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61.
Młotkowski Wojciech Sakuma Noriyoshi Ueda Yuki 《Journal of statistical physics》2020,178(5):1055-1075
Journal of Statistical Physics - We study properties of the Fuss–Catalan distributions $$\mu (p,r)$$, $$p\ge 1$$, $$01$$ there exists $$r_{0}(p)$$, with $$p-1 相似文献
62.
63.
Photoirradiation of α-arylthiophene derivatives linked with an alkene moiety through a three-atom spacer gave unprecedented cyclobutene-fused perhydrothiapentalene-type compounds in high yields, but neither [2 + 2] nor [4 + 2] cycloaddition products. The reaction afforded a single diastereomer in many cases. The chemical structure and relative configuration of a typical product were unambiguously determined by X-ray crystallographic analysis. 相似文献
64.
Ogoshi T Ueshima N Yamagishi TA Toyota Y Matsumi N 《Chemical communications (Cambridge, England)》2012,48(29):3536-3538
A room-temperature ionic liquid containing macrocyclic compound pillar[5]arene in its core was synthesized. The ionic liquid showed high thermal stability, moderate ionic conductivity and solvent-free complexation ability with the guest tetracyanoethylene. 相似文献
65.
[reaction: see text] A catalyst system consisting of RuCl2[(S)-tolbinap][(R)-dmapen] and t-C4H9OK in 2-propanol effects asymmetric hydrogenation of arylglyoxal dialkylacetals to give the alpha-hydroxy acetals in up to 98% ee. Hydrogenation of racemic alpha-amidopropiophenones under dynamic kinetic resolution predominantly gives the syn alcohols in up to 99% ee and >98% de, while the reaction of racemic bezoin methyl ether gives the anti alcohols in excellent stereoselectivity. 相似文献
66.
Matsumura K Arai N Hori K Saito T Sayo N Ohkuma T 《Journal of the American Chemical Society》2011,133(28):10696-10699
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and base-labile ketones are smoothly converted to the corresponding alcohols in high enantioselectivity. The catalytic cycle for this hydrogenation, in which the ruthenabicyclic structure of the catalyst is maintained, is proposed on the basis of the deuteration experiment and spectroscopic analysis data. 相似文献
67.
Okuma K Matsunaga N Nagahora N Shioji K Yokomori Y 《Chemical communications (Cambridge, England)》2011,47(20):5822-5824
An efficient route to a variety of 2-phenylindolin-3-ones from amino acid methyl esters has been developed. The reaction of amino acid methyl esters with benzyne prepared from 2-(trimethylsilyl)phenyl triflate and CsF gave 2-phenylindolin-3-ones in moderate to good yields. 相似文献
68.
A new type of rotating anticathode X-ray generator, where an electron beam of up to 60 keV irradiates the inner surface of a U-shaped Cu anticathode, has achieved a beam brilliance of 130 kW mm(-2) (at 2.3 kW). A higher-flux electron beam is expected from simulation by optimizing the geometry of a combined-function-type magnet instead of the fringing field of the bending magnet. In order to minimize the size of the X-ray source the electron beam has been focused over a short distance by a new combined-function bending magnet, whose geometrical shape was determined by simulation using the Opera-3D, General Particle Tracer and CST-STUDIO codes. The result of the simulation clearly shows that the role of combined functions in both the bending and the steering magnets is important for focusing the beam to a small size. FWHM sizes of the beam are predicted by simulation to be 0.45 mm (horizontal) and 0.05 mm (vertical) for a 120 keV/75 mA beam, of which the effective brilliance is about 500 kW mm(-2) on the supposition of a two-dimensional Gaussian distribution. High-power tests have begun using a high-voltage 120 kV/75 mA power supply for the X-ray generator instead of 60 kV/100 mA. The beam focus size on the target will be verified in the experiments. 相似文献
69.
Kentaro Okuma Kazunori Munakata Toshiaki Tsubota Masayuki Kanto Noriyoshi Nagahora Kosei Shioji Yoshinobu Yokomori 《Tetrahedron》2012,68(31):6211-6217
Cyclic polysulfanes containing a norbornane skeleton (tetrathiins and pentathiepins) were synthesized by two methods. One is the sulfurization of camphor hydrazone with disulfur dichloride, and the other is the reaction of thiocamphor with disulfur dichloride. The reduction of tetrathiin with LiEt3BH gave the corresponding dithiol that further reacted with methyl iodide to afford the corresponding methyl sulfide. Reaction of tetrathiin with (Ph3P)2PdCl2 or NiBr2 resulted in the formation of the corresponding dithiolene metal complexes. Tetrathiins were stereoselectively oxidized by m-CPBA to afford the corresponding α-disulfines. 相似文献
70.
Development of highly active catalysts has been an important research area in synthetic chemistry, especially from a practical point of view. Herein, we focus on the homogeneous catalytic hydrogenation using well‐defined molecular catalysts and discuss recent advances in the field with regard to the turnover number for these catalysts. DOI 10.1002/tcr.201100019 相似文献