全文获取类型
收费全文 | 311854篇 |
免费 | 2339篇 |
国内免费 | 980篇 |
专业分类
化学 | 146081篇 |
晶体学 | 4795篇 |
力学 | 16670篇 |
综合类 | 4篇 |
数学 | 57901篇 |
物理学 | 89722篇 |
出版年
2021年 | 1967篇 |
2020年 | 2215篇 |
2019年 | 2512篇 |
2018年 | 13475篇 |
2017年 | 13447篇 |
2016年 | 10867篇 |
2015年 | 3564篇 |
2014年 | 4835篇 |
2013年 | 10713篇 |
2012年 | 11743篇 |
2011年 | 19650篇 |
2010年 | 12604篇 |
2009年 | 13032篇 |
2008年 | 15334篇 |
2007年 | 17246篇 |
2006年 | 8597篇 |
2005年 | 8686篇 |
2004年 | 8418篇 |
2003年 | 8203篇 |
2002年 | 7185篇 |
2001年 | 7287篇 |
2000年 | 5528篇 |
1999年 | 4161篇 |
1998年 | 3642篇 |
1997年 | 3413篇 |
1996年 | 3189篇 |
1995年 | 2934篇 |
1994年 | 2856篇 |
1993年 | 2791篇 |
1992年 | 3100篇 |
1991年 | 3097篇 |
1990年 | 2980篇 |
1989年 | 2927篇 |
1988年 | 2859篇 |
1987年 | 2820篇 |
1986年 | 2670篇 |
1985年 | 3415篇 |
1984年 | 3543篇 |
1983年 | 3112篇 |
1982年 | 3234篇 |
1981年 | 2960篇 |
1980年 | 2931篇 |
1979年 | 3098篇 |
1978年 | 3236篇 |
1977年 | 3182篇 |
1976年 | 3146篇 |
1975年 | 3044篇 |
1974年 | 3002篇 |
1973年 | 3163篇 |
1972年 | 2142篇 |
排序方式: 共有10000条查询结果,搜索用时 25 毫秒
101.
Benzildithiosemicarbazone (BDTSC) is proposed as a sensitive and selective analytical reagent for the extractive spectrophotometric determination of copper(II). BDTSC reacts with copper(II) in the pH range 1.0-7.0 to form a yellowish complex. Beer's law is obeyed in the concentration range 0.5-0.4 microg cm(-3). The yellowish Cu(II)-BDTSC complex in chloroform shows a maximum absorbance at 380 nm, with molar absorptivity and Sandell's sensitivity values of 1.63 x 10(4) dm3 mol(-1) cm(-1) and 0.00389 microg cm(-2), respectively. A repetition of the method is checked by finding the relative standard deviation (RSD) (n = 10), which is 0.6%. The composition of the Cu(II)-BDTSC complex is established as 1:1 by slope analysis, molar ratio and Asmus' methods. An excellent linearity with a correlation coefficient value of 0.98 is obtained for the Cu(II)-BDTSC complex. The instability constant of the complex calculated from Edmond and Birnbaum's method is 7.70 x 10(-4) and that of Asmus' method is 7.66 x 10(-4), at room temperature. The method is successfully employed for the determination copper(II) in pharmaceutical and environmental samples. The reliability of the method is assured by analyzing the standard alloys (BCS 5g, 10g, 19e, 78, 32a, 207 and 179) and by inter-comparison of experimental values, using an atomic absorption spectrometer. 相似文献
102.
An experimental apparatus and related procedures for the determination of the effective thermal conductivity of sintered powder-metal
plates saturated with distilled water at temperatures in the range 20–150°C are discussed. The apparatus and procedures are
applied to two samples of sintered powder-metal plates, one made of nickel 200 and the other of stainless steel 316, with
porosities of 28.10 and 46.45%, respectively, and each of nominal dimensions 127 mm × 127 mm × 6.35 mm. The experimental
results are compared with corresponding predictions yielded by several correlations available in the literature. The correlations
based on experimental data for packed beds of spherical particles and also porous plates made of cold-pressed (but not sintered)
particles of angular shapes do not apply well to sintered powder-metal plates. A new correlation, which is based on extensions
of ideas contained in earlier works and provides improved predictions, is proposed. 相似文献
103.
104.
Results are presented of an experimental investigation of vortex ring formation by a fluid drop contacting a free surface
with negligible velocity. The pool fluid is mixed with fluorescein dye, and a laser sheet is used to illuminate a plane of
the flow. A series of representative images is recorded by a CCD camera and speculation is made regarding specific sources
of vorticity flux through the free surface. Two scaling analyses previously presented by other investigators are demonstrated
to be equivalent under the assumptions of this experiment, and they provide the motivation for a series of test runs in which
the duration of the coalescence process, τ*, is related to variations in drop diameter L and fluid surface tension σ. Experimental results are in agreement with the analyses, showing τ*∼σ-1/2 and τ*∼L
3/2.
Received: 22 December 1995 / Accepted: 15 October 1996 相似文献
105.
