Controlling the motion of interacting particles: homogeneous systems and binary mixtures

We elaborate on recent results on the transport of interacting particles for both single-species and binary mixtures subject to an external driving on a ratchetlike asymmetric substrate. Moreover, we also briefly review motion control without any spatial asymmetric potential (i.e., no ratchet). Our results are obtained using an analytical approach based on a nonlinear Fokker-Planck equation as well as via numerical simulations. By increasing the particle density, the net dc ratchet current in our alternating (ac)-driven systems can either increase or decrease depending on the temperature, the drive amplitude, and the nature of the inter-particle interactions. This provides an effective control of particle motion by just changing the particle density. At low temperatures, attracting particles can condense at some potential minima, thus breaking the discrete translational symmetry of the substrate. Depending on the drive amplitude, an agglomeration or condensation results either in a drop to zero or in a saturation of the net particle velocity at densities above the condensation density-the latter case producing a very efficient rectification mechanism. For binary mixtures we find three ways of controlling the particle motion of one (passive) B species by means of another (active) A species: (i) Dragging the target particles B by driving the auxiliary particles A, (ii) rectifying the motion of the B particles on the asymmetric potential created by the A-B interactions, and (iii) dynamically modifying (pulsating) this potential by controlling the motion of the A particles. This allows to easily control the magnitude and direction of the velocity of the target particles by changing either the frequency, phase and/or amplitude of the applied ac drive(s).     

Modeling an adiabatic quantum computer via an exact map to a gas of particles

We map adiabatic quantum evolution on the classical Hamiltonian dynamics of a 1D gas (Pechukas gas) and simulate the latter numerically. This approach turns out to be both insightful and numerically efficient, as seen from our example of a CNOT gate simulation. For a general class of Hamiltonians we show that the escape probability from the initial state scales no faster than |lambda|gamma, where |lambda| is the adiabaticity parameter. The scaling exponent for the escape probability is gamma=1/2 for all levels, except the edge (bottom and top) ones, where gamma approximately < 1/3. In principle, our method can solve arbitrarily large adiabatic quantum Hamiltonians.     

Quantum terahertz electrodynamics and macroscopic quantum tunneling in layered superconductors

We derive a quantum field theory of Josephson plasma waves (JPWs) in layered superconductors, which describes two types of interacting JPW bosonic quanta (one heavy and one lighter). We propose a mechanism of enhancement of macroscopic quantum tunneling (MQT) in stacks of intrinsic Josephson junctions. Because of the long-range interaction between junctions in layered superconductors, the calculated MQT escape rate Gamma has a nonlinear dependence on the number of junctions in the stack. We show that the crossover temperature between quantum and thermal escape increases when increasing the number of junctions. This allows us to quantitatively describe striking recent experiments in Bi2Sr2CaCu2O8+delta stacks.     

Analgesic and anti-inflammatory activities of salicylaldehyde 2-chlorobenzoyl hydrazone (H(2)LASSBio-466), salicylaldehyde 4-chlorobenzoyl hydrazone (H(2)LASSBio-1064) and their zinc(II) complexes

Salicylaldehyde 2-chlorobenzoyl hydrazone (H(2)LASSBio-466), salicylaldehyde 4-chlorobenzoyl hydrazone (H(2)LASSBio-1064) and their complexes [Zn(LASSBio-466)H(2)O](2) (1) and [Zn(HLASSBio-1064)Cl](2) (2) were evaluated in animal models of peripheral and central nociception, and acute inflammation. All studied compounds significantly inhibited acetic acid-induced writhing response. Upon coordination the anti-nociceptive activity was favored in the complex 1. H(2)LASSBio-466 inhibited only the first phase of the formalin test, while 1 was active in the second phase, like indomethacin, indicating its ability to inhibit nociception associated with the inflammatory response. Hence coordination to zinc(II) altered the pharmacological profile of H(2)LASSBio-466. H(2)LASSBio-1064 inhibited both phases but this effect was not improved by coordination. The studied compounds did not increase the latency of response in the hot plate model, indicating their lack of central anti-nociceptive activity. All compounds showed levels of inhibition of zymosan-induced peritonitis comparable or superior to indomethacin, indicating an expressive anti-inflammatory profile.     

Ruthenium(II) complexes containing 2-pyridineformamide- and 2-benzoylpyridine-derived thiosemicarbazones and PPh3: NMR and electrochemical studies of cis-trans-isomerization

[RuCl(L)(PPh(3))(2)] complexes with 2-benzoylpyridine- and 2-pyridineformamide-derived thiosemicarbazones (HL) were obtained and fully characterized. The complexes form cis-trans isomers. The cis isomer is disfavored by the sterical effect of two bulky groups close to each other whereas the trans isomer is disfavored by the electronic effect of competition of two phosphorous for pi-bonding d orbitals of the metal. Our results suggest that, although both factors may be operating simultaneously, in CH(2)Cl(2) solution the balance of these counterpoising effects favors the formation of the trans isomer.     

Quantum two-level systems in Josephson junctions as naturally formed qubits

The two-level systems (TLSs) naturally occurring in Josephson junctions constitute a major obstacle for the operation of superconducting phase qubits. Since these TLSs can possess remarkably long decoherence times, we show that such TLSs can themselves be used as qubits, allowing for a well controlled initialization, universal sets of quantum gates, and readout. Thus, a single current-biased Josephson junction can be considered as a multiqubit register. It can be coupled to other junctions to allow the application of quantum gates to an arbitrary pair of qubits in the system. Our results indicate an alternative way to realize superconducting quantum information processing.     

Binary Mixtures in Linear Convection Arrays

We numerically investigated the dynamics of a mixture of finite-size active and passive disks in a linear array of two-dimensional convection rolls. The interplay of advection and steric interactions produces a number of interesting effects, like the stirring of a passive colloidal fluid by a small fraction of slow active particles, or the separation of the mixture active and passive colloidal fractions by increasing the motility of the active one, which eventually clusters in stagnation areas along the array walls. These mechanisms are quantitatively characterized by studying the dependence of the diffusion constants of the active and passive particles on the parameters of the active mixture fraction.