全文获取类型
收费全文 | 764篇 |
免费 | 22篇 |
国内免费 | 6篇 |
专业分类
化学 | 334篇 |
晶体学 | 27篇 |
力学 | 17篇 |
数学 | 206篇 |
物理学 | 208篇 |
出版年
2023年 | 4篇 |
2022年 | 21篇 |
2021年 | 34篇 |
2020年 | 14篇 |
2019年 | 9篇 |
2018年 | 12篇 |
2017年 | 4篇 |
2016年 | 22篇 |
2015年 | 19篇 |
2014年 | 22篇 |
2013年 | 33篇 |
2012年 | 34篇 |
2011年 | 26篇 |
2010年 | 30篇 |
2009年 | 33篇 |
2008年 | 39篇 |
2007年 | 38篇 |
2006年 | 29篇 |
2005年 | 24篇 |
2004年 | 15篇 |
2003年 | 12篇 |
2002年 | 20篇 |
2001年 | 13篇 |
2000年 | 25篇 |
1999年 | 17篇 |
1998年 | 15篇 |
1997年 | 6篇 |
1996年 | 9篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 10篇 |
1988年 | 13篇 |
1987年 | 11篇 |
1986年 | 16篇 |
1985年 | 9篇 |
1984年 | 15篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 11篇 |
1978年 | 7篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1974年 | 4篇 |
1937年 | 3篇 |
1873年 | 6篇 |
排序方式: 共有792条查询结果,搜索用时 15 毫秒
71.
A generic bubble structure in a 230 kHz ultrasonic field is observed in a partly developed standing wave field in water. It is characterized by high-speed imaging, sonoluminescence recordings, and surface cleaning tests. The structure has two distinct bubble populations. Bigger bubbles (much larger than linear resonance size) group on rings in planes parallel to the transducer surface, apparently in locations of driving pressure minima. They slowly rise in a jittering, but synchronous way, and they can have smaller satellite bubbles, thus resembling the arrays of bubbles observed by Miller [D. Miller, Stable arrays of resonant bubbles in a 1-MHz standing-wave acoustic field, J. Acoust. Soc. Am. 62 (1977) 12]. Smaller bubbles (below and near linear resonance size) show a fast "streamer" motion perpendicular to and away from the transducer surface. While the bigger bubbles do not emit light, the smaller bubbles in the streamers show sonoluminescence when they pass the planes of high driving pressure. Both bubble populations exhibit cleaning potential with respect to micro-particles attached to a glass substrate. The respective mechanisms of particle removal, though, might be different. 相似文献
72.
Xi X Cegla FB Lowe M Thiemann A Nowak T Mettin R Holsteyns F Lippert A 《Ultrasonics》2011,51(8):1014-1025
The use of bubbles in applications such as surface chemistry, drug delivery, and ultrasonic cleaning etc. has been enormously popular in the past two decades. It has been recognized that acoustically-driven bubbles can be used to disturb the flow field near a boundary in order to accelerate physical or chemical reactions on the surface. The interactions between bubbles and a surface have been studied experimentally and analytically. However, most of the investigations focused on violently oscillating bubbles (also known as cavitation bubble), less attention has been given to understand the interactions between moderately oscillating bubbles and a boundary. Moreover, cavitation bubbles were normally generated in situ by a high intensity laser beam, little experimental work has been carried out to study the translational trajectory of a moderately oscillating bubble in an acoustic field and subsequent interactions with the surface. This paper describes the design of an ultrasonic test cell and explores the mechanism of bubble manipulation within the test cell. The test cell consists of a transducer, a liquid medium and a glass backing plate. The acoustic field within the multi-layered stack was designed in such a way that it was effectively one dimensional. This was then successfully simulated by a one dimensional network model. The model can accurately predict the impedance of the test cell as well as the mode shape (distribution of particle velocity and stress/pressure field) within the whole assembly. The mode shape of the stack was designed so that bubbles can be pushed from their injection point onto a backing glass plate. Bubble radial oscillation was simulated by a modified Keller–Miksis equation and bubble translational motion was derived from an equation obtained by applying Newton’s second law to a bubble in a liquid medium. Results indicated that the bubble trajectory depends on the acoustic pressure amplitude and initial bubble size: an increase of pressure amplitude or a decrease of bubble size forces bubbles larger than their resonant size to arrive at the target plate at lower heights, while the trajectories of smaller bubbles are less influenced by these factors. The test cell is also suitable for testing the effects of drag force on the bubble motion and for studying the bubble behavior near a surface. 相似文献
73.
Anna Jaśkiewicz Janusz Matkowski Andrzej S. Nowak 《Annals of Operations Research》2014,220(1):263-278
This paper generalizes the classical discounted utility model introduced in Samuelson (Rev. Econ. Stud. 4:155–161, 1937) by replacing a constant discount rate with a function. The existence of recursive utilities and their constructions are based on Matkowski’s extension of the Banach Contraction Principle. The derived utilities go beyond the class of recursive utilities studied in the literature and enable a discussion on subtle issues concerning time preferences in the theory of finance, economics or psychology. Moreover, our main results are applied to the theory of optimal economic growth related with resource extraction models with unbounded utility function of consumption. 相似文献
74.
