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901.
The properties of p-type ZnGeP2 [p0=(5–10)·1010 cm–3, 0=(2–5)·10–7 (·cm)–1], irradiated with H+ ions [E=5 MeV, Tirr=300 K, D=(1·1012–1.7·1016) cm–2] are studied. An increase in the resistivity (to grmax - 5·1011 ·cm) and subsequent reduction in for large currents of H+ ions ( - 9·108 ·cm for D - 1.7·1016 cm–2), is observed in irradiated crystals. The resistivity of irradiated p-type ZnGeP2 is found to be very sensitive to hydrostatic pressure [(4–5)·10–5 bar–1]. The annealing of radiation defects in the temperature interval (20–600) °C is examined.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 91–93, October, 1991. 相似文献
902.
Conclusions The condensation of 2, 2-dinitro-1, 3-propanediol with pyrazineacetic acid esters leads to the formation of the esters of 4, 4-dinitropyrazolidine-2-acetic acid, which are spontaneously converted to the esters of 4-nitropyrazole-1-acetic acid.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2333–2334, October, 1972. 相似文献
903.
Summary We have suggested an improved method for preparing , -dinitroalkanes which consists in the action of silver nitrite on , -dibromoalkanes in petrofeum ether medium with heating. 相似文献
904.
V. A. Nikanorov S. V. Sergeev S. G. Novikov P. V. Petrovskii 《Russian Chemical Bulletin》1998,47(10):2012-2014
η4-endo-(17α,21-dihydroxypregna-1,4-diene-3,11,20-trione)-(η5-cyclopentadienyl)rhodium(I) was synthesized by successive treatment of 17α,21-dihydroxypregna-1,4-diene-3,11,20-trione with [(C2H4)2RhCl]2 and CpT1 in a yield of 54%.1H NMR studies demonstrated that coordination of the organometallic moiety occurs from the side opposite to the 19-CH3 group. Upon coordination, ringA of the prednisone ligand is fixed to adopt a boat conformation, and the basicity of the 3-CO group increases substantially. 相似文献
905.
Summary A mixture of nitric acid and acetic anhydride with a nitric acid content of 80 moles per cent has a considerably more powerful nitrating action than a mixture with 35–50 moles per cent of nitric acid. It is desirable to use this mixture for the nitration of furans with low sensitivity to electrophilic attack.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 103–110, January, 1965 相似文献
906.
Chemistry of Natural Compounds - It has been shown that the dehydration of the sesquiterpene lactone coronopilin with SOCl2 forms Δ1(2)-anhydrocoronopilin. The configuration of the methyl... 相似文献
907.
An algorithm is proposed to construct the righthand sides and the Jacobian matrix for a set of differential equations and a heat balance equation in terms of a given kinetic mechanism of a chemical reaction in a non-isothermal, constant-volume reactor. Its application is illustrated by the calculation of the dependence of the carbon monoxide explosion limit on the concentration of hydrogen added.
. .相似文献
908.
S. S. Novikov A. A. Fainzil'berg S. N. Shvedova V. I. Gulevskaya 《Russian Chemical Bulletin》1960,9(11):1908-1910
Summary Gem-dinitroalkanes condense readily with acetaldehyde, propionaldehyde, butyraldehyde, and amines. The use of these aldehydes instead of formaldehyde extends the field of application of the Mannich reaction with nitro compounds. 相似文献
909.
Tataurov A. V. Meteleva Yu. V. Sermakasheva N. L. Novikov G. F. 《Russian Chemical Bulletin》2003,52(5):1201-1203
The transient decay kinetics of electrons generated in thin cadmium sulfide films by short laser pulses was studied by the microwave photoconductivity method (9 and 36 GHz) at 295 K. The films were prepared by the pulverization method from thiocarbamide coordination compounds. At the high light intensity I
0 > 1014 photon cm–2 per pulse, the decay kinetics of photoelectrons corresponded to a reaction of the second order. Analysis of the kinetic data made it possible to determine the rate constant of recombination of free electrons and holes: k
3 2(±1)·10–13 cm3 s–1. 相似文献
910.
The reaction of difluorocarbene with azirines affords a new type of azomethine ylides, viz., strained aziriniodifluoromethanides. 1,3-Dipolar cycloadditions of ylides derived from 2-unsubstituted 3-arylazirines to dimethyl acetylenedicarboxylate and aldehydes give derivatives of 2,2-difluoro-1-azabicyclo[3.1.0]hex-3-ene-3,4-dicarboxylic acids and 1,4-oxazin-3(4H)-ones, respectively. Ylides derived from 2-mono- and 2,2-disubstituted azirines undergo isomerization to 2-aza-1,3-diene derivatives. 2,2-Difluoro-1-azabicyclo[3.1.0]hex-3-enes are transformed into 2-fluoropyridine derivatives in high yields and react with amines to give 2,4-diamino-1-azabicyclo[3.1.0]hex-2-ene derivatives. 相似文献