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51.
S. Schilt V. Dolgovskiy N. Bucalovic C. Schori M. C. Stumpf G. Di Domenico S. Pekarek A. E. H. Oehler T. Südmeyer U. Keller P. Thomann 《Applied physics. B, Lasers and optics》2012,109(3):391-402
We present a detailed investigation of the noise properties of an optical frequency comb generated from a femtosecond diode-pumped solid-state laser operating in the 1.5-??m spectral region. The stabilization of the passively mode-locked Er:Yb:glass laser oscillator, referred to as ERGO, is achieved using pump power modulation for the control of the carrier envelope offset (CEO) frequency and by adjusting the laser cavity length for the control of the repetition rate. The stability and the noise of the ERGO comb are characterized in free-running and in phase-locked operation by measuring the noise properties of the CEO, of the repetition rate, and of a comb line at 1558?nm. The comb line is analyzed from the heterodyne beat signal with a cavity-stabilized ultra-narrow-linewidth laser using a frequency discriminator. Two different schemes to stabilize the comb to a radio-frequency (RF) reference are compared. The comb properties (phase noise, frequency stability) are limited in both cases by the RF oscillator used to stabilize the repetition rate, while the contribution of the CEO is negligible at all Fourier frequencies, as a consequence of the low-noise characteristics of the CEO-beat. A?linewidth of ??150?kHz and a fractional frequency instability of 4.2×10?13 at 1?s are obtained for an optical comb line at 1558?nm. Improved performance is obtained by stabilizing the comb to an optical reference, which is a cavity-stabilized ultra-narrow linewidth laser at 1558?nm. The fractional frequency stability of 8×10?14 at 1?s, measured in preliminary experiments, is limited by the reference oscillator used in the frequency comparison. 相似文献
52.
A new reader for radiation dose measurements using RADFET (pMOSFET) dosemeters has been developed. The threshold voltage (VT) of the pMOSFETs is measured using a “one-point” method that determines VT as the gate voltage for a given drain current. Using VT, the absorbed dose, which is directly proportional to the threshold voltage shift, is calculated. The reader is based on a low cost 8-bit PIC 18F4520 microcontroller (MCU), and works independently of a personal computer, uses a touch screen and stores the data in microcontroller memory. Good agreement in threshold voltage values, obtained using a high-quality source-measure unit and the reader, was obtained. In addition, the reader can be used for threshold voltage measurement with other types of MOSFETs, especially in long duration experiments, as well as for the real-time measurements in radiotherapy, either as an autonomous system or integrated in a larger monitoring configuration. 相似文献
53.
54.
Nikola Toljic Kaz Adamiak G.S. Peter Castle Hong-Hsiang Kuo Hua-Tzu Fan 《Journal of Electrostatics》2012,70(6):499-504
In this paper, a full three dimensional FLUENT numerical model of the electrostatic coating process with the embedded moving mesh capability and piecewise linear type target motion is presented. The model includes target geometries that do not exhibit symmetry. All the dominant mechanical and electrical phenomena are taken into account. Mechanical phenomena include shaping air effects, downdraft effects and the motion of the polydispersed particles. Electrical phenomena include the particle space charge distribution, corona discharge and the electrohydrodynamic flow effects. It was demonstrated that the numerical model can accurately mimic the type of the motion used in real world applications. 相似文献
55.
<正>Coarse-graining of some sort is a fundamental and unavoidable step in any attempt to derive the classical mechanical behavior from the quantum formalism.We utilize the two-mode Bose-Hubbard model to illustrate how different coarse-grained systems can be naturally associated with a fixed quantum system if it is compatible with different dynamical algebras.Alternative coarse-grained systems generate different evolutions of the same physical quantities,and the difference becomes negligible only in the appropriate macro-limit. 相似文献
56.
Lian C. T. Shoute Nikola Pekas Yiliang Wu Richard L. McCreery 《Applied Physics A: Materials Science & Processing》2011,102(4):841-850
The relationship between bias-induced redox reactions and resistance switching is considered for memory devices containing TiO2 or a conducting polymer in “molecular heterojunctions” consisting of thin (2–25 nm) films of covalently bonded molecules, polymers, and oxides. Raman spectroscopy was used to monitor changes in the oxidation state of polythiophene in Au/P3HT/SiO2/Au devices, and it was possible to directly determine the formation and stability of the conducting polaron state of P3HT by applied bias pulses [P3HT = poly(3-hexyl thiophene)]. Polaron formation was strongly dependent on junction composition, particularly on the interfaces between the polymer, oxide, and electrodes. In all cases, trace water was required for polaron formation, leading to the proposal that water reduction acts as a redox counter-reaction to polymer oxidation. Polaron stability was longest for the case of a direct contact between Au and SiO2, implying that catalytic water reduction at the Au surface generated hydroxide ions which stabilized the cationic polaron. The spectroscopic information about the dependence of polaron stability on device composition will be useful for designing and monitoring resistive switching memory based on conducting polymers, with or without TiO2 present. 相似文献
57.
