds are formed by both molecular and free-radical processes in a second-order process with an overall k ? 3 × 108 exp(?122 kJ/mol RT) L/mol · s (average of packed and unpacked cell results). The molecular process occurs with an overall k = 8.5 × 107 exp (?118 kJ/mol RT) L/mol · s. The COT, DHP, and an unidentified isomer (d), are formed exclusively in molecular processes with respective rate coefficients of 4.4 × 104 exp(?77 kJ/mol RT), 1.7 × 105 exp(?89 kJ/mol RT), and 3.1 × 109 exp(? 148 kJ/mol RT) L/mol · s. The styrene is formed both by a direct free-radical process and by isomerization of COT. 相似文献
179.
Modifications to the hole-drilling technique of measuring residual stresses for improved accuracy and reproducibility 总被引:1,自引:0,他引:1
Julian E. Bynum 《Experimental Mechanics》1981,21(1):21-30
The hole-drilling technique is a relatively well established and straightforward semidestructive method for measuring residual stresses in fabricated components. However, a number of factors can have a marked influence on the accuracy of this technique. Some of the factors evaluated in the present work were the method of drilling the hole, the size and shape of the hole, and the equations used to calculate the principal residual stresses from the relaxed-strain measurements. In this investigation, air-abrasive hole drilling using a 0.062-in.-ID stationary nozzle gave the most reproducible and accurate results. Of the three approaches used to calculate the residual stresses, one method proved to be superior, especially in a biaxial-stress field. 相似文献
180.
The sample size required for determination of a given degree of difference between two therapies or modalities A and B being compared with each other, supposing that the sample sizes are equal, is given by Here Cα/2 is the upper α/2 percentile point of the standard normal distribution, C1?β is the abscissa cutting off the proportion 1?β in its upper tail and β in its lower tail; pA and pB are the probabilities of favorable response to A and B; if p?A and p?B are the corresponding measured proportions, then = (p?A + p?B); and the Q's are 1 minus the p's. When it is desirable to use unequal size groups, the sample sizes n1 相似文献