全文获取类型
收费全文 | 1299篇 |
免费 | 87篇 |
国内免费 | 11篇 |
专业分类
化学 | 964篇 |
晶体学 | 5篇 |
力学 | 30篇 |
综合类 | 1篇 |
数学 | 194篇 |
物理学 | 203篇 |
出版年
2023年 | 15篇 |
2022年 | 17篇 |
2021年 | 42篇 |
2020年 | 59篇 |
2019年 | 49篇 |
2018年 | 30篇 |
2017年 | 33篇 |
2016年 | 64篇 |
2015年 | 61篇 |
2014年 | 48篇 |
2013年 | 89篇 |
2012年 | 69篇 |
2011年 | 99篇 |
2010年 | 38篇 |
2009年 | 38篇 |
2008年 | 64篇 |
2007年 | 54篇 |
2006年 | 56篇 |
2005年 | 47篇 |
2004年 | 56篇 |
2003年 | 33篇 |
2002年 | 29篇 |
2001年 | 11篇 |
2000年 | 8篇 |
1998年 | 16篇 |
1997年 | 14篇 |
1996年 | 14篇 |
1995年 | 7篇 |
1994年 | 12篇 |
1993年 | 10篇 |
1992年 | 13篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1989年 | 8篇 |
1988年 | 10篇 |
1987年 | 6篇 |
1986年 | 9篇 |
1985年 | 12篇 |
1984年 | 8篇 |
1983年 | 10篇 |
1982年 | 7篇 |
1981年 | 14篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 12篇 |
1976年 | 10篇 |
1975年 | 8篇 |
1974年 | 9篇 |
1973年 | 9篇 |
1971年 | 6篇 |
排序方式: 共有1397条查询结果,搜索用时 15 毫秒
131.
A (ν, k, k?1) near resolvable block design (NRBD) is r‐rotational over a group G if it admits G as an automorphism group of order (ν?1)/r fixing exactly one point and acting semiregularly on the others. We give direct and recursive constructions for rotational NRBDs with particular attention to 1‐rotational ones. © 2001 John Wiley & Sons, Inc. J Combin Designs 9: 157–181, 2001 相似文献
132.
Julian D. Cole 《Theoretical and Computational Fluid Dynamics》1998,10(1-4):91-104
The hodograph method is used to formulate several design problems in transonic flow using small-disturbance theory. Analytical
and numerical methods give solutions to several optimum critical airfoil designs with different constraints on the tail angle.
Special airfoil shapes flying at free-stream Mach number one are designed. The problem of constructing a shock-free body of
revolution at subsonic speed but having a supersonic zone is formulated in the hodograph and solved numerically.
Received 10 January 1997 and accepted 14 April 1997 相似文献
133.
Julian Gevirtz 《Journal d'Analyse Mathématique》1994,64(1):173-202
A condition of the formf′ (D) ⊂R is calleda first-order univalence criterion if all functions for which it holds are univalent inD. By means of a careful analysis of the behavior of the corresponding extremal functions, we establish fundamental principles
for a coherent theory of sharp criteria of this kind. In particular, we examine the relationship between three different concepts
of sharpness and show how large classes of first-order univalence criteria which are sharp in a strong sense may be described
in terms of the univalence properties of families of analytic functions depending on a finite number of parameters.
This research was supported in part by the Chilean government through FONDECYT grant No. 0809-91. 相似文献
134.
Julian Edward 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1994,45(3):493-496
Study of the zeta function associated to the Neumann operator on planar domains yields an inequality for Steklov eigenvalues for planar domains.This research was partially supported by the Natural Sciences and Engineering Research Council of Canada. 相似文献
135.
Teemu Pennanen Julian P. Revalski Michel Thé ra 《Proceedings of the American Mathematical Society》2003,131(12):3721-3729
In this article we study graph-distance convergence of monotone operators. First, we prove a property that has been an open problem up to now: the limit of a sequence of graph-distance convergent maximal monotone operators in a Hilbert space is a maximal monotone operator. Next, we show that a sequence of maximal monotone operators converging in the same sense in a reflexive Banach space is uniformly locally bounded around any point from the interior of the domain of the limit mapping. The result is an extension of a similar one from finite dimensions. As an application we give a simplified condition for the stability (under graph-distance convergence) of the sum of maximal monotone mappings in Hilbert spaces.
136.
137.
