全文获取类型
收费全文 | 596篇 |
免费 | 16篇 |
专业分类
化学 | 405篇 |
晶体学 | 19篇 |
力学 | 5篇 |
数学 | 32篇 |
物理学 | 151篇 |
出版年
2023年 | 7篇 |
2022年 | 15篇 |
2021年 | 17篇 |
2020年 | 20篇 |
2019年 | 21篇 |
2018年 | 16篇 |
2017年 | 10篇 |
2016年 | 20篇 |
2015年 | 14篇 |
2014年 | 26篇 |
2013年 | 31篇 |
2012年 | 37篇 |
2011年 | 40篇 |
2010年 | 29篇 |
2009年 | 46篇 |
2008年 | 44篇 |
2007年 | 30篇 |
2006年 | 23篇 |
2005年 | 31篇 |
2004年 | 15篇 |
2003年 | 14篇 |
2002年 | 25篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 10篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有612条查询结果,搜索用时 15 毫秒
51.
52.
Hernane T. Barcelos Luclecia D. Nunes Guilherme W. Tavares Edesio F. C. Alcantara Alexandre G. S. Prado 《Journal of Thermal Analysis and Calorimetry》2011,106(2):421-425
Silica gel was modified by silanization reaction followed by functionalization of histamine in a heterogeneous route. These
materials were characterized by elementary nitrogen and chloride analyses, porosity, thermogravimetry, and infrared. The functionalized
surface adsorbed Cu(II), Co(II), Ni(II), and Zn(II) ions in an aqueous solution at 25 °C. The isotherms of adsorption are
in accordance with Langmuir model and the surface presented a great potential to form complexes metal-surface in the chemical
reason of 1:1. 相似文献
53.
Adriana Lídia Santana Cristiano Giacomelli Paula Nunes Oliveira Alfredo Tibúrcio Nunes Pires José Roberto Bertolino Almir Spinelli 《Journal of Polymer Science.Polymer Physics》2009,47(2):215-225
The effect of poly(2‐vinyl pyridine) (P2VP) and poly(4‐vinyl pyridine) (P4VP) isomers on the growth of surface films on copper substrates was studied by electrochemical, spectroscopic, thermogravimentric, and microscopic methods. In acid environment (3% v/v acetic acid) and in the presence of KSCN, electrochemically generated copper cations reacted rapidly with SCN? and P2VP or P4VP, yielding coordination compounds, which deposited onto copper surfaces as films. The characteristics of such polymer–metal complexes (films) were markedly isomer‐dependent. Cu(I)/P2VP/SCN? complexes with monovalent cations and sulfur‐coordinated thiocyanate were obtained in the presence of P2VP, whereas the formation of Cu(II)/P4VP/SCN? complexes with divalent cations and nitrogen‐coordinated thiocyanate was observed in the presence of P4VP. Interestingly, similar physical–chemical properties (electronic structure, stoichiometry, and thermal behavior) were observed for materials synthesized by electrochemical and chemical methods. These results suggest, therefore, that control over the surface properties of copper substrates can be achieved using electrosynthesized films based on different PVP isomers. Besides acting as effective protective barriers against aggressive media and thus reducing the metal dissolution (corrosion) kinetics, these materials are potentially attractive for other applications in which surface properties are paramount, such as in catalysis. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 215–225, 2009 相似文献
54.
55.
Sandra S. Ferreira Dário Ferreira Célia Nunes João T. Mexia 《Mathematical Methods in the Applied Sciences》2023,46(1):356-367
Sub-models of mixed linear models are considered. The independence of these sub-models leads to sufficient statistics for the parameters relevant for their densities. Using pivot variables, confidence regions are obtained as well hypothesis testing for variance components, estimable functions, and estimable vectors. In addition, to compare the estimators and the models, we present the histograms with the empirical joint densities for positive and negative parts of the estimators. The figures, for the two-dimensional charts, contain the corresponding UMVUE and are all unimodal with the UMVUE near the mode. The nearness of the estimators and the modes validates the presented methodology and allows the safe use of induced densities. A numerical example applied to real data is presented. 相似文献
56.
