Corelationship between local structure and water purifying ability of iron-containing waste glasses

A relationship between the structure and water purifying ability of waste glass prepared from household garbage and Fe₂O₃ was examined by ⁵⁷Fe-Mössbauer and induced coupled plasma (ICP) measurements. From the Debye temperature of waste glass, Fe^II proved to be loosely bound in the glass network as a network modifier. Dissolution amount of Fe^III into artificial drain can be controlled from 0.14 to 0.35 mg/l by changing the Fe₂O₃ content. It proved that chemical oxygen demand (COD) decreases in proportion to the content of Fe^III, indicating that iron causes decomposition of organic and phosphorus compounds.     

Measurement of Principal-Stress Directions from Photoelastic Experiment Using Generalized Phase-Shift Method

A generalized phase-shift method is developed for automatic measurement of principal-stress directions in the whole field of a model from photoelastic experiments. This method uses a set of light intensities obtained from the rotation of polaroids in dark-field plane polariscopes at each point. To investigate the accuracy of the measurement, time-series light intensity curves with different noise and different numbers of data which constitute the curves are used in computer simulation. The error of the measurement of the principal-stress directions obtained by the method is not greatly affected by noise when the number of data exceeds 50. This method is applied to a circular disk subjected to a concentrated load. The principal-stress directions obtained by the method are found to be in good agreement with the theory.Presented at 1996 International Workshop on Interferometry (IWI ‘96), August 27–29, Saitama, Japan.     

Electronic specific heat for the Anderson model

The expression of the electronic specific heat for the symmetric Anderson model is obtained in closed form.     

Negative theta-pinch experiment

Plasma temperature obtained with a negative theta-pinch experiment is somewhat lower than that with an ordinary thete-pinch. This is consistent with a numerical calculation assuming Sagdeev resistivity.     

Alkynes as activators in the nickel-catalysed addition of organoboronates to aldehydes

Alkynes act not as substrates but as co-catalysts in the presence of a nickel catalyst, an organoboronate and an aldehyde to promote the addition reaction between the substrates in combination with H2O.     

Organogel of an 8-quinolinol platinum(II) chelate derivative and its efficient phosphorescence emission effected by inhibition of dioxygen quenching

A newly synthesized 8-quinolinol platinum(II) chelate derivative gelates various organic solvents, and the gel formed shows unique thermo- and solvatochromism of visible and phosphorescent colour in response to a sol-gel phase transition and possesses an attractive ability to inhibit dioxygen quenching of excited triplet states.