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121.
In order to use a hydrophilic solvent as an organic phase in liquid-liquid extraction by retaining it to a solid support, the occlusion and desorption of nine hydrophilic solvents, such as methanol, to three kinds of commercially available oil-adsorbent were examined. The combination of tetrahydrofuran and WOSEP made by fibrous polypropylene was finally selected, and was subjected to the extraction of alkaline Earth metals with 8-quinolinol. It was proved that Mg2+, Ca2+, and Sr2+ ions could be successfully extracted into the tetrahydrofuran phase in the form of 8-quinolinolato complexes, which could not be extracted into CHCl3. 相似文献
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The signal quality of a fiber-optic distributed temperature sensor based on optical time domain reflectometry (OTDR) is improved using a pre-filtering technique in the iterative deconvolution method. Investigation of the performance is proposed using iteration conditions in which recovery rate of the signal-component is equal to that of the unfiltering technique. The recovered signal in the pre-filtering technique gives a good signal-to-noise ratio (SNR), 3 times of the unfiltered signal. Consequently, improvements in the OTDR signal with SNR of from 10 to 100 are obtained under the iterations for both distance and temperature resolutions. 相似文献
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Mohammad Mizanur Rahman Kazuaki Ninomiya Chiaki Ogino Nobuaki Shimizu 《Ultrasonics sonochemistry》2010,17(4):738-743
A non-woven titanium dioxide (TiO2) fabric was applied to disinfection by ultrasound (US) irradiation, and the disinfection efficiency and lipid peroxidation of Escherichia coli (E. coli) cell membrane were evaluated to investigate the killing process. The addition of non-woven TiO2 fabric enhanced hydroxyl (OH) radical generation and disinfection efficiency. Judging from the disinfection experiments using glutathione or t-butanol as a radical scavenger, the OH radical played a major role in cell killing in sonodynamic disinfection with non-woven TiO2 fabric. Moreover, to understand the detailed killing process, damage to cell membrane was also evaluated using a diphenyl-1-pyrenylphosphine (DPPP) fluorescent probe, which detects the membrane’s lipid peroxidation. The addition of non-woven TiO2 fabric aggravated this peroxidation. This aggravation was caused by the OH radical according to an assay using a radical scavenger. From these results, it was concluded that non-woven TiO2 fabric as a sonocatalyst promoted peroxidation of the polyunsaturated phospholipid component of the lipid membrane initially and induced a major disorder in the E. coli cell membrane under US irradiation. 相似文献
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Macías-Ruvalcaba NA Okumura N Evans DH 《The journal of physical chemistry. B》2006,110(43):22043-22047
The electrochemical reduction of 3,5-di-tert-butyl-1,2-benzoquinone, 1, has been studied in acetonitrile with added 2,2,2-trifluoroethanol, 2. At low concentrations of 2 the reaction proceeds by the following pathway: reduction of the quinone (Q) to its anion radical (Q*-) followed by complexation of the anion radical with 2 (HA) and the further reduction of the hydrogen-bonded complex (Q*- (HA)) to form HQ- and A-. The latter reaction is a concerted proton and electron- transfer reaction (CPET). At higher concentrations of 2, the pathway changes. The first steps remain the same, but now Q*- (HA) is reduced to HQ- via a disproportionation reaction with Q*- along with proton transfer from HA to Q*- to form HQ* which is reduced to HQ-. The only mechanism that could be found which would account for all of the data involves proton transfer to Q*- occurring within a higher complex, Q*-(HA)3. 相似文献