Bruno Fernandes Ana C. Correia Fernanda Cosme Fernando M. Nunes 《Natural product research》2015,29(1):37-45
The purpose of this work was to study the volatile composition of vine leaves and vine leaf infusion prepared from vine leaves collected at 30 and 60 days after grape harvest of two Vitis vinifera L. species. Eighteen volatile compounds were identified by gas chromatography–mass spectrometry in vine leaves and in vine leaf infusions. It was observed that the volatile compounds present in vine leaves are dependent on the time of harvest, with benzaldehyde being the major volatile present in vine leaves collected at 30 days after harvesting. There are significant differences in the volatile composition of the leaves from the two grape cultivars, especially in the sample collected at 60 days after grape harvest. This is not reflected in the volatile composition of the vine leaf infusion made from this two cultivars, the more important being the harvesting date for the volatile profile of vine leaf infusion than the vine leaves grape cultivar. 相似文献
57.
58.
Clovis Piovezan Fábio da Silva Lisboa Fábio Souza Nunes Sueli Maria Drechsel 《Transition Metal Chemistry》2011,36(1):79-85
We report the reactivity of three binuclear non-heme Fe(III) compounds, namely [Fe2(bbppnol)(μ-AcO)(H2O)2](ClO4)2 (1), [Fe2(bbppnol)(μ-AcO)2](PF6) (2), and [Fe2(bbppnol)(μ-OH)(Cl)2]·6H2O (3), where H3bbppnol = N,N′-bis(2-hydroxybenzyl)-N,N′-bis(2-methylpyridyl)–1,3-propanediamine-2-ol, toward the hydrolysis of bis-(2,4-dinitrophenyl)phosphate as models for phosphoesterase
activity. The synthesis and characterization of the new complexes 1 and 3 was also described. The reactivity differences observed for these complexes show that the accessibility of the substrate
to the reaction site is one of the key steps that determinate the hydrolysis efficiency. 相似文献
59.
G.V.S.M. CarreraZ. Visak R. Bogel-Lukasik M. Nunes da Ponte 《Fluid Phase Equilibria》2011,303(2):180-183
Vapour-liquid equilibrium of CO2 + [0.00871 glycerol + 0.99129 (ethanol or 1-propanol or 1-butanol)] mixtures was measured at the temperatures of 313.15 K and 333.15 K, and close to the critical line, at pressures up to 12 MPa. On the liquid side, the bubble points measured for these ternary mixtures follow closely the behaviour of VLE reported by several authors for the corresponding binary mixtures without glycerol. On the vapour side, however, dew points for the ternary mixtures deviate significantly from VLE results for the binaries. A correlation of the results obtained for the CO2 + glycerol + ethanol mixture with the Peng-Robinson equation of state, admitting quasi-binary behaviour, equally yields good agreement on the liquid side, and significant deviations on the vapour side. 相似文献
60.
Nunes SP Karunakaran M Pradeep N Behzad AR Hooghan B Sougrat R He H Peinemann KV 《Langmuir : the ACS journal of surfaces and colloids》2011,27(16):10184-10190
The supramolecular assembly of PS-b-P4VP copolymer micelles induced by selective solvent mixtures was used to manufacture isoporous membranes. Micelle order in solution was confirmed by cryo-scanning electron microscopy in casting solutions, leading to ordered pore morphology. When dioxane, a solvent that interacts poorly with the micelle corona, was added to the solution, polymer-polymer segment contact was preferential, increasing the intermicelle contact. Immersion in water gave rise to asymmetric porous membranes with exceptional pore uniformity and high porosity. The introduction of a small number of carbon nanotubes to the casting solution improved the membrane stability and the reversibility of the gate response in the presence of different pH values. 相似文献