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81.
Electronic polarizabilities and sizes of ions in AN B10?N type semiconductors (PbS, PbSe, PbTe and SnTe) have been deduced in the present study. The free ion polarizabilities of Sn2+ and Pb2+ ions are estimated approximately following the procedure of Pauling. The effect of crystalline potential is then estimated on free cation polarizabilities. An empirical relation between ionic radii and polarizabilities has been applied to deduce the ionic sizes and anion polarizabilities. The calculated molecular electronic polarizabilities agree well with the experimental values. The variation of dielectric constant with strain has also been estimated in each crystal and the results are explained in terms of the optical anisotropy parameter. 相似文献
82.
The energy transfer phenomenon has been studied from Tb3+ → Nd3+ and Tb3+ → Ho3+ in DMSO. A diffusion limited dipole-dipole mechanism of energy transfer is suggested for both systems. At high acceptor concentrations, Pda depends linearly on C2 consistent with the Fong and Diestler theory of energy transfer. However, at low acceptor concentrations the observations of time evolutions of Tb3+ luminescence decay following flash excitation has enabled us to examine diffusion limited energy transfer from Tb3+ to Nd3+ and Tb3+ to Ho3+ in DMSO. 相似文献
83.
A new cyclic amide heterodimer has been isolated from Clausena-lansium leaves. The structure of this amide heterodimer was determined by X-ray crystallographic studies and spectrochemical evidence. 相似文献
84.
Using a simple hydrophobic/polar protein model, we perform a Monte Carlo study of the thermodynamics and kinetics of binding to a target structure for two closely related sequences, one of which has a unique folded state while the other is unstructured. We obtain significant differences in their binding behavior. The stable sequence has rigid docking as its preferred binding mode, while the unstructured chain tends to first attach to the target and then fold. The free-energy profiles associated with these two binding modes are compared. 相似文献
85.
Two uncoupled two-level atoms cannot be jointly excited by classical light under general circumstances, due to destructive interference of excitation pathways in two-photon absorption. However, with temporally entangled light, two-atom excitation is shown possible. Photons arising from three-level cascade decay are intrinsically ordered in time of emission. This field correlation induces a joint resonance in the two-atom excitation probability via suppression of one of the time-ordered excitation pathways. The relative gain in two-photon absorption increases with the time-frequency entanglement. 相似文献
86.
We consider pulse propagation through a Fabry-Perot cavity with silver mirrors that contain macroscopic samples of resonant absorbers. We show that the pulse velocity can be tuned from subluminal to superluminal in a strongly coupled atom-cavity system. We delineate the effects of the interplay of cavity and absorbers. We demonstrate the saturation effects of pulse advancement with increasing mirror thickness and atomic damping. 相似文献
87.
In this work we have combined a Wang-Landau sampling scheme [F. Wang and D. Landau, Phys. Rev. Lett. 86, 2050 (2001)] with an expanded ensemble formalism to yield a simple and powerful method for computing potentials of mean force. The new method is implemented to investigate the mechanical deformation of proteins. Comparisons are made with analytical results for simple model systems such as harmonic springs and Rouse chains. The method is then illustrated on a model 15-residue alanine molecule in an implicit solvent. Results for mechanical unfolding of this oligopeptide are compared to those of steered molecular dynamics calculations. 相似文献
88.
Ravi P. Agarwal Said R. Grace Donal O'Regan 《Proceedings of the American Mathematical Society》2003,131(1):129-140
This paper introduces a nonoscillatory theory for differential inclusions based on fixed point theory for multivalued maps.
89.
We propose a scheme for slowing down decay into a continuum. We make use of a sequence of ultrashort 2pi pulses applied on an auxiliary transition of the system so that there is a destructive interference between the two transition amplitudes--one before the application of the pulse and the other after the application of the pulse. We give explicit results for a structured continuum. Our scheme can also inhibit unwanted transitions. 相似文献
90.
Agarwal GS 《Physical review letters》2000,84(24):5500-5503
We demonstrate how the anisotropy of the vacuum of the electromagnetic field can lead to quantum interferences among the decay channels of close lying states. Our key result is that interferences are given by the scalar formed from the antinormally ordered electric field correlation tensor for the anisotropic vacuum and the dipole matrix elements for the two transitions. We present results for emission between two conducting plates as well as for a two photon process involving fluorescence produced under coherent cw excitation. 相似文献