Observation of the nonlinear meissner effect in YBCO thin films: evidence for a D-wave order parameter in the bulk of the cuprate superconductors

We present experimental evidence for the observation of the nonlinear Meissner effect in high-quality epitaxial yttrium barium copper oxide thin films by measuring their intermodulation distortion at microwave frequencies versus temperature. Most of the films measured show a characteristic increase in nonlinearity at low temperatures as predicted by the nonlinear Meissner effect. We could measure the nonlinear Meissner effect because intermodulation distortion measurements are an extremely sensitive method that can detect changes in the penetration depth of the order of 1 part in 10(5).     

Thermodynamics and point defects in the B2 intermetallic phase PdIn

The X-ray and bulk densities of PdIn alloys have been determined at ambient temperature on samples annealed at 1273 and 1373 K and quenched in water-ice mixtures. From these measurements the vacancy concentrations in this intermetallic phase have been obtained as a function of In concentration at these two temperatures. In addition, a generalized thermodynamic model is presented which considers the existence of antisite and vacancy defects on both sublattices without any dilute solution approximations. This model uses three energy parameters, whose values have been obtained for PdIn using the measured vacancy concentrations and the chemical potentials of In. This model is able to describe all the available vacancy data and is suitable for calculating these values at compositions and temperatures when such data are not available. In addition, the model permits the calculation of the concentrations of the minority point defects. It is shown that dilute-solution approximations, which have invariably been used in this kind of modelling, are unsatisfactory. The present results and their analysis confirm that PdIn is a near-triple-defect type of intermetallic and not a near-Schottky type, as has been claimed recently.     

A colorimetric reaction to quantify fluid mixing

We found the colorimetric reaction of Tiron (1,2-dihydroxybenzene-3,5-disulfonic acid) and molybdate suitable for optical quantification of chemical reaction during fluid–fluid mixing in laboratory chambers. This reaction consists of two colorless reagents that mix to rapidly form colored, stable, soluble products. These products can be digitally imaged and quantified using light absorbance to study fluid–fluid mixing. Here we provide a model and equilibrium constants for the relevant complexation reactions. We also provide methods for relating light absorbance to product concentrations. Practical implementation issues of this reaction are discussed and an example of imaged absorbances for fluid–fluid mixing in heterogeneous porous media is given.     

Effects of laryngeal endoscopy on the vocal performanceof young adult females with normal voices

This study investigated changes in maximum phonation time andacoustic and perceptual measures of voice following topical anesthesia and laryngeal endoscopy with the flexible endoscope. Forty-four females, aged 18–33 years and with normal voices, performed four vocal tasks: (a) 3-second /i/ prolongation, (b) maximum phonation time on /i/, (c) stepwise scale-singing, and (d) reading a standard passage. Subjects performed these tasks prior to anesthesia, after anesthesia, and again during laryngeal endoscopy. Voice samples were analyzed for jitter, shimmer, harmonic-to-noise ratio, speaking fundamental frequency, maximum phonational frequency range, maximum phonation time, harshness, and breathiness. Results demonstrated significant reductions in maximum phonational frequency range following anesthesia and, during laryngeal endoscopy, reductions in maximum phonation time and increases in speaking fundamental frequency, minimum fundamental frequency on scale-singing, and breathiness. Clinicians using laryngeal endoscopy for evaluation and management of vocal dysfunction should, therefore, consider the possible effects of these procedures on vocal functioning.     

Development of an Auditory-Perceptual Rating Instrument for the Operatic Singing Voice

Although considerable progress has been made in the development of acoustic and physiological measures of operatic singing voice, there is still no widely accepted objective tool for the evaluation of its multidimensional features. Auditory-perceptual evaluation, therefore, remains an important evaluation method for singing pedagogues, voice scientists, and clinicians who work with opera singers. Few investigators, however, have attempted to develop standard auditory-perceptual tools for evaluation of the operatic voice. This study aimed to pilot test a new auditory-perceptual rating instrument for operatic singing voice. Nine expert teachers of operatic singing used the instrument to rate the singing voices of 21 professional opera chorus artists from a national opera company. The findings showed that the instrument has good face validity, that it can be legitimately treated as a psychometrically sound scale, and that raters can use the scale consistently, both between and within judges. This new instrument, therefore, has the potential to allow opera singers, their teachers, voice care clinicians, and researchers to evaluate the important auditory-perceptual features of operatic voice quality.     

Iron-57 Mössbauer spectroscopy study of iron oxide pillared clays synthesised by microwave heating

A novel method for the rapid preparation of iron oxide-pillared montmorillonite clay using microwave heating is described. The iron oxide pillared clay is progressively reduced in hydrogen at temperatures between 300 and 600°C. The metallic iron formed under reducing conditions is stable to oxygen at room temperature and partially oxidised when heated in oxygen at 300°C.     

A simplified optical lattice clock

Existing optical lattice clocks demonstrate a high level of performance but they remain complex experimental devices. In order to address a wider range of applications including those requiring transportable devices, it will be necessary to simplify the laser systems and reduce the amount of support hardware. Here we demonstrate two significant steps towards this goal: demonstration of clock signals from a Sr lattice clock based solely on semiconductor laser technology, and a method for finding the clock transition (based on a coincidence in atomic wavelengths) that removes the need for extensive frequency metrology hardware. Moreover, the unexpected high contrast in the signal revealed evidence of density dependent collisions in ⁸⁸Sr atoms.