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The energy and structural changes of lithium microclusters based on temperature has been investigated by using Molecular-Dynamic simulation Method. Two and three-body interacted semi-empiric potential energy formula that characterized the interaction has been used. It has been calculated that the dissociation of atoms from cluster has started after 1300 K for Li3 and 1350 K for Li4, respectively. Dissociations at the fixed temperatures are very close to the expected values of the lithium metal. Additionally, it has been observed that Li4 microclusters above 1000 K and Li3 clusters above 700 K temperatures have steady structures in two different energy values. 相似文献
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Mustafa Yıldız Hava Özay Hüseyin Ünver Nazan Ocak İskeleli D. Mehmet Zengin Tahsin Nuri Durlu 《Journal of chemical crystallography》2010,40(11):909-913
Abstract
Schiff base (E)-2-[(benzo[d]thiazol-2-ylimino)methyl]phenol (1) has been synthesized from the reaction of 2-hydroxy-benzaldehyde with 2-aminobenzothiazole. The 2-[(benzo[d]thiazol-2-ylamino)methyl]phenol (2) was prepared reduction of the Schiff base 1 with sodium borohydride. The compounds 1 and 2 have been characterized by elemental analysis, FT-IR, 1H-NMR, 13C-NMR and UV–visible spectroscopic techniques. The structure of the compound 2 has also been examined crystallographically. The compound 2 crystallizes in the monoclinic space group P2/c. The unit cell parameters were found as a = 10.017(1), b = 11.725(1), c = 10.341(1) ?, V = 1208.1(1) ?3, D x = 1.409 g cm−3 and Z = 4. The crystal structure was solved by direct methods and refined by the full-matrix least squares method and found as R 1 = 0.0308 and wR 2 = 0.0818 for 2032 for the observed reflections [I > 2σ(I)]. 相似文献15.
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In this work, we report a comprehensive theoretical investigation of electroactive star shaped pyrrole functionalized triazine monomer with two main goals. First goal of this work is to explore the physical and chemical properties of the monomer, then to investigate correlation between the experimental and the theoretical properties of monomer. The scale factor which is calculated from B3LYP/cc-pVDZ was determined as 0.985 for FT-IR and it is an important and reliable contribution to the literature. It is determined that the most appropriate basis set for this molecule. The other novel objective of this research is to investigate temperature effect on displacement of chlorine atoms in 2,4,6-trichloro-1,3,5-triazine. This method applied for the first time in the literature for triazines is especially crucial to the synthesis of unsymmetrical triazines. 相似文献
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Nuri Yücel 《Heat and Mass Transfer》1994,29(8):471-477
The flow and heat transfer in partially heated and partially cooled cavities were numerically analyzed. Using the control volume approach, a computer program based on SIMPLE algorithm was developed. A square enclosure with variable size heater and cooler on the vertical walls was considered. Computations were carried out to investigate the effects of heater and cooler size on the heat transfer rate. It was observed that for a given cooler size, the mean Nusselt number decreases with increasing heater size. On the other hand, for a given heater size, the mean Nusselt number increases with increasing cooler size. For all Rayleigh numbers considered, the same behavior was observed.
Nomenclature g gravitational acceleration - H height of cavity - k thermal conductivity of fluid - l C cooler size - l H heater size - mean Nusselt number - Nu y local Nusselt number - P pressure - Pr Prandtl number - Ra Rayleigh number (Ra = gH 3(T H –T C)/()) - T temperature - T C temperature of cold surface - T H temperature of hot surface - T R reference temperature (T R = (T C +T H)/2) - u velocity component inx-direction - x horizontal axis - v velocity component iny-direction - y vertical axis Greek symbols thermal diffusivity - thermal expansion coefficient - density of fluid - stream function - kinematic viscosity 相似文献
Natürliche Konvektion in geschlossenen Räumen mit partieller Heizung und Kühlung der Wände
Zusammenfassung Es wurde ein numerisches Modell zur Analyse des Strömungs- und Wärmeübergangsverhaltens in teilweise beheizten und gekühlten Hohlräumen entwickelt und unter Verwendung des Kontrollvolumenprinzips und des Algorithmus SIMPLE als Computer-Programm formuliert. Der Hohlraum ist rechteckig und die variablen Heiz- und Kühlflächen befinden sich auf gegenüberliegenden Vertikalseiten. Hauptziel der Berechnungen war es, den Einfluß der variablen Heiz- und Kühlflächen auf den Wärmeübergang zu ermitteln. Für eine bestimmte Kühlergröße zeigte sich eine Abnahme der gemittelten Nußelt-Zahl mit zunehmender Heizfläche. Andererseits — bei gegebener Heizfläche — stieg die Nußelt-Zahl mit der Kühlfläche an. Dieses Verhalten wurde bei allen untersuchten Rayleighzahlen gefunden.
Nomenclature g gravitational acceleration - H height of cavity - k thermal conductivity of fluid - l C cooler size - l H heater size - mean Nusselt number - Nu y local Nusselt number - P pressure - Pr Prandtl number - Ra Rayleigh number (Ra = gH 3(T H –T C)/()) - T temperature - T C temperature of cold surface - T H temperature of hot surface - T R reference temperature (T R = (T C +T H)/2) - u velocity component inx-direction - x horizontal axis - v velocity component iny-direction - y vertical axis Greek symbols thermal diffusivity - thermal expansion coefficient - density of fluid - stream function - kinematic viscosity 相似文献
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Nuri Akkas 《International Journal of Non》1978,13(3):177-183
The dynamic behavior of a spherical membrane, made of Mooney material and subjected to a uniform inflating step-pressure, is studied. Its phase-planes and nondimensional radius versus time curves are plotted for different values of the material constants. The conditions for dynamic snapout instability are discussed. The relations between the static behavior of the membrane and the dynamic instability are pointed out. 相似文献
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Yusuf Uar Nuri M. Yamurlu hsan elikkaya 《Numerical Methods for Partial Differential Equations》2019,35(2):478-492
The aim of this study is to obtain numerical behavior of a one‐dimensional modified Burgers' equation using cubic B‐spline collocation finite element method after splitting the equation with Strang splitting technique. Moreover, the Ext4 and Ext6 methods based on Strang splitting and derived from extrapolation have also been applied to the equation. To observe how good and effective this technique is, we have used the well‐known the error norms L2 and L∞ in the literature and compared them with previous studies. In addition, the von Neumann (Fourier series) method has been applied after the nonlinear term has been linearized to investigate the stability of the method. 相似文献
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