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81.
The electrochemical behavior of sulfaguanidine was investigated in PBS buffer aqueous solutions. Cyclic voltammograms have shown that (1) the Sg provided a well-defined irreversible oxidation peak (2) the signal-to-background current ratio is 3 times higher at COOH-MWCNT coated GCE than that of bare GCE and (3) the modifying GCE surface by COOH-MWCNT led to a significant improvement (2.7 folds) of the electrochemical response. It has been shown that Sg oxidizes according to a diffusion-controlled mechanism. A linear calibration curve was obtained for the oxidation of Sg at 10–70 μM. The COOH-MWCNT coated GCE has also been successfully used for the determination of Sg in real samples. 相似文献
82.
An amperometric chemosensor for the detection of hydrogen peroxide is reported. The sensor is based on 1,4-benzoquinone immobilized on the gold electrode using self-assembled monolayer of short chain symmetrical dithiol as an anchor layer. Sensor analysis was performed by cyclic voltammetry at the potential range from −0.6 V till +0.9 V as well as in the anodic or cathodic potential ranges only. The results indicate oxidative electrochemical decomposition of hydrogen peroxide at the potential of ∼+0.4 V leading to the formation of oxygen while at cathodic potentials a reduction of the formed oxygen as well as of the hydrogen peroxide occur. A decrease in the oxidation potential of hydrogen peroxide on the gold electrode coated by self-assembled monolayer with 1,4-benzoquinone in comparison with that measured on the electrodes coated by the same self-assembled monolayer without 1,4-benzoquinone, indicates electrocatalytic effect of this moiety on oxidative decomposition of hydrogen peroxide. Analytical evaluation of the sensor performance was done in the voltammetric as well as in the chronoamperometric mode. The sensor exhibited linear response over the concentration range till 2.5 mM with a limit of detection ∼4 μM. 相似文献
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84.
Douglas R. Lyon Jr. Bryan R. Smith Noureddine Abidi Julia L. Shamshina 《Molecules (Basel, Switzerland)》2022,27(13)
The isolation of chitin utilizing ionic liquid 1-ethyl-3-methylimidazolium acetate has been determined to result in polymer contaminated with proteins. For the first time, the proteins in chitin extracted with ionic liquid have been quantified; the protein content was found to vary from 1.3 to 1.9% of the total weight. These proteins were identified and include allergenic proteins such as tropomyosin. In order to avoid ‘traditional’ hydroxide-based deproteinization of chitin, which could reduce the molecular weight of the final product, alternative deproteinization strategies were attempted. Testing of the previously reported deproteinization method using aqueous K3PO4 resulted in protein reduction by factors varying from 2 to 10, but resulted in significant phosphate salt contamination of the final product. Contrarily, the incorporation of GRAS (Generally Recognized as Safe) compound Polysorbate 80 into the polymer washing step provided the polymer of comparable purity with no contaminants. This study presents new options for the deproteinization of chitin that can replace traditional approaches with methods that are environmentally friendly and can produce high purity polymer. 相似文献
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Experiments are carried out in the wake of a cylinder of d
c
= 10 mm diameter placed symmetrically between two parallel walls with a blockage ratio r = 1/3 and a Reynolds number varying between 75 ≤ Re ≤ 277. Particle image velocimetry is exerted to obtain the instantaneous velocity components in the cylinder wake. A snapshot
proper orthogonal decomposition (POD) is also applied to these PIV results in order to extract the dominant modes through
the implementation of an inhomogeneous filtering of these different snapshots, apart from an interpolation to estimate the
wall shear rate at the lower wall downstream the cylinder. Mass transfer circular probes are placed at the lower wall downstream
this obstacle so as to further determine the time evolution of the wall shear rate, by bringing the inverse method to bear
on the convective-diffusion equation. Comparisons between the two synchronized techniques demonstrate that electrochemical
method can give more accurate information about the coherent structures present in the flow and about the interaction of the
von Kármán vortices with the walls of the tunnel as well. The comparison between the two measurement techniques in the flow
regions concerns the spatiotemporal evolutions of the wall shear rate obtained from PIV measurements and the wall shear rate
using mass transfer probes. Discrepancy between the PIV measurements and the electrochemical ones near the wall, where the
secondary vortices P
1′ are generated at wall, are caused by a PIV bias and a limitations of the singular mass transfer probes. 相似文献
88.
Amel Bendali-Braham Noureddine Ikhlef-Eschouf Mostafa Blidia 《Comptes Rendus Mathematique》2018,356(2):115-120
The b-chromatic number of a graph G is the largest integer k such that G admits a proper coloring with k colors for which each color class contains a vertex that has at least one neighbor in all the other color classes. A graph G is called -critical if the contraction of any edge e of G decreases the b-chromatic number of G. The purpose of this paper is the characterization of all -critical trees. 相似文献
89.
Dr. Khouloud Hchicha Dr. Noureddine Mhadhbi Dr. Ahlem Guesmi Dr. Taoufik Soltani Dr. Naoufel Ben Hamadi Prof. Houcine Naïli 《欧洲无机化学杂志》2023,26(13):e202200696
S-substituted La2Mo2O9 were synthesized by a solid-state procedure employing ammonium sulfate (NH4)2SO4 as a sulfur source. The synthesized powders were examined using X-ray diffraction (XRD), thermogravimetric analysis (TGA), infrared, and Raman spectroscopies. The results divulged that the stabilization of the β-La2Mo2O9 polymorph occurred in the interval of sulfur composition 0.1≤y≤0.6. This substitution generates a linear dwindling of the unit cell volume. The decomposition of all substituted samples started above 900 °C with a total weight loss linearly dependent on the sulfur content. Electrical studies confirmed that substituting S6+ for Mo6+ suppresses the phase transition of La2Mo2O9 and stabilizes the cubic polymorph down to ambient temperature. It was also remarkable that this substitution caused a decrease in the conductivity, and unfortunately, none of the tested compositions allowed exceeding the conductivity of La2Mo2O9. Infrared and Raman spectra confirmed the presence of the characteristic peaks of sulfates and molybdates groups. 相似文献
90.