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51.
The flow of a solution between parallel plates is considered. The bottom plate is porous, while the top one is an impermeable solid. A computer program based on the control volume approach was developed to analyse the flow and concentration fields. The effects of the slip at the porous wall on the velocity and particle concentration distributions were investigated. It was observed that as the slip increases, the concentration on the porous wall decreases and the maximum velocity moves towards the porous wall. The concentration on the porous wall increases in the flow direction. This increase in the particle concentration along the porous wall may cause a reduction of the porosity and hence a variation in the suction rate along the porous wall. In order to take this effect into account, a linearly varying transverse velocity along the porous wall was considered. The results were compared with the data available in the literature. 相似文献
52.
A series of ester formylhydrazones 2 were synthesized from the reaction of alkyl imidate hydrochlorides 1 with formylhydrazine. Treatment of 2 with hydrazine hydrate, ethyl carbazate and tert-butyl carbazate led to the formation of 3-alkyl-4-amino-, 3-alkyl-4-ethoxycarbonylamino- and 3-alkyl-4-tert-butoxycar-bonylamino-4H-1,2,4-triazoles 3–5 , respectively. Reaction of compounds 2 with formylhydrazine gave N,N'-diformylhydrazine 6 . Compounds 2 were reacted with 2,5-dimethoxytetrahydrofuran to afford 3-alkyl-4-(1H-pyrrol-1-yl)-4H-1,2,4-triazoles 8 . 相似文献
53.
Increasingly stringent demands on the production of biopharmaceuticals demand monitoring of process parameters that impact on their quality. We developed an automated platform for on-line, near real-time monitoring of suspension cultures by integrating microfluidic components for cell counting and filtration with a high-resolution separation technique. This enabled the correlation of the growth of a human lymphocyte cell line with changes in the essential metabolic markers, glucose, glutamine, leucine/isoleucine and lactate, determined by Sequential Injection-Capillary Electrophoresis (SI-CE). Using 8.1 mL of media (41 μL per run), the metabolic status and cell density were recorded every 30 min over 4 days. The presented platform is flexible, simple and automated and allows for fast, robust and sensitive analysis with low sample consumption and high sample throughput. It is compatible with up- and out-scaling, and as such provides a promising new solution to meet the future demands in process monitoring in the biopharmaceutical industry. 相似文献
54.
In the present study, the effect of parameters, including microwave irradiation power, pH, dosage of chemical reagents (collector, depressant and activator) were studied by microflotation (in Hallimond tube) process. The mechanical flotation tests were carried out on optimum parameters obtained from microflotation tests. The software based on experimental design method (DX7) with the two-level full factorial design was applied to determine the parameter effects and to optimize the microflotation recovery. The optimum conditions were determined by analysis of variance (ANOVA), indicating that the irradiation power was the most effective parameter. The optimum values of parameters in the microflotation process are as follows: power of microwave (1000 W), pH (6.3), dosage of chemical reagents (sodium oleate 3.65 × 10-4 M as a collector, acidified sodium silicate 2 g L–1 as a depressant, and lead(II) nitrate 2.1 × 10–5 M as an activator). By applying these optimized parameters, a product with ilmenite recovery of 83.26% was predicted by the software. The results of microflotation tests indicated that an ilmenite recovery of 82.35% was achieved being very close to the predicted value. The results of mechanical flotation based on optimized condition showed that the recovery and separation efficiency of irradiated ilmenite were improved up to 86.03% and 48.61%, respectively, indicating the positive effect of irradiation on ilmenite floatability. 相似文献
55.
56.
In this paper, we consider Caputo type fractional differential equations of order 0<α<1 with initial condition x(0)=x0. We introduce a technique to find the exact solutions of fractional differential equations by using the solutions of integer order differential equations. Generalization of the technique to finite systems is also given. Finally, we give some examples to illustrate the applications of our results. 相似文献
57.
Nuri Ünal 《Foundations of Physics》1997,27(5):731-746
We propose a simple classical model of the zitterbewegung. In this model spin is proportional to the velocity of the particle,
the component parallel top is constant and the orthogonal components are oscillating with2p frequency. The quantization of the system gives wave equations for spin,0, 1/2, 1, 3/2,…, etc. respectively. These equations are convenient for massless particles. The wave equation of the spin-1, massless free particle is equivalent to the Maxwell equations and the state functions have a probability interpretation
and exhibit conserved current densities. The ground state has zero energy. 相似文献
58.
Cordycepin is the main active metabolite of Cordyceps militaris extracts; according to recent studies it has interesting therapeutic activities. A new capillary electrophoresis (CE) procedure with UV detection at 254 nm for determination of cordycepin was developed and optimized. Optimal conditions found were 20 mM sodium borate buffer with 28.6% methanol, pH 9.5, separation voltage 20 kV, hydrodynamic injection time 10 s and temperature 25 °C. Linearity was found over the 20-100 μg/mL concentration ranges of cordycepin. The developed method has been applied for determination of cordycepin in various pharmaceutical products. A comparison was made between CE and a high performance liquid chromatography (HPLC) method. Both of these methods gave comparable results. The shorter analysis time and low running cost are the main advantages of CE method. 相似文献
59.
Melahat Göktaş Mehmet Nuri Atalar Ahmet T. Tekeş Baki Hazer 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(11):854-863
One-step synthesis of the triblock copolymers was carried out by reversible addition–fragmentation chain transfer (RAFT) polymerization of methyl methacrylate (MMA) and ring-opening polymerization (ROP) of β-butyrolactone (BL) or ?-caprolactone (CL) using a novel difunctional macro-RAFT agent. For this purpose, primarily PEG-Br (polyethylene glycol bromine) was obtained by using 3-bromopropanoyl chloride and PEGs (polyethylene glycols) with different molecular weights. Then, macro-RAFT agent was synthesized by the reaction of potassium ethyl xanthogenate and PEG-Br. By using macro-RAFT agent, poly(MMA-b-EG-b-BL), and poly(MMA-b-EG-b-CL) triblock copolymers were synthesized by changing some polymerization conditions such as monomer/initiator concentration, polymerization time. The effect of the reaction conditions on the polydispersity and molecular weights were also investigated. The block lengths of the triblock copolymers were calculated by using 1H-nuclear magnetic resonance (1H-NMR) spectra. It was observed that the block length could be altered by varying the monomer and initiator concentrations. The characterization of the products were achieved using 1H-NMR, Fourier-transform infrared spectroscopy (FTIR), gel-permeation chromatography (GPC), thermogravimetric analysis (TGA), and fractional precipitation (γ) techniques. 相似文献
60.
Solubilities at invariant points of the Na,Ca‖SO4,F-H2O system at 0°C was studied, and a phase diagram of this system at 0°C was constructed. 相似文献