Jorge G. Ibanez Alejandro Alatorre-Ordaz Nikola Batina 《Polymer Degradation and Stability》2008,93(4):827-837
Atomic force microscopy (AFM) is employed to monitor the surface morphology of polypyrrole (PPy) films grown on vitreous carbon substrates during the catalytic reduction of Cr(VI) to Cr(III). The morphology of freshly-prepared films depends on substrate characteristics. Upon reaction, uniform nodules of aggregated PPy clusters appear. No significant differences in surface morphology are found between its oxidized and reduced forms. Loss of catalytic activity after 8-9 oxidation/reduction cycles of exposure to the chromate solution (oxidation) and electrochemical recharging of the film at negative potentials (reduction) correlates well with the observed polymer film dissolution/detachment from the carbon substrate. Formation of well-defined circular features (PPy rings) at different stages leads to a model for the film degradation process that includes formation of Cl2 gas inside the polymer matrix. In the final stages, the bulk of the film typically fractures and detaches from the electrode. A catalytically inactive, ultrathin PPy layer remains on the substrate even after prolonged exposure to the target solution. A review of techniques for the study of PPy aging/degradation is given. 相似文献
58.
59.
Pasa-Tolić L Lipton MS Masselon CD Anderson GA Shen Y Tolić N Smith RD 《Journal of mass spectrometry : JMS》2002,37(12):1185-1198
In the era of systems biology, computational and high-throughput experimental biological approaches are increasingly being combined to provide global snapshots of entire genomes and proteomes under tissue- and disease-specific conditions. The aim is to identify proteins changing in concentration and/or post-translational state and/or location, and develop a better molecular level understanding of the operation of biological systems. Here we describe an approach for comparative proteomics that builds upon the combination of high-performance nano-scale separations with the high-mass measurement accuracy, mass-resolving power and sensitivity of Fourier transform ion cyclotron resonance mass spectrometry to provide broad dynamic range, comprehensive and quantitative proteome measurements. 相似文献
60.
Dr. Antoine Demont Dr. Carmelo Prestipino Dr. Olivier Hernandez Dr. Erik Elkaïm Serge Paofai Prof. Nikolaï Naumov Dr. Bruno Fontaine Prof. Régis Gautier Dr. Stéphane Cordier 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(38):12711-12719
The crystal structure of Cs2BaTa6Br15O3 has been elucidated by using synchrotron X‐ray powder diffraction and absorption experiments. It is built from edge‐bridged octahedral [(Ta6${{\rm Br}{{{\rm i}\hfill \atop 9\hfill}}}$ ${{\rm O}{{{\rm i}\hfill \atop 3\hfill}}}$ )${{\rm Br}{{{\rm a}\hfill \atop 6\hfill}}}$ ]4? cluster units with a singular poor metallic electron (ME) count equal to thirteen. This leads to a paramagnetic behaviour related to one unpaired electron. The arrangement of the Ta6 clusters is similar to that of Cs2LaTa6Br15O3 exhibiting 14‐MEs per [(Ta6${{\rm Br}{{{\rm i}\hfill \atop 9\hfill}}}$ ${{\rm O}{{{\rm i}\hfill \atop 3\hfill}}}$ )${{\rm Br}{{{\rm a}\hfill \atop 6\hfill}}}$ ]5? motif. The poorer electron‐count cluster presents longer metal–metal distances as foreseen according to the electronic structure of edge‐bridged hexanuclear cluster. Density functional theory (DFT) calculations on molecular models were used to rationalise the structural properties of 13‐ and 14‐ME clusters. Periodic DFT calculations demonstrate that the electronic structure of these solid‐state compounds is related to those of the discrete octahedral units. Oxygen–barium interactions seem to prevent the geometry of the octahedral cluster to strongly distort, allowing stabilisation of this unprecedented electron‐poor Ta6 cluster in the solid state. 相似文献