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471.
Kamiya K Tanaka Y Endang H Umar M Satake T 《Chemical & pharmaceutical bulletin》2005,53(12):1597-1599
From the fruits of Morinda citrifolia L., one new anthraquinone, 5,15-O-dimethylmorindol, together with five known anthraquinones and one new iridoid, morindacin, together with two known iridoids, were isolated. Their structures were elucidated by analysis of spectroscopic data. 相似文献
472.
[reaction: see text] Ring-closing metathesis of ene-ynamide using the second-generation Grubbs' catalyst produced nitrogen-containing heterocycles, which have dienamide moieties, in high yields. Diels-Alder reaction of the cyclized product and dienophile proceeded smoothly to afford a bi- or tricyclic compound. 相似文献
473.
Yuichi Kamiya 《Acta Mathematica Hungarica》2006,110(1-2):51-65
Summary A. Beurling introduced the concept of spectral sets of unbounded functions to study the possibility of the approximation of
those by trigonometric polynomials. We consider spectral sets of unbounded functions in a certain class which contains the
square of the Riemann zeta-function as a typical example. 相似文献
474.
475.
Masayuki Masuko Takuji Kataoka Norikazu Sugiyama Shigeru Uchiyama Hirofumi Sugiyama Katsunori Tarui Kiyoshi Kamiya Tohru Kawai † 《Photochemistry and photobiology》1992,56(1):107-111
Abstract— We developed a photon counting TV camera system, which uses an image guide consisting of tapered optical fibers, for the rapid detection and counting of microscopic sized luminous particles in a wide field. Using a luminous bacterium as a standard, we compared this image guide-coupled TV camera to a lens-coupled TV camera by determining their light collecting powers and detection abilities for single bacteria on a membrane filter. The image guide shortened the detection time by an order of magnitude, making the photon counting TV camera a practical system for rapid counting of bacteria. 相似文献
476.
477.
H. Hiramatsu K. Ueda K. Takafuji H. Ohta M. Hirano T. Kamiya H. Hosono 《Applied Physics A: Materials Science & Processing》2004,79(4-6):1521-1523
Electrical and photoluminescence properties were investigated for epitaxial films of layered oxychalcogenides, LnCuOCh (Ln=La, Pr, and Nd, Ch=S or Se). Epitaxial films of Mg 10 at.% doped LaCuOS1-xSex are the first demonstration of degenerate conduction with high hole concentration >1020 cm-3 in wide gap p-type semiconductors. Ion substitution varied the excitonic emission energy from 3.21 eV to 2.89 eV while lanthanide and chalcogenide ion substitutions displayed the opposite tendency against cell volume. These unique properties are discussed with respect to the electronic structure originating from the layered crystal structure. PACS 72.20.-i; 73.50.-h; 78.55.Hx; 78.66.-w 相似文献
478.
H. Hiramatsu K. Ueda K. Takafuji H. Ohta M. Hirano T. Kamiya H. Hosono 《Applied Physics A: Materials Science & Processing》2004,79(4-6):1517-1520
Heteroepitaxial thin films of Cu-based oxychalcogenides, LnCuOCh (Ln=La, Pr and Nd; Ch=mixture of S and Se), were fabricated and their resulting film structures were characterized. A reactive solid-phase epitaxy method successfully yielded heteroepitaxial films on MgO(001) substrates. A high-resolution electron microscopic examination of a LaCuOS film revealed a sharp film-substrate interface. Four-axes high-resolution X-ray diffraction measurements revealed that crystalline lattices in the films are fully relaxed and that the crystallographic orientation is (001)[110] LnCuOCh || (001)[110] MgO. Furthermore, systematic variations in the lattice constant by lanthanide or chalcogen ion substitutions were observed. PACS 81.10.Jt; 81.15.-z; 81.15.Np; 68.55.-a; 81.20.-n 相似文献
479.
Y. Shimbara Y. Fujita T. Adachi G. P. A. Berg H. Fujita K. Fujita I. Hamamoto K. Hatanaka J. Kamiya K. Nakanishi Y. Sakemi Y. Shimizu M. Uchida T. Wakasa M. Yosoi 《The European Physical Journal A - Hadrons and Nuclei》2004,19(1):25-31
The mirror nuclei 25Mg and 25Al are expected to have very similar structures. The Gamow-Teller (GT) transitions from the
ground state of 25Mg to the excited states in 25Al were studied by high-resolution measurements of the 25Mg(
) charge-exchange reaction at
and at 140 MeV/nucleon. Assuming the usual
selection rule for the spin-isospin-type GT transitions, the states with
, and 7/2 + should be excited. However, of the more than ten states with these
values below 6 MeV excitation energy, only the 5/2 + ground state and the 7/2 + , 1.613 MeV state in 25Al were strongly populated, while all other states were strongly suppressed. The analysis of M1 transitions in 25Mg also suggested a very similar feature for the analogous M1 transitions. Both 25Mg and 25Al are known to be largely deformed, and most low-lying states can be interpreted in terms of one-particle quantum numbers in the deformed potential and the associated rotational spectra. The observed suppression can be explained in terms of the K quantum number selection rules that are inherent to axially deformed nuclei.-1Received: 18 July 2003, Published online: 18 December 2003PACS:
21.10.Re Collective levels - 21.60.Ev Collective models - 25.55.Kr Charge-exchange reactions - 27.30. + t
H. Fujita: Present address: Research Center for Nuclear Physics, Osaka University, Ibaraki, Osaka 567-0047, Japan.J. Kamiya: Present address: Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan.T. Wakasa: Present address: Department of Physics, Kyushu University, Higashi, Fukuoka 812-8581, Japan. 相似文献
480.
Yoshimura D Ishii H Ouchi Y Miyamae T Hasegawa S Okudaira KK Ueno N Seki K 《The Journal of chemical physics》2004,120(22):10753-10762
Theoretical simulations of the angle-resolved ultraviolet photoemission spectra (ARUPS) for the oligomer of poly(tetrafluoroethylene) [(CF(2))(n); PTFE] were performed using the independent-atomic-center approximation combined with ab initio molecular orbital calculations. Previously observed normal-emission spectra for the end-on oriented sample (with long-chain axis perpendicular to the surface) showed the incident photon-energy (hnu) dependence due to the intramolecular energy-band dispersion along the one-dimensional chain, and the present simulations successfully reproduced this hnu dependence of the observed spectra. We employed the experimentally observed helical structure for PTFE oligomers for the simulations. We also calculated the density of states (DOS) for the planar zigzag structure, and examined the changes in the electronic structure due to the difference in the molecular structure by comparing the DOS for the helical and planar zigzag structures. Only a small change in the DOS was found between these structures, showing little change of the electronic structure between these conformations. We also evaluated the inner potential V(0), which is the parameter defining the energy origin of the free-electron-like final state, and checked the validity of the value of -10 eV estimated in our previous study using the experimentally observed hnu dependence of the peak intensity. The estimation of V(0) was performed by pursuing the best agreement between the energy-band dispersion [E=E(k)] relation along the chain direction obtained from the simulated spectra and the experimentally deduced one. An excellent agreement in the topmost band was achieved when the assumed inner potential V(0) was set at about zero. This value of V(0) is much different from the value of V(0)=-10 eV in the previous study, suggesting the invalidity of the previous assumption at the estimation of V(0) from the peak intensity variation with hnu. Using the presently obtained V(0), we could derive more reliable E=E(k) dispersion relation from the observed ARUPS spectra. The comparison of this newly derived relation gave good agreement with theoretically calculated E=E(k) relations, in contrast to the poor agreement for the previous results with V(0)=-10 eV. 相似文献