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We fabricate mesoporous silica/epoxy polymer composites through a solvent evaporation process. The easy penetration of the epoxy polymers into mesopores is achieved by using a diluted polymer solution including a volatile organic solvent. After the complete solvent evaporation, around 90% of the mesopores are estimated to be filled with the epoxy polymer chains. Here we carefully investigate the thermal expansion behavior of the obtained mesoporous silica/polymer composites. Thermal mechanical analysis (TMA) charts revealed that coefficient of linear thermal expansion (CTE) gradually decreases, as the amount of the doped mesoporous silica increases. Compared with spherical silica particle without mesopores, mesoporous silica particles show a greater effect on lowering the CTE values. Interestingly, it is found that the CTE values are proportionally decreased with the decrease of the total amount of the polymers outside the mesopores. These data demonstrate that polymers embedded inside the mesopores become thermally stable, and do not greatly contribute to the thermal expansion behavior of the composites. 相似文献
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Norihiro Kamide 《Mathematical Logic Quarterly》2005,51(6):579-585
The logic just corresponding to (non‐commutative) involutive quantales, which was introduced by Wendy MacCaull, is reconsidered in order to obtain a cut‐free sequent calculus formulation, and the completeness theorem (with respect to the involutive quantale model ) for this logic is proved using a new admissible rule. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
66.
Norihiro Kamide 《International Journal of Theoretical Physics》2005,44(4):399-428
Completeness and cut-elimination theorems are proved for some Gentzen-type sequent calculi which are closely related to non-commutative involutive quantales. 相似文献
67.
K. Umeda T. Yamaya T. Suehiro K. Takimoto R. Wada E. Takada S. Shimoura A. Sakaguchi S. Murakami M. Fukada Y. Okuma 《Nuclear Physics A》1984,429(1):88-104
The differential cross sections for the (d, 6Li) reaction on targets of 12C, 16O, 24Mg, 40Ca, 58Ni and 94Mo have been measured at Ed = 54.2 MeV. The measured angular distributions have been analyzed by finite-range DWBA calculations, and spectroscopic factors for an α-cluster transfer have been extracted. In the DWBA analysis using an optical model with a phenomenological Woods-Saxon potential, the spin-orbit part of the deuteron optical potential played a significant role in reproducing the measured angular distributions but the spin-orbit part of the 6Li optical potential had a minor effect. Relative spectroscopic factors extracted from the present data were compared with theoretical predictions together with the results from the (p, pα) reaction. The relative spectroscopic factors for 1p-shell nuclei were in quantitative agreement with theoretical predictions. However, there were certain discrepancies between the spectroscopic factors extracted from the (d, 6Li) reaction and those from the (p, pα) reaction, and the discrepancies increased with target mass number. 相似文献
68.
Peter Cirkel Takashi Kato Norihiro Mizoshita Henri Jagt Kenji Hanabusa 《Liquid crystals》2004,31(12):1649-1653
Liquid crystalline physical gels have been prepared in a super twisted nematic configuration. These gels show a remarkable increase in switching speed from the in field to out of field relaxation. We explore whether these gels might be used in fast passive matrix displays. 相似文献
69.
Non-stereospecific ring expansions of 3-acetylbenzothiazoline sulfoxides to benzothiazines from the reaction with acetic anhydride are reported. 相似文献
70.
Ochiai M Nishi Y Mori T Tada N Suefuji T Frohn HJ 《Journal of the American Chemical Society》2005,127(30):10460-10461
Reported here for the first time are the synthesis, isolation, and characterization of hypervalent beta-haloalkenyl-lambda3-bromanes. Exposure of terminal alkynes to p-trifluoromethylphenyl(difluoro)-lambda3-bromane activated by BF3-i-Pr2O resulted in fluoro-lambda3-bromanation of the triple bonds in a Markovnikov fashion, yielding (E)-beta-fluoroalkenyl-lambda3-bromanes stereoselectively in good yields. 5-Chloro-1-pentynes undergo domino lambda3-bromanation-chlorine shift-fluorination or lambda3-bromanation-chlorine shift-alkyl shift-fluorination reaction, depending on the substituents and afford (E)-beta-chloroalkenyl-lambda3-bromanes stereoselectively in high yields. The beta-chloroalkenyl-lambda3-bromanes contain three kinds of halogen atoms, F, Cl, and Br, in the molecule. 相似文献