全文获取类型
收费全文 | 3429篇 |
免费 | 80篇 |
国内免费 | 18篇 |
专业分类
化学 | 2379篇 |
晶体学 | 41篇 |
力学 | 31篇 |
数学 | 138篇 |
物理学 | 938篇 |
出版年
2022年 | 26篇 |
2020年 | 33篇 |
2019年 | 49篇 |
2018年 | 25篇 |
2017年 | 29篇 |
2016年 | 60篇 |
2015年 | 60篇 |
2014年 | 70篇 |
2013年 | 158篇 |
2012年 | 153篇 |
2011年 | 169篇 |
2010年 | 111篇 |
2009年 | 109篇 |
2008年 | 176篇 |
2007年 | 163篇 |
2006年 | 193篇 |
2005年 | 153篇 |
2004年 | 161篇 |
2003年 | 141篇 |
2002年 | 111篇 |
2001年 | 94篇 |
2000年 | 71篇 |
1999年 | 43篇 |
1998年 | 34篇 |
1997年 | 34篇 |
1996年 | 51篇 |
1995年 | 49篇 |
1994年 | 35篇 |
1993年 | 49篇 |
1992年 | 57篇 |
1991年 | 42篇 |
1990年 | 30篇 |
1989年 | 36篇 |
1988年 | 44篇 |
1987年 | 35篇 |
1986年 | 25篇 |
1985年 | 72篇 |
1984年 | 61篇 |
1983年 | 41篇 |
1982年 | 50篇 |
1981年 | 43篇 |
1980年 | 38篇 |
1979年 | 36篇 |
1978年 | 39篇 |
1977年 | 38篇 |
1976年 | 34篇 |
1975年 | 29篇 |
1974年 | 18篇 |
1973年 | 30篇 |
1966年 | 17篇 |
排序方式: 共有3527条查询结果,搜索用时 15 毫秒
161.
Jun-Ichi Yamada 《Optical and Quantum Electronics》1982,14(2):183-187
A simple method for measuring dispersion in long-span single-mode fibre, by using directly modulated multi-longitudinal mode semiconductor lasers, is proposed. Experimental values for single-mode fibre dispersion over a 44.3km span at 1.1 and 1.5m are 19 and 17 ps km–1 nm–1, respectively, and are in good agreement with Gloge's theory. The zero-dispersion wavelength estimated from the experimental results is about 1.28m, 8 nm shorter than the theoretical value. 相似文献
162.
Cluster size effects of SiO2 thin film formation with size-selected O2 gas cluster ion beams (GCIBs) irradiation on Si surface were studied. The cluster size varied between 500 and 20,000 molecules/cluster. With acceleration voltage of 5 kV, the SiO2 thickness was close to the native oxide thickness by irradiation of (O2)20,000 (0.25 eV/molecule), or (O2)10,000 (0.5 eV/molecule). However, it increased suddenly above 1 eV/molecule (5000 molecules/cluster), and increased monotonically up to 10 eV/molecule (500 molecules/cluster). The SiO2 thickness with 1 and 10 eV/molecule O2-GCIB were 2.1 and 5.0 nm, respectively. When the acceleration voltage was 30 kV, the SiO2 thickness has a peak around 10 eV/molecule (3000 molecules/cluster), and it decreased gradually with increasing the energy/molecule. At high energy/molecule, physical sputtering effect became more dominant process than oxide formation. These results suggest that SiO2 thin film formation can be controlled by energy per molecule. 相似文献
163.
C.-B. Moon T. Komatsubara Y. Sasaki T. Jumatsu K. Yamada K. Satou K. Furuno 《The European Physical Journal A - Hadrons and Nuclei》2002,14(1):13-16
Excited states of the 119Xe nucleus have been studied by using in-beam γ-ray spectroscopy with the 107Ag ( 16O, p3n) 119Xe fusion-evaporation reaction at a beam energy of 85 MeV. The level scheme of 119Xe has been derived from γ-γ coincidence and γ-γ angular correlation analyses. We have, for the first time, established the
second negative-parity favored and unfavored states built on the 11/2- state, namely the yrare rotational bands in 119Xe. In contrast to the behavior of the yrast bands where the favored states are lying lower in energy, the yrare favored states
were observed to lie above the unfavored band. Such a signature inversion in 119Xe is changed to be normal at I = 12?.
Received: 8 January 2002 / Accepted: 18 April 2002 相似文献
164.
A pressure sensitive paint (PSP) measurement has been known as a pressure field measurement technique based on the oxygen quenching phenomenon of luminescence of specific luminophores. A PSP measurement was applied for pressure field measurement in a low-solidity circular cascade diffuser of a single-stage transonic centrifugal compressor with 5 in pressure ratio for HFC134a gas. The oxygen concentration was about 500 ppm. Ru (bath-phen) was adsorbed on a silica-gel thinlayer chromatography sheet, and the sheet was pasted onto the side-wall between the cascade vanes. A drastic change in luminescent intensity was recognized during a surge condition. Also the pressure variations based on luminescent intensity agreed well with the pressure fluctuations measured using a semiconductor pressure sensor with high-frequency-response. It was shown that a PSP measurement worked well to investigate the unsteady pressure fields in a circular cascade diffuser of a transonic centrifugal compressor. Moreover, the time response of PSP becomes clear as a problem to be overcome for the present. 相似文献
165.
