Mass transfer limitation in thermogravimetry of biomass gasification

In order to determine the intrinsic reactivity behavior from thermogravimetry studies, the experimental conditions should be such that the reactions are not mass transfer limited. Biomass char usually has a higher reactivity than coal chars. Therefore, mass transfer limitations may be more problematic when studying biomass char reactivity. Chemical reaction kinetics and mass transfer processes present in thermogravimetry are used for modeling the overall reaction rate for spruce bark CO₂ gasification. Thermogravimetric experiments are carried out between 700 and 900 °C, and the CO₂ concentration is varied between 10 and 90 vol%. The intrinsic activation energy is found to be 120 kJ mol^?1. The transition temperature between regimes I and II is here defined when the fraction apparent to true activation energy equals 0.75. Higher external mass transfer (e.g., by decreasing the diffusion path through the crucible’s freeboard), decreasing the sample amounts, and higher CO₂ partial pressures for the Langmuir–Hinshelwood reaction type increase the transition temperature. The results show that the transition temperature between regimes I and II conditions is approx. 1,030 °C for 90 vol% CO₂.     

Conditional weak compactness in vector-valued function spaces

Let be an ideal of over a -finite measure space and let be the Köthe dual of with . Let be a real Banach space, and the topological dual of . Let be a subspace of the space of equivalence classes of strongly measurable functions and consisting of all those for which the scalar function belongs to . For a subset of for which the set is -bounded the following statement is equivalent to conditional -compactness: the set is conditionally -compact and is a conditionally weakly compact subset of for each , with . Applications to Orlicz-Bochner spaces are given.

     

Strong topologies on vector-valued function spaces

Let be a real Banach space and let E be an ideal of L ⁰ over a -finite measure space (, , ). Let (X) be the space of all strongly -measurable functions f: X such that the scalar function , defined by , belongs to E. The paper deals with strong topologies on E(X). In particular, the strong topology the order continuous dual of E(X)) is examined. We generalize earlier results of [PC] and [FPS] concerning the strong topologies.     

Stochastic Lagrangian Relaxation Applied to Power Scheduling in a Hydro-Thermal System under Uncertainty

A dynamic (multi-stage) stochastic programming model for the weekly cost-optimal generation of electric power in a hydro-thermal generation system under uncertain demand (or load) is developed. The model involves a large number of mixed-integer (stochastic) decision variables and constraints linking time periods and operating power units. A stochastic Lagrangian relaxation scheme is designed by assigning (stochastic) multipliers to all constraints coupling power units. It is assumed that the stochastic load process is given (or approximated) by a finite number of realizations (scenarios) in scenario tree form. Solving the dual by a bundle subgradient method leads to a successive decomposition into stochastic single (thermal or hydro) unit subproblems. The stochastic thermal and hydro subproblems are solved by a stochastic dynamic programming technique and by a specific descent algorithm, respectively. A Lagrangian heuristics that provides approximate solutions for the first stage (primal) decisions starting from the optimal (stochastic) multipliers is developed. Numerical results are presented for realistic data from a German power utility and for numbers of scenarios ranging from 5 to 100 and a time horizon of 168 hours. The sizes of the corresponding optimization problems go up to 200000 binary and 350000 continuous variables, and more than 500000 constraints.     

Diluted antiferromagnets in exchange bias: proof of the domain state model

The exchange bias coupling at ferromagnetic/antiferromagnetic interfaces in epitaxially grown Co/CoO layers can intentionally be increased by a factor of up to 3 if the antiferromagnetic CoO layer is diluted by nonmagnetic defects in its volume part away from the interface. Monte Carlo simulations of a simple model of a ferromagnetic layer on a diluted antiferromagnet show exchange bias and explain qualitatively its dilution and temperature dependence. These investigations reveal that diluting the antiferromagnet leads to the formation of volume domains, which cause and control exchange bias.     

Atmospheric plasma treatment of pre‐electrospinning polymer solution: A feasible method to improve electrospinnability

The electrospinnability of polyethylene oxide (PEO) was manipulated by atmospheric plasma treatment of pre‐electrospinning solutions. Conductivity, viscosity, and surface tension of PEO solutions increased after plasma treatment, and the plasma effect remained longer when the solution concentrate increased. Both untreated and treated solutions were then electrospun, and the morphology of the resultant nanofibers was observed by SEM. Atmospheric plasma treatment improved the electrospinnability of PEO solutions and led to less beads and finer diameter distribution in the resultant nanofibers. Additionally, plasma treatment of the pre‐electrospinning solutions affected the crystal structure of resultant nanofibers. These results suggest that atmospheric plasma treatment is a feasible approach to improve the electrospinnability of polymer solutions and can used to control the structure of electrospun nanofibers. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011     

Spacer-modified stationary phases for anion chromatography: Alkyl- and carbonylalkylspacers – A comparison

A comparison of two separation columns for high-capacity anion chromatography is presented. The distinctive feature of both packing materials is the structure of the alkyl-chain (spacer-group) between the polymer-backbone and the functional group. All other parameters, e.g. exchange capacity, functionality and length of the spacer-arm, are identical. The retention behavior of the so-called standard-anions is investigated on both columns under identical chromatographic conditions using an experimental design technique in the course of which the composition of the elution system applied is varied. The statistical treatment of the retention data offers the possibility to explain the different chromatographic behavior of both stationary phases, at least qualitatively.     

Meromorphic univalent functions in an annulus

We consider the integral means for the class of functions which are meromorphic and univalent in an annulus.