Modeling the consequences of crystalline defects requires efficient interaction sampling. Empirical potentials can identify relevant pathways if the energetics and configurations of competing defects are captured. Here, we develop such a potential for an alloy of arbitrary point defect concentration, body-centered cubic alpha-Fe supersaturated in C. This potential successfully calculates energetically favored defects, and predicts formation energies and configurations of multicarbon-multivacancy clusters that were not attainable with existing potentials or identified previously via ab initio methods. 相似文献
138.
Metal‐Doped Nitrogenated Carbon as an Efficient Catalyst for Direct CO2 Electroreduction to CO and Hydrocarbons
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Ana Sofia Varela Dr. Nastaran Ranjbar Sahraie Julian Steinberg Wen Ju Dr. Hyung‐Suk Oh Prof. Dr. Peter Strasser 《Angewandte Chemie (International ed. in English)》2015,54(37):10758-10762
This study explores the kinetics, mechanism, and active sites of the CO2 electroreduction reaction (CO2RR) to syngas and hydrocarbons on a class of functionalized solid carbon‐based catalysts. Commercial carbon blacks were functionalized with nitrogen and Fe and/or Mn ions using pyrolysis and acid leaching. The resulting solid powder catalysts were found to be active and highly CO selective electrocatalysts in the electroreduction of CO2 to CO/H2 mixtures outperforming a low‐area polycrystalline gold benchmark. Unspecific with respect to the nature of the metal, CO production is believed to occur on nitrogen functionalities in competition with hydrogen evolution. Evidence is provided that sufficiently strong interaction between CO and the metal enables the protonation of CO and the formation of hydrocarbons. Our results highlight a promising new class of low‐cost, abundant electrocatalysts for synthetic fuel production from CO2. 相似文献
139.
Photophysics of a Ruthenium 4H‐Imidazole Panchromatic Dye in Interaction with Titanium Dioxide
下载免费PDF全文
![点击此处可从《Chemphyschem》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Julian Schindler Dr. Stephan Kupfer Dr. Maria Wächtler Dr. Julien Guthmuller Prof. Dr. Sven Rau Prof. Dr. Benjamin Dietzek 《Chemphyschem》2015,16(5):1061-1070
The photophysics of bis(4,4′‐di‐tert‐butyl‐2,2′‐bipyridine‐κ2N,N′)[2‐(4‐carboxyphenyl)‐4,5‐bis(p‐tolylimino‐κN)imidazolato]ruthenium(II) hexafluorophosphate is investigated, both in solution and attached to a nanocrystalline TiO2 film. The studied substitution pattern of the 4H‐imidazole ligand is observed to block a photoinduced structural reorganization pathway within the 4H‐imidazole ligand that has been previously investigated. Protonation at the 4H‐imidazole ring decreases the excited‐state lifetime in solution. When the unprotonated dye is anchored to TiO2, photoinduced electron injection occurs from thermally nonrelaxed triplet metal‐to‐ligand charge transfer (3MLCT) states with a characteristic time constant of 0.5 ps and an injection efficiency of roughly 25 %. Electron injection from the subsequently populated thermalized 3MLCT state of the dye does not take place. The energy of this state seems to be lower than the conduction band edge of TiO2. 相似文献
140.
The Synthesis of B2(SIDip)2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Julian Bhnke Holger Braunschweig Theresa Dellermann William C. Ewing Kai Hammond J. Oscar C. Jimenez‐Halla Thomas Kramer Jan Mies 《Angewandte Chemie (International ed. in English)》2015,54(46):13801-13805
A new compound with the formula L‐B2‐L wherein the stabilizing ligand (L) is 1,3‐bis[diisopropylphenyl]‐4,5‐dihydroimidazol‐2‐ylidene (SIDip) has been synthesized, isolated, and characterized. The π‐acidity of the SIDip ligand, intermediate between the relatively non‐acidic IDip (1,3‐bis[diisopropylphenyl]imidazol‐2‐ylidene) ligand and the much more highly acidic CAAC (1‐[2,6‐diisopropylphenyl]‐3,3,5,5‐tetramethylpyrrolidin‐2‐ylidene) ligand, gives rise to a compound with spectroscopic, electrochemical, and structural properties between those of L‐B2‐L compounds stabilized by CAAC and IDip. Reactions of all three L‐B2‐L compounds with CO demonstrate the differences caused by their respective ligands, as the π‐acidities of the CAAC and SIDip carbenes enabled the isolation of bis(boraketene) compounds (L(OC)B‐B(CO)L), which could not be isolated from reactions with B2(IDip)2. However, only B2(IDip)2 and B2(SIDip)2 could be converted into bicyclic bis(boralactone) compounds. 相似文献