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91.
Jonathan S. H. Kornbluth Nigel Meade Gerald R. Salkin 《The Journal of the Operational Research Society》1993,44(9):945-953
Index funds can be used by investment managers as a method of ensuring that their portfolio performs as well as the general market. Methods have been proposed for creating index funds for the stock market, and in this paper a method for creating an index fund for a sector of the bond market is suggested. The underlying indexing mechanism uses the duration moments of the portfolio to capture the various aspects of the sector and its response to changes in the yield curve. The initial results suggest that a relatively small basic set of bonds can be used to model the movements of a particular market segment. 相似文献
92.
Franz‐Josef K. Rehmann Laurence P. Cuffe Oscar Mendoza Dilip K. Rai Nigel Sweeney Katja Strohfeldt William M. Gallagher Matthias Tacke 《应用有机金属化学》2005,19(3):293-300
Starting from 2‐furylfulvene (1a) , 2‐thiophenylfulvene (1b) , and 1‐methyl‐2‐pyrrolylfulvene (1c), [1,2‐di(cyclopentadienyl)‐1,2‐di‐(2‐furyl)ethanediyl] titanium dichloride (2a) , [1,2‐di(cyclopentadienyl)‐1,2‐di‐(2‐thiophenyl)ethanediyl] titanium dichloride (2b) , and [1,2‐di(cyclopentadienyl)‐1,2‐bis‐(1‐methyl‐2‐pyrrolyl)ethanediyl] titanium dichloride (2c) were synthesized. When titanocenes (2a–c) were tested against pig kidney carcinoma cells (LLC‐PK), inhibitory concentrations (50%) of 4.5 × 10?4 M , 2.9 × 10?4 M and 2.0 × 10?4 M respectively were observed. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
93.
Nigel Martin 《Discrete Mathematics》2006,306(17):2084-2090
We construct a new infinite family of factorizations of complete bipartite graphs by factors all of whose components are copies of a (fixed) complete bipartite graph Kp,q. There are simple necessary conditions for such factorizations to exist. The family constructed here demonstrates sufficiency in many new cases. In particular, the conditions are always sufficient when q=p+1. 相似文献
94.
95.
Solid state 1H, 29Si and 31P MAS NMR have been used to investigate the microstructure of phosphosilicate gels prepared by a modified sol-gel method involving hydrolysis of silicon precursors in a solely aqueous environment at 50 °C. Gels with molar compositions 5, 10, 20 and 30 mol% P2O5 in P2O5-SiO2 were studied. After drying to 400 °C the gels have very similar structures formed by a siloxane framework containing silanol groups and trapped molecules of orthophosphoric acid together with a very small amount, of pyrophosphoric acid. Unlike the gel samples previously synthesized by the hydrolysis of the silicon precursor in alcoholic solution at room temperature, the co-polymerization of phosphorus and silicon is much reduced. Although co-polymerization increases with phosphorus content, it still represents less than 50% of the phosphorus in the 30 mol% P2O5 gel. Furthermore there is no evidence for six-coordinated silicon in the glassy matrix. 相似文献
96.
A new asymmetric approach to the erythrinan alkaloid system is described, which involves chiral base desymmetrisation of a ring fused imide and a 6-exo-trig radical cyclisation as the key steps. 相似文献
97.
Nigel Boston 《Inventiones Mathematicae》1991,103(1):181-196
98.
Nigel Ribeiro Denis Heissler Anne Marie Albrecht-Gary Mari Gotoh Yoichi Nakatani Guy Ourisson 《Tetrahedron》2007,63(16):3395-3407
Cholesterol plays the role of membrane reinforcer in eukaryotes, whereas hopanoids play the same role in bacteria. Which components could have reinforced ‘primitive’ membranes? We describe here an efficient biomimetic synthesis of bi- and tri-cyclopolyprenols and demonstrate that these compounds reinforce the membranes of polyprenyl phosphate, which we speculated as ‘primitive’ membranes. 相似文献
99.
A potentially biomimetic synthesis of the guanidine-containing marine natural product crambescidin 359 via a double Michael addition of guanidine to a suitably functionalised bis-enone is reported. 相似文献
100.
Nigel J. Newton 《Journal of statistical physics》2008,133(4):711-737
This paper connects non-equilibrium statistical mechanics and optimal nonlinear filtering. The latter concerns the observation-conditional
behaviour of Markov