The paper presents an exact analysis of the dispersion of an immiscible solute in a non-Newtonian fluid (known as an incompressible second-order fluid which shows viscoelastic behaviour) flowing slowly in a parallel plate channel in the presence of a periodic pressure gradient. Using a generalized dispersion model which is valid for all times after the solute injection, the diffusion coefficients K i (τ)(i=1,2,3,…) are obtained as functions of time τ in the case when the initial solute distribution is in the form of a slug of finite extent. The analysis leads to the novel result that K 2(τ) (which is a measure of the longitudinal dispersion coefficient of the solute) has a steady part S in addition to a fluctuating part D 2(τ) due to the pulsatility of the flow. It is found that S decreases with increase in the viscoelastic parameter M for given values of the amplitude λ and frequency ω of the pressure pulsation. On the other hand, it is found that at a fixed instant τ, the amplitude of D 2(τ) increases with increase in M for given values of λ and ω. Further it is shown that at a given instant τ, the amplitude of D 2(τ) decreases with increase in ω for given λ and M and the profile for D 2(τ) becomes progressively flatter with increase in ω. Finally the axial distribution of the average concentration θ m of the solute over the channel cross-section is determined at different instants after the solute injection for several values of M, λ and ω. The present study is likely to have important bearing on the problem of dispersion of tracers in blood flow through arteries. 相似文献
106.
In the case of number fields the embedding problem of a p-extension with non-Abelian kernel of order p4 is studied. The two kernels of order 34 with generators α, γ and relations α9 = 1, [α,α]3=1,[α,αγγ]==1,[αγγ]=α3,γ3=1 or γ3=α3 and the kernel of order 24 with generators α, β, γ and relations α4=1 β2,[αγ]=1, [α,γ]=1,[βγ]=α2 are considered. For kernels of odd order the embedding problem is always solvable. For the kernel of order 16 the solvability
conditions are reduced to those for the associated problems at the Archimedean points, and to the compatibility condition.
Bibliography: 9 titles.
Translated fromZapiski Nauchnykh Seminarov POMI, Vol. 227, 1995, pp. 74–82. 相似文献
107.
J. Kircher M. Cardona M. Alouani S. Gopalan O. Jepsen O. K. Andersen
E. Kaldis
J. Karpinski S. Rusieki 《Physica C: Superconductivity and its Applications》1992,200(3-4):413-417We report results of ellipsometric measurements of the dielectric tensor of YBa2Cu4O8 as well as calculations employing density functional theory in the local density approximation (LDA). For the computation of the one-electron eigenvalues and states the linear-muffin-tin-orbital method (LMTO) was used. Measured and calculated results show good agreement. In particular, the calculation predicts different band structures for YBa2Cu3O7 and YBa2Cu4O8 in the vicinity of the Fermi energy which lead to significant differences in the optical spectra. One such difference is a region of small ε2 in the near infrared which is a fingerprint of the high (relative to the top of the highest fully occupied band) Fermi energy as compared to the situation in YBa2Cu3O7. Our experimental results confirm the theoretical findings. 相似文献
108.
Ablation of an optically homogeneous absorbing medium by scattered pulsed laser radiation 总被引:1,自引:0,他引:1
V. V. Golovlyov R. O. Esenaliev V. S. Letokhov 《Applied physics. B, Lasers and optics》1993,57(6):451-457
We have studied the ablation of an aqueous CuCl2 solution in a pulsed Nd:YAG laser field featuring a speckle-patterned structure characterized by spatial radiation energy fluence fluctuations. This leads to a nonuniform distribution of the energy absorbed in the bulk of the sample being irradiated and causes local overheating centers to form, wherein ablation is observed to take place at laser energy fluences below the threshold value found in experiments with a homogeneous laser beam. This effect should be manifest in the laser irradiation of biotissues which, as a rule, scatter light strongly. 相似文献
109.
Experiments for the determination of mono-, di and tri-butyltin (MBT, DBT and TBT) by hydride generation/gas chromatography/atomic absorption spectrometry in various matrices (sediment, suspended matter, mussel, algae and water) have revealed that poor butyltin recoveries are obtained in sediments displaying high sulphur and hydrocarbon contents; very poor recoveries were also observed for TBT in sediments with high chlorophyll pigment contents as well as in algal samples. It was however not clear whether the hydride generatin was inhibited by these infering compounds, as was previously assumed in the case of hydrocarbons, or whether interferences affected the atomization rate. Further studies were performed to solve this problem in order to validate this method in the case of analyses of, for example, oil-contaminated sediment and algae. This paper presents the results obtained. It is concluded here that the poor recoveries were due to an inhibition of hydride generation rather than to interference at the atomization stage. 相似文献
110.
Summary X-ray reflectivity may be used to determine the internal structure of thin polymer films. An electron density difference of 10% for polystyrene and polyisoprene is sufficient to distinguish between a random distribution of lamellae, complete orientation parallel to the substrate surface and a surface induced formation of lamellae. The disappearance of the lamellar Bragg-peaks, with heating of the film, shows the transition into the disordered state. 相似文献