As input flows of secondary raw materials show high volatility and tend to behave in a chaotic way, the identification of the main drivers of the dynamic behavior of returns plays a crucial role. Based on a stylized production-recycling system consisting of a set of nonlinear difference equations, we explicitly derive parameter constellations where the system will or will not converge to its equilibrium. Using a constant elasticity of substitution production function, the model is then extended to enable coverage of real world situations. Using waste paper as a reference raw material, we empirically estimate the parameters of the system. By using these regression results, we are able to show that the equilibrium solution is a Lyapunov unstable saddle point. This implies that the system is sensitive on initial conditions that will hence impede the predictability of product returns. Small variations of production input proportions could however stabilize the whole system. 相似文献
75.
M Szyrszyng E Nowak M Gdaniec M J Milewska A Herman T Po?oński 《The Journal of organic chemistry》2001,66(22):7380-7384
The crystalline inclusion complexes of cholic acid with three symmetric N-aryl-N-nitrosamines were prepared, and their X-ray structures were solved. As a result of chiral conformations adopted by the enclathrated guest nitrosamines, the solid-state CD spectra were measured in KBr disks. The observed Cotton effect sign, corresponding to the n-pi* transition, was correlated with the helicity of the twisted nitrosamine chromophore conjugated with the N-aryl substituent. In addition, the absolute configuration of the enantiomorphous crystals of N-benzyl-N-nitroso-4-chloroaniline was established on the basis of the solid-state CD and X-ray crystallographic results. 相似文献
76.
V. V. Ammosov E. N. Ardashev D. S. Baranov V. I. Hleborad A. A. Ivanilov P. V. Ivanov V. I. Konyushko V. M. Korablev V. A. Korotkov V. V. Makeev A. G. Myagkov N. A. Netyaga A. Yu. Polyarush A. A. Sokolov E. P. Kuznetsov H. -J. Grabosch H. H. Kaufmann U. Krecker R. Nahnhauer S. Nowak S. Schlenstedt H. Vogt SKAT-Collaboration 《Zeitschrift fur Physik C Particles and Fields》1986,30(2):183-189
For charged current neutrino nucleus interactions at energies below 30 GeV, resulting from an experiment with the freon filled bubble chamber SKAT,K 0 and Λ production is investigated. An estimation of the total strange and charm production cross section is made.K 0 and Λ production rates are given in dependence on different inclusive variables. The production properties forK 0′s and Λ′s are discussed in terms of the Quark-Parton-Model. Comparisons with other ν-experiments at higher energies are performed. 相似文献
77.
We propose a new scenario tree reduction algorithm for multistage stochastic programs, which integrates the reduction of a
scenario tree into the solution process of the stochastic program. This allows to construct a scenario tree that is highly
adapted on the optimization problem. The algorithm starts with a rough approximation of the original tree and locally refines
this approximation as long as necessary. Promising numerical results for scenario tree reductions in the settings of portfolio
management and power management with uncertain load are presented. 相似文献
78.
Electronic Olfactory Sensor Based on A. mellifera Odorant‐Binding Protein 14 on a Reduced Graphene Oxide Field‐Effect Transistor
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Melanie Larisika Caroline Kotlowski Christoph Steininger Rosa Mastrogiacomo Prof. Paolo Pelosi Prof. Stefan Schütz Serban F. Peteu Prof. Christoph Kleber Ciril Reiner‐Rozman Dr. Christoph Nowak Prof. Wolfgang Knoll 《Angewandte Chemie (International ed. in English)》2015,54(45):13245-13248
An olfactory biosensor based on a reduced graphene oxide (rGO) field‐effect transistor (FET), functionalized by the odorant‐binding protein 14 (OBP14) from the honey bee (Apis mellifera) has been designed for the in situ and real‐time monitoring of a broad spectrum of odorants in aqueous solutions known to be attractants for bees. The electrical measurements of the binding of all tested odorants are shown to follow the Langmuir model for ligand–receptor interactions. The results demonstrate that OBP14 is able to bind odorants even after immobilization on rGO and can discriminate between ligands binding within a range of dissociation constants from Kd=4 μM to Kd=3.3 mM . The strongest ligands, such as homovanillic acid, eugenol, and methyl vanillate all contain a hydroxy group which is apparently important for the strong interaction with the protein. 相似文献
79.
In a recent paper (Appl. Math. Comput. 215:1622–1645, 2009), the authors proposed a method of summation of some slowly convergent series. The purpose of this note is to give more theoretical analysis for this transformation, including the convergence acceleration theorem in the case of summation of generalized hypergeometric series. Some new theoretical results and illustrative numerical examples are given. 相似文献
80.
We study Riesz and Bessel potentials in the settings of Hankel transform, modified Hankel transform and Hankel-Dunkl transform. We prove sharp or qualitatively sharp pointwise estimates of the corresponding potential kernels. Then we characterize those 1 ≤ p, q≤∞, for which the potential operators satisfy L p -L q estimates. In case of the Riesz potentials, we also characterize those 1 ≤ p, q ≤ ∞, for which two-weight L p -L q estimates, with power weights involved, hold. As a special case of our results, we obtain a full characterization of two power-weight L p -L q bounds for the classical Riesz potentials in the radial case. This complements an old result of Rubin and its recent reinvestigations by De Nápoli, Drelichman and Durán, and Duoandikoetxea. 相似文献