全文获取类型
收费全文 | 367篇 |
免费 | 9篇 |
国内免费 | 2篇 |
专业分类
化学 | 228篇 |
晶体学 | 6篇 |
力学 | 1篇 |
数学 | 20篇 |
物理学 | 123篇 |
出版年
2022年 | 4篇 |
2021年 | 1篇 |
2020年 | 4篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2017年 | 6篇 |
2016年 | 11篇 |
2015年 | 9篇 |
2014年 | 11篇 |
2013年 | 27篇 |
2012年 | 13篇 |
2011年 | 22篇 |
2010年 | 18篇 |
2009年 | 18篇 |
2008年 | 23篇 |
2007年 | 24篇 |
2006年 | 29篇 |
2005年 | 28篇 |
2004年 | 15篇 |
2003年 | 21篇 |
2002年 | 9篇 |
2001年 | 8篇 |
2000年 | 7篇 |
1999年 | 1篇 |
1998年 | 7篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有378条查询结果,搜索用时 15 毫秒
61.
62.
We report herein a practical synthesis of 4'-thiothymidine (15) and appropriately protected 2'-deoxy-4'-thiocytidine (16), -thioadenosine (27), and -thioguanosine (29) derivatives, substrates for the synthesis of 4'-thioDNA, from the corresponding 4'-thioribonucleosides. 2'-deoxy-4'-thiopyrimidine nucleosides were synthesized using a radical reaction of the corresponding 2'-alpha-bromo derivatives, which were prepared via 2,2'-O-anhydro derivatives. 2'-deoxy-4'-thiopurine nucleosides were synthesized using the same radical reaction of the corresponding 2'-beta-bromo derivatives. 相似文献
63.
Chiral macrocyclic amine 2 was found to be useful as an NMR chiral shift reagent for the determination of the enantiomeric purity and absolute configurations of several kinds of carboxylic acid and amino acid derivatives. 相似文献
64.
Optical Review - Recently, smartphone cameras have been increasingly used to take pictures of documents. When a shadow appears in the captured document image, it causes problems such as reduced... 相似文献
65.
Masahiro Yodoshi Natsumi Ikeda Naoko Yamaguchi Mana Nagata Noriaki Nishida Kazuaki Kakehi Takao Hayakawa Shigeo Suzuki 《Electrophoresis》2013,34(22-23):3198-3205
We have identified novel CE conditions for the separation of 7‐amino‐4‐methylcoumarin‐labeled monosaccharides and oligosaccharides from glycoproteins. Using a neutrally coated capillary and alkaline borate buffer containing hydroxypropylcellulose and ACN, saccharide derivatives form anionic borate complexes, which move from the cathode to the anode in an electric field and are detected near the anodic end. Excess labeling reagents and other fluorescent products remain at the cathodic end. Fluorimetric detection using an LED as a light source enables determination of monosaccharide derivatives with good linearity between at least 0.4 and 400 μM, may correspond to 140 amol to 140 fmol. The lower LOD (S/N = 5) is only 80 nM in the sample solution (ca. 28 amol). The results were comparable to reported values using fluorometric detection LC. The method was also applied to the analysis of oligosaccharides that were enzymatically released from glycoproteins. Fine resolution enables profiling of glycans in glycoproteins. The applicability of the method was examined by applying it to other derivatives labeled with nonacidic tags such as ethyl p‐aminobenzoate‐ and 2‐aminoacridone‐labeled saccharides. 相似文献
66.
Noriaki Takahashi 《Hyperfine Interactions》1985,21(1-4):173-195
A series of experiments is described in which beta-ray asymmetry has been used to determine polarization of heavy-ion reaction products12B and the present status of the studies of polarization phenomena in heavy-ion reactions is reviewed. A large amount of angular momentum sustained by the two colliding nuclei gives rise to polarization phenomena of reaction products. Coupling between the degrees of freedom accompanying the intrinsic and the relative motions is investigated from the systematic behaviour of polarization of reaction products disclosed by the experiments. 相似文献
67.
Kataoka M Kouda Y Sato K Minakawa N Matsuda A 《Chemical communications (Cambridge, England)》2011,47(30):8700-8702
The synthesis of the 3'-deoxyapionucleoside 3'-triphosphates (apioNTPs) having the four natural nucleobases and their enzymatic incorporation into a DNA-DNA primer-template have been tried. Therminator DNA polymerase was shown to incorporate these apioNTPs effectively giving 43mer DNA-apioNA chimera. 相似文献
68.
69.
70.
Yoshiki Nakata Noriaki Miyanaga 《Applied Physics A: Materials Science & Processing》2010,98(2):401-405
Combined structures composed of a micron-sized periodic structure and a nano-sized quasi-periodic ripple structure were generated
by a single process of multiple shots of an interfering femtosecond laser. The former structure was generated by an interference
pattern and controlled by a number of beams. The latter structure was generated by a multiple shot method. As a result, multiple
periodic structures were generated. The periodicity of the structures was analyzed by two-dimensional (2D) fast Fourier transform
(FFT). The most probable period of ripple structure was downsized to 177 nm by restricting irradiated region by a TM wave
interference pattern. The smallest period was 105 nm. The dispersion angle of a ripple decreased to about 50%. The period
and direction of the ripples were for a first time controlled by using interference. 相似文献