全文获取类型
收费全文 | 942篇 |
免费 | 19篇 |
国内免费 | 57篇 |
专业分类
化学 | 385篇 |
晶体学 | 1篇 |
力学 | 24篇 |
综合类 | 2篇 |
数学 | 151篇 |
物理学 | 455篇 |
出版年
2022年 | 11篇 |
2021年 | 11篇 |
2020年 | 9篇 |
2019年 | 7篇 |
2018年 | 10篇 |
2017年 | 13篇 |
2016年 | 28篇 |
2015年 | 12篇 |
2014年 | 22篇 |
2013年 | 23篇 |
2012年 | 22篇 |
2011年 | 41篇 |
2010年 | 40篇 |
2009年 | 35篇 |
2008年 | 13篇 |
2007年 | 13篇 |
2006年 | 51篇 |
2005年 | 53篇 |
2004年 | 118篇 |
2003年 | 106篇 |
2002年 | 67篇 |
2001年 | 72篇 |
2000年 | 14篇 |
1999年 | 13篇 |
1998年 | 23篇 |
1997年 | 13篇 |
1996年 | 9篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 22篇 |
1992年 | 19篇 |
1991年 | 8篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1988年 | 17篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1977年 | 3篇 |
1935年 | 2篇 |
1932年 | 2篇 |
1928年 | 2篇 |
1919年 | 3篇 |
1917年 | 2篇 |
1916年 | 2篇 |
1911年 | 4篇 |
1910年 | 3篇 |
1909年 | 3篇 |
1907年 | 3篇 |
排序方式: 共有1018条查询结果,搜索用时 0 毫秒
41.
LI Haitao XU Mancai SHI Zuoqing HE Binglin The State Key Laboratory of Functional Polymeric Materials for Adsorption Separation Institute of Polymer Chemistry Nankai University Tianjin China College of Chemistry Chem 《Chinese Journal of Reactive Polymers》2001,(1)
1. INTRODUCTIONMolecular imprinted polymers (MIPs) have attracted wide attention for its molecular recognition properties. More and more publications involved in the area of adsorption and separation with MIPs. As early as in 1931, Poljacov [1] found that the pore structure of silica gel was influenced by the size and shape of the molecules in the gas atmosphere when he removed water from the gel under the atmosphere of benzene, toluene and xylene. The gel dried in benzene atmosphere a… 相似文献
42.
Jie Ju Yu Jin Li Jian Rong Gao Jian Hong Jia Liang Han Wei Jian Sheng Yi Xia Jia 《中国化学快报》2011,22(4):382-384
An aqueous solution of hydrogen peroxide and hydrogen bromide illuminated by a 60 W incandescent light bulb serves as a source of bromine radicals.Various substituted toluenes(NO2,Cl,Br,H,CH3) were high selectively brominated at the benzyl position for monobromination in CH2C12 at ice water with catalyst free.This simple but effective bromination of toluene derivatives with an aqueous H2O2-HBr system is characterized with the use of inexpensive reagents and a lower impact on the environment, which make it a good alternative to the existing bromination methods. 相似文献
43.
44.
分别以(8R,10R)-(-)-[4,5]-pineno-2,2′-bipyridine或(8S,10S)-(+)-[4,5]-pineno-2,2′-bipyridine(LRR和LSS)为手性配体合成双核铜络合物[Cu2(μ-ox)(LRR)2(H2O)2(ClO4)2](1)、[Cu2(μ-ox)(LRR)2(CH3COCH3)2(ClO4)2](1a)、[Cu2(μ-ox)(LSS)2(H2O)2(ClO4)2](2)和[Cu2(μ-ox)-(LRR)(LSS)(CH3COCH3)2(ClO4)2](3)(ox2-=草酸根),并探讨了其反应机理.由元素分析、电导率、紫外可见谱(UV-vis)、圆二色(CD)谱和晶体结构分析推测:该系列络合物具有草酸根桥联的双核结构,两个铜(II)离子与草酸根几乎成共平面;1a和3的晶体结构分析表明,每个Cu(II)的配位构型为拉长畸变八面体,双核分子中轴向的两个溶剂分子和两个高氯酸根互为反式配位.对映体络合物1和2的溶液CD光谱大致呈镜像对称,在可见区的极弱CD吸收峰可能源于LRR和LSS蒎烯基上的手性中心对Cu(II)d-d生色团的手性微扰产生的邻位效应.采用最小二乘法和Bleaney-Bowers方程对络合物1的变温磁化率测试数据进行拟合,求得交换积分J=-338.41(4)cm-1,表明铜(II)离子间有较强的反铁磁自旋交换作用. 相似文献
45.
<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods. 相似文献
46.
<正>A novel polyester containing ferrocenyl was prepared by low-temperature interface polycondensation of 1,1'-ferrocenedicarboxylic acid chloride with 4-(4-hydroxyphenyl)-2,3-phthalazin-1-one(DHPZ),which is a twisted non-coplanar heterocyclic bisphenol-like monomer.The newly generated polymer was evaluated based on characterization of its solubility,viscosity measurements,elemental analysis,FTIR spectroscopy,differential scanning calorimetric and thermogravimetric studies. 相似文献
47.
48.
吡啶-BH~3相互作用复合物的理论研究 总被引:2,自引:2,他引:2
对吡啶-BH~3复合物分别用MP2/6-31+G^*和B3LYP/6-31+G^*进行理论计算以预测该复合物的构型及解离能,得到四种构型,在MP2优化构型基础上作CCSD/6-31+G^*单点能量计算以验证MP2与B3LYP结果的可靠性,然后用B3LYP作振动频率分析,计算了各构型的垂直电离势,最后用更大基组作单点能量计算和自然键轨道(NBO)分析。结果表明,N-B直接相连的构型最稳定,其解离能为141.50kJ/mol,MP2和B3LYP对N-H接近的构型结果相关较大,另外两种构型稳定性介于二者之间,解离能分别为15.18kJ/mol,14.06kJ/mol(MP2/6-31+G^*)。 相似文献
49.
50.
Robyn M. Lucas Patricia Valery Ingrid van der Mei Terence Dwyer Michael P. Pender Bruce Taylor Anne‐Louise Ponsonby The Ausimmune Investigator Group 《Photochemistry and photobiology》2013,89(3):737-744
Spatio‐temporal patterns in sun exposure underlie variations in skin cancer incidence and vitamin D deficiency, indicate effectiveness of sun protection programs and provide insights into future health risks. From 558 adults across four regions of Australia (Brisbane (27°S), Newcastle (33°S), Geelong and the Western Districts of Victoria (37°S) and Tasmania (43°S)), we collected: self‐report data on time‐in‐the‐sun from age 6 years; natural skin color and ethnicity; silicone skin casts (for cumulative skin damage); and serum for vitamin D status. Ambient ultraviolet radiation (UVR) at the location of residence, with time‐in‐the‐sun, was used to calculate a “UVR dose” for each year of life. Individuals maintained their ranking compared to their peers for time‐in‐the‐sun in summer compared to winter and across ages (Spearman rho 0.24–0.84, all P < 0.001). Time‐in‐the‐sun decreased with age in all birth cohorts, and over calendar time. Summer time‐in‐the‐sun increased with increasing latitude (P < 0.001). Seasonal variation in vitamin D status had greater amplitude and vitamin D deficiency increased with increasing latitude. Temporal patterns are consistent with effectiveness of sun protection programs. Higher relative time‐in‐the‐sun persists from childhood through adulthood. Lower summer time‐in‐the‐sun in the warmest location may have implications for predictions of UVR‐related health risks of climate change. 相似文献