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131.
M. S. Kalinin M. B. Krainev 《Bulletin of the Russian Academy of Sciences: Physics》2007,71(7):984-987
The behavior of the intensity of anomalous and galactic cosmic rays in the outer heliosphere is compared. The previous hypothesis, according to which the lowest energy galactic cosmic rays affected by large-scale electric fields far beyond the termination shock wave of the solar wind may contribute to the behavior of the anomalous component intensity, is analyzed. 相似文献
132.
133.
We investigate the dependence of the relaxation time of the current flowing in a nematic cell submitted to an external dc voltage on the physical properties of the substrate. We show that previously presented analyses of the same problem are not very useful for practical applications. We compare our theoretical predictions with experimental data, and show that the agreement is rather good. The influence of the adsorption-desorption phenomenon on the relaxation time is also discussed. 相似文献
134.
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136.
B. Sanjeeva Rao M. Ramakrishna Murthy 《Journal of Polymer Science.Polymer Physics》1989,27(6):1187-1194
Electron spin resonance (ESR) spectra of poly(acrylic acid) (PAA) γ-irradiated in air at room temperature and recorded at room temperature and at liquid-nitrogen temperature have been studied to identify the radiation products. The ESR spectra are composed of eight lines with hyperfine splittings of 23 ± 1 G and 11 ± 1 G. The method of least-squares total curve fitting, employing the Lorentzian line shape function, to the observed spectra enabled the assignment of the spectra. Computed spectra obtained by the superposition of a singlet and the spectra due to chain radicals are considered to give the best fits to the observed ESR spectra. The singlet is assigned to the radicals COOH, and the component 10-line spectra are assigned to the chain radicals CH3? CH? CH2 ~ and/or ~ CH2? CH? CH2 ~. The observed change in line shape with temperature of the ESR spectra is attributed to the hindered oscillations of the methyl groups about the Cα? Cβ bond axis of the chain radicals. The existence of the methyl groups is confirmed by the measurement of infrared absorption. 相似文献
137.
Praveen K. Tandon Gayatri Sumita Sahgal Manish Srivastava Santosh B. Singh 《应用有机金属化学》2007,21(3):135-138
Catalytic activities of three transition metals, as iridium (III) chloride, rhodium (III) chloride and palladium (II) chloride, were compared in the oxidation of six aromatic aldehydes (benzaldehyde, p‐chloro benzaldehyde, p‐nitro benzaldehyde, m‐nitro benzaldehyde, p‐methoxy benzaldehyde and cinnamaldehyde), two hydrocarbons (viz. (anthracene and phenanthrene)) and one aromatic and one cyclic alcohol (cyclohexanol and benzyl alcohol) by 50% H2O2. The presence of traces (substrate: catalyst ratio equal to 1:62500 to 1:1961) of the chlorides of iridium(III), rhodium(III) and palladium(II) catalyze these oxidations, resulting in good to excellent yields. It was observed that in most of the cases palladium(II) chloride is the most efficient catalyst. Conditions for the highest and most economical yields were obtained. Deviation from the optimum conditions decreases the yields. Oxidation in aromatic aldehydes is selective at the aldehydeic group only and other groups remain unaffected. This new, simple and economical method, which is environmentally safe, also requires less time. Reactive species of catalysts, existing in the reaction mixture are also discussed. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
138.
The effect of crack tip sharpness on crack propagation in vulcanized rubbers has been studied. For very sharp cracks, tearing is found to occur on a small scale at very low energies not far above the threshold required for the onset of mechanical crack growth. The “small-scale” tearing energies show relatively little variation for rubbers that differ widely in tear strength as normally measured. Thus the latter property appears to be strongly influenced by variations in the ability of rubbers to promote tip blunting. The small-scale tear behavior is of relevance to other fracture phenomena, including cutting by sharp objects and tensile failure. Natural variations in tip sharpness occur during cyclic or time-dependent mechanical crack growth and influence the form of the crack growth characteristics. 相似文献
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140.
T. Riesterer J. G. Bednorz K. A. Müller B. Reihl 《Applied Physics A: Materials Science & Processing》1987,44(1):81-82
We have measured ultraviolet and inverse-photoemission spectra of the novel superconductor Sr02La1.8CuO4. Our results compare favorably with recent band-structure calculations for La2CuO4.A full account of this work will be published elsewhere [1] 相似文献