The existence of a stripe-liquid phase in a layered nickelate, La(1.725)Sr(0.275)NiO(4), is demonstrated through neutron scattering measurements. We show that incommensurate magnetic fluctuations evolve continuously through the charge-ordering temperature, although an abrupt decrease in the effective damping energy is observed on cooling through the transition. The energy and momentum dependence of the magnetic scattering are parametrized with a damped-harmonic-oscillator model describing overdamped spin waves in the antiferromagnetic domains defined instantaneously by charge stripes. 相似文献
166.
Transverse wave generation mechanism in rotating detonation 总被引:2,自引:0,他引:2
Yuho Uemura A. Koichi Hayashi Makoto Asahara Nobuyuki Tsuboi Eisuke Yamada 《Proceedings of the Combustion Institute》2013,34(2):1981-1989
Detonation engines are expected to be included in a number of aerospace thrusters in the future. Several types of detonation engines are currently under examination, including the rotating detonation engine (RDE). Although the RDE has been explored experimentally, its rotating detonation propagation mechanism is not well understood. This paper clarifies the detonation mechanism and dynamics of the RDE by 2D and 3D simulation using compressible Euler equations with a full chemical reaction mechanism of H2/O2 and H2/Air, especially from the triple-point and transverse detonation points of view. A total variation diminishing (TVD) scheme is used for the mixture of H2/Air, and an advection upwind splitting method difference vector (AUSMDV) scheme is used for the mixture of H2/O2. The use of an AUSMDV scheme provides a much clearer detonation structure than does the TVD scheme. We focus on the complex interaction mechanism of the detonation front and burned mixture gases. We found out that at this interaction point, an unreacted gas pocket appears and ignites periodically to generate transverse waves at the detonation front and maintain detonation propagation. 相似文献
167.
Kohei Tada Kohei Sakata Satoru Yamada Kazuyuki Okazaki Yasutaka Kitagawa Takashi Kawakami 《Molecular physics》2014,112(3-4):365-378
Residual chlorines, which originate from HAuCl4, enhance the aggregation of gold (Au) nanoparticles and clusters, preventing the generation of highly active supported Au catalysts. However, the detailed mechanism of residual-chlorine-promoted aggregation of Au is unknown. Herein to investigate this mechanism, density functional theory (DFT) calculations of Au and Cl adsorption onto a reduced rutile TiO2 (110) surface were performed using a generalised gradient approximation Perdew, Burke, and Ernzerhof formula (GGA–PBE) functional and plane-wave basis. Although both Au and Cl atoms prefer to mono-absorb onto oxygen defect sites, Cl atoms have a stronger absorption onto a reduced TiO2 (110) surface, abbreviated as rTiO2 (110) in the following, than Au atoms. Additionally, co-adsorption of a Cl atom and a Au atom or Au nanorod onto a rTiO2 surface was investigated; Cl adsorption onto an oxygen defect site weakens the interaction between a Au atom or Au nanorod and rTiO2 (110) surface. The calculation results suggest that the depletion of interaction between Au and rTiO2 surface is due to strong interaction between Cl atoms at oxygen defect sites and neighbouring bridging oxygen (OB) atoms. 相似文献
168.
H. Yonemura S. Moribe K. Hayashi M. Noda H. Tokudome S. Yamada H. Nakamura 《Applied magnetic resonance》2003,23(3-4):289-307
Photoinduced intramolecular electron-transfer reactions in carbazole (Cz)-fullerene (C60) (Cz(8)C60) and phenothiazine (Ph)-C60 (Ph(n)C60 (n=8, 10, 12)) linked compounds have been investigated in benzene and benzonitrile by fluorescence, transient absorption, and time-resolved electron paramagnetic resonance measurements, and by magnetic field effects on the decay rate constants of the photogenerated biradicals. In benzonitrile, photoinduced intramolecular electron transfer from Cz to the singlet excited state of C60 (1C60 *) occurred in Cz(8)C60, but not to the triplet excited state (3C60 *), while the intramolecular electron-transfer to both1C60 * and3C60 * occurred in Ph(n)C60 (n=8, 10, 12). In benzene, on the other hand, no electron transfer to both1C60 * and3C60 * took place in all linked compounds. These results were interpreted in terms of the different Gibbs free energy changes in the two solvents. 相似文献
169.
170.
Chikashi Shinagawa Yusuke Morikawa Shin-ichi Nishimura Hiroshi Ushiyama Atsuo Yamada Koichi Yamashita 《Journal of computational chemistry》2019,40(1):237-246
Na2FePO4F is a promising cathode material for a Na-ion battery because of its high electronic capacity and good cycle performance. In this work, first principle calculations combined with cluster expansion and the Monte Carlo method have been applied to analyze the charge and discharge processes of Na2FePO4F by examining the voltage curve and the phase diagram. As a result of the density functional theory calculation and experimental verification with structural analysis, we found that the most stable structure of Na1.5FePO4F has the P21/b11 space group, which has not been reported to date. The estimated voltage curve has two clear plateaus caused by the two-phase structure composed of P21/b11 Na1.5FePO4F and Pbcn Na2FePO4F or Na1FePO4F and separated along the c-axis direction. The phase diagram shows the stability of the phase-separated structure. Considering that Na2FePO4F has diffusion paths in the a- and c-axis directions, Na2FePO4F has both innerphase and interphase diffusion paths. We suggest that the stable two-phase structure and the diffusion paths to both the innerphase and interphases are a key for the very clear plateau. We challenge to simulate a nonequilibrium state at high rate discharge with high temperature by introducing a coordinate-dependent chemical potential. The simulation shows agreement with the experimental discharge curve on the disappearance of the two plateaus. © 2018 Wiley Periodicals, Inc. 相似文献