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51.
This note is a continuation of our recent paper [V. Jakšić Y. Ogata, and C.-A. Pillet, The Green-Kubo formula and Onsager reciprocity relations in quantum statistical mechanics. Commun. Math. Phys. in press.] where we have proven the Green-Kubo formula and the Onsager reciprocity relations for heat fluxes in thermally driven quantum open systems. In this note we extend the derivation of the Green-Kubo formula to heat and charge fluxes and discuss some other generalizations of the model and results of [V. Jakšić Y. Ogata and C.-A. Pillet, The Green-Kubo formula and Onsager reciprocity relations in quantum statistical mechanics. Commun. Math. Phys. in press.]. 相似文献
52.
Nikola Popović Dirk Praetorius Anja Schlömerkemper 《Continuum Mechanics and Thermodynamics》2007,19(1-2):67-80
The mathematical and physical analysis of magnetoelastic phenomena is a topic of ongoing research. Different formulae have
been proposed to describe the magnetic forces in macroscopic systems. We discuss several of these formulae in the context
of rigid magnetized bodies. In case the bodies are in contact, we consider formulae both in the framework of macroscopic electrodynamics
and via a multiscale approach, i.e., in a discrete setting of magnetic dipole moments. We give mathematically rigorous proofs
for domains of polygonal shape (as well as for more general geometries) in two and three space dimensions. In an accompanying
second article, we investigate the formulae in a number of numerical experiments, where we focus on the dependence of the
magnetic force on the distance between the bodies and on the case when the two bodies are in contact. The aim of the analysis
as well as of the numerical simulation is to contribute to the ongoing debate about which formula describes the magnetic force
between macroscopic bodies best and to stimulate corresponding real-life experiments.
相似文献
53.
54.
Dependence of surface potential (electrostatic potential at the inner Helmholtz plane, Ψ(0)) at the silver bromide aqueous electrolyte interface was measured as a function of the activities of Br(-) and Ag(+) by using a single crystal silver bromide electrode (SCr-AgBr). Absolute values of surface potentials were obtained from electrode potentials of SCr-AgBr and isoelectric points. Measurements were performed at different temperatures in the range from 10 to 50°C. Corresponding equilibrium constants of interfacial reactions were obtained using the surface complexation model and interpreted via the van't Hoff equation. As a result of the interpretation for the binding of bromide ions leading to a negative surface charge, the thermodynamic parameters obtained were Δ(n)H(°)=-33kJmol(-1) and Δ(n)S(°)=-31Jmol(-1)K(-1); and for the binding of silver ions leading to a positive surface charge, Δ(p)H(°)=-72kJmol(-1) and Δ(p)S(°)=-196Jmol(-1)K(-1). Association of counterions (CI) with oppositely charged surface sites partially compensates the surface charge. Assuming approximately the same affinities for anions (NO(3)(-)) and cations (K(+)) thermodynamic parameters for their binding were obtained as Δ(CI)H(°)≈7kJmol(-1) and Δ(CI)S(°)≈105Jmol(-1)K(-1). 相似文献
55.
A new family of optically pure tetrathiafulvalenium and tetraselenafulvalenium salts, D(3)[M(III)(S,S-EDDS)](2)·nH(2)O (where D = TTF, TSF; M = Co, Fe, Cr; EDDS = ethylenediaminedisuccinato), were synthesized electrochemically. These phases are semiconductors with conductivities between 6.9 × 10(-6) and 1.3 × 10(-5) S·cm(-1) (E(a)ca. 0.3 eV) for TTF and 2.8 × 10(-4) to 2.8 × 10(-5) S·cm(-1) (E(a)ca. 0.1 eV) for TSF compounds. While some crystals suffer from twinning, other well resolved structures consist of TTF/TSF stacks which, under the influence of the chiral anion, exhibit a periodic undulation described by an elliptical helix. The crystallographic data, along with computational work, indicate charge localization in the semiconducting motifs. 相似文献
56.
Gaidzik N Kaiser A Kowalczyk D Westerlind U Gerlitzki B Sinn HP Schmitt E Kunz H 《Angewandte Chemie (International ed. in English)》2011,50(42):9977-9981
A shot in the arm for cancer treatment: Two MUC1 tetanus toxoid vaccines were synthesized and induced a strong immune response in mice. The antibodies elicited by the vaccines show a high selectivity for the tumor cells in mammary carcinoma tissues and also distinguish between tumor tissues at different stages. 相似文献
57.
We consider a model describing finitely many free Fermi gas reservoirs coupled by local interactions and prove the Green–Kubo
formulas and the Onsager reciprocity relations for heat and charge fluxes generated by temperature and chemical potential
differentials.
Submitted: September 2, 2006. Accepted: November 21, 2006. 相似文献
58.
We investigate the dynamics of anN-level system linearly coupled to a field of mass-less bosons at positive temperature. Using complex deformation techniques, we develop time-dependent perturbation theory and study spectral properties of the total Hamiltonian. We also calculate the lifetime of resonances to second order in the coupling. 相似文献
59.
We study linear response theory in the general framework of algebraic quantum statistical mechanics and prove the Green-Kubo formula and the Onsager reciprocity relations for heat fluxes generated by temperature differentials. Our derivation is axiomatic and the key assumptions concern ergodic properties of non-equilibrium steady states. 相似文献
60.