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21.
Visualization of Heterogeneous Oxygen Storage Behavior in Platinum‐Supported Cerium‐Zirconium Oxide Three‐Way Catalyst Particles by Hard X‐ray Spectro‐Ptychography
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Makoto Hirose Dr. Nozomu Ishiguro Kei Shimomura Dr. Nicolas Burdet Dr. Hirosuke Matsui Prof. Dr. Mizuki Tada Prof. Dr. Yukio Takahashi 《Angewandte Chemie (International ed. in English)》2018,57(6):1474-1479
The cerium density and valence in micrometer‐size platinum‐supported cerium–zirconium oxide Pt/Ce2Zr2Ox (x=7–8) three‐way catalyst particles were successfully mapped by hard X‐ray spectro‐ptychography (ptychographic‐X‐ray absorption fine structure, XAFS). The analysis of correlation between the Ce density and valence in ptychographic‐XAFS images suggested the existence of several oxidation behaviors in the oxygen storage process in the Ce2Zr2Ox particles. Ptychographic‐XAFS will open up the nanoscale chemical imaging and structural analysis of heterogeneous catalysts. 相似文献
22.
Imaging of Oxygen Diffusion in Individual Platinum/Ce2Zr2Ox Catalyst Particles During Oxygen Storage and Release
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Dr. Hirosuke Matsui Dr. Nozomu Ishiguro Kaori Enomoto Dr. Oki Sekizawa Prof. Dr. Tomoya Uruga Prof. Dr. Mizuki Tada 《Angewandte Chemie (International ed. in English)》2016,55(39):12022-12025
The spatial distribution of Ce3+ and Ce4+ in each particle of Ce2Zr2Ox in a three‐way conversion catalyst system was successfully imaged during an oxygen storage/release cycle by scanning X‐ray absorption fine structure (XAFS) using hard X‐ray nanobeams. For the first time, nano‐XAFS imaging visualized and identified the modes of non‐uniform oxygen diffusion from the interface of Pt catalyst and Ce2Zr2Ox support and the active parts in individual catalyst particles. 相似文献
23.
Schocker A Uetake M Kanno N Koshi M Tonokura K 《The journal of physical chemistry. A》2007,111(29):6622-6627
The kinetics and absolute rate constants of the gas-phase reaction of the hydroxymethyl radical (CH2OH) with molecular oxygen have been studied using laser photolysis/near-IR absorption spectroscopy. The reaction was tracked by monitoring the time-dependent changes in the production of the hydroperoxy radical (HO2) concentration. For sensitive detection of HO2, two-tone frequency modulation absorption spectroscopy was used in combination with a Herriott-type optical multipass absorption cell. Rate constants were determined as a function of temperature (236 K相似文献
24.
Koizumi H Kimata Y Shiraishi Y Hirai T 《Chemical communications (Cambridge, England)》2007,(18):1846-1848
A polymeric photosensitizer, poly(NIPAM-co-RB), consisting of N-isopropylacrylamide and rose bengal units, demonstrates a temperature-controlled changeable oxygenation selectivity by singlet oxygen in water. 相似文献
25.
This study aims to measure the oxidative status of LDL from human plasma (n=26) as assessed by biomarkers for lipid peroxidation, total hydroxyoctadecadienoic acid (tHODE), 7alpha- and 7beta-hydroxycholesterol (t7-OHCh), and 8-iso-prostaglandin F(2alpha) (t8-iso-PGF(2alpha)) after subfractionation of LDL with an anion-exchange HPLC (AE-HPLC). LDL was separated and quantified by AE-HPLC as LDL-1, LDL-2, and LDL-3 in the order of the anionic charge of the LDL particles. The concentrations of tHODE, t7-OHCh, and t8-iso-PGF(2alpha) in both plasma and LDL subfractions were assessed after reduction and saponification. In this method, the free and ester forms of hydroperoxides, ketones, and hydroxides of linoleic acid and cholesterol are measured as tHODE and t7-OHCh, respectively. It was found that tHODE significantly correlated with the proportion of LDL-2 and LDL-3 as well as with the concentration of malondialdehyde-modified LDL in plasma. Further, by the analyses of LDL subfractions, the concentrations of tHODE, t8-iso-PGF(2alpha), and t7-OHCh in LDL-3 were found to be significantly higher than those in LDL-1 and LDL-2. These results clearly indicate that the extent of oxidation increases in the order of LDL-1相似文献
26.
Tasuku Onodera Yusuke Morita Michihisa Koyama Nozomu Hatakeyama Hiromitsu Takaba Momoji Kubo Jean-Michel Martin 《Applied Surface Science》2009,256(4):976-979
We investigated the influence of a nanometer scale film structure of a tribofilm generated from zinc dialkyldithiophosphate (ZDDP) anti-wear additive on its mechanical properties using a combined molecular dynamics (MD) and finite element (FE) method. The frictional behavior of an interface between a native iron oxide layer on steel surface and zinc metaphosphate - regarded as a model material of ZDDP tribofilm - was firstly studied using the MD method. The results showed that the iron atoms in the oxide layer diffused into the phosphate layer during the friction process. The zinc atoms in the phosphate layer also diffused into the oxide layer. Significant interdiffusion of iron and zinc atoms was observed with increasing simulation time. Thus, metallic phosphate with a gradient composition of iron and zinc atoms was formed on the phosphate/oxide interface. We then constructed an axisymmetric nanoindentation simulation model from the MD-derived structures at a certain simulation time and carried out a FE calculation. As a result, we found that the rubbed ZDDP tribofilm, including the phosphate with the gradient composition of metallic atoms, showed larger contact stiffness and hardness. The combined MD/FE simulation indicates that the tribofilm becomes stiffer and harder due to the interdiffusion of iron and zinc atoms on the tribofilm/oxide interface. We have found that the gradient composition formation in ZDDP tribofilm during friction process influences on its mechanical properties. 相似文献
27.
Zhigang Zhu Arunabhiram Chutia Hideyuki Tsuboi Nozomu Hatakeyama Hiromitsu Takaba Momoji Kubo 《Journal of Physics and Chemistry of Solids》2009,70(9):1248-258
A theoretical study on Ru-doped rutile SnO2(1 1 0) surface has been carried out by means of periodic density functional theory (DFT) at generalized gradient approximation (GGA-RPBE) level with a periodic supercell approach. Electronic structure analysis was performed based on the band structure and partial density of states. The results provide evidence that the electronic structures of SnO2(1 1 0) surface are modified by the surface Ru dopant, in which Ru 4d orbital are located at the edge of the band gap region. It is demonstrated that molecular oxygen adsorption characteristics on stoichiometric SnO2(1 1 0) surface are changed from endothermic to exothermic due to the existence of surface Ru dopant. The dissociative adsorption of molecular oxygen on the Ru5c/SnO2(1 1 0) surface is exothermic, which indicates that Ru could act as an active site to increase the oxygen atom species on SnO2(1 1 0) surface. Our present study reveals that the Ru dopant on surface is playing both electronic and chemical role in promoting the SnO2 gas-sensing property. 相似文献
28.
Koseki N Nakashima A Nagae Y Masuda N 《Rapid communications in mass spectrometry : RCM》2006,20(5):733-740
We have developed a sensitive and specific liquid chromatography/mass spectrometry (LC/MS) method for the simultaneous determination of cyclosporine A (CsA) and its three main metabolites (AM1, AM4N and AM9) in human blood. Following protein precipitation, supernatant was directly injected into the LC/MS system. Chromatographic separation was accomplished on a Symmetry C8 (4.6 x 75 mm, 3.5 microm) column with a linear gradient elution prior to detection by atmospheric pressure chemical ionization (APCI) MS using selected ion monitoring (SIM) in positive mode. This method can be applied to single mass equipment. The analytical range for each analyte was set at 1-2500 ng/mL using 100 microL of blood sample. The analytical method was fully validated according to FDA guidance. Intra-day mean accuracy and precision were 95.2-113.5% and 0.9-8.9%, respectively. Inter-day mean accuracy and precision were 95.8-107.0% and 1.5-10.7%, respectively. In blood all analytes were stable during three freeze/thaw cycles, for 24 h at room temperature and for 12 months at or below -15 degrees C. Stability was also confirmed in processed samples for 24 h at 10 degrees C and for 6 months at 4 degrees C in methanol. In addition, we confirmed the method could avoid matrix effects from transplant subjects' samples. This LC/MS technique provided an excellent method for simultaneous quantitative determination of CsA and its three metabolites for evaluation of their pharmacokinetic profiles. 相似文献
29.
30.
M Tada S Zhang S Malwadkar N Ishiguro J Soga Y Nagai K Tezuka H Imoto S Otsuka-Yao-Matsuo S Ohkoshi Y Iwasawa 《Angewandte Chemie (International ed. in English)》2012,51(37):9361-9365
Breaking news: A unique discontinuous property and an active phase of Ni/ordered Ce(2) Zr(2) O(x) (x=7-8) solid-solution catalysts were observed during methane steam reforming. The catalytic performance of Ni/Ce(2) Zr(2) O(x) strongly depended on the phase and oxygen content of the Ce(2) Zr(2) O(x) support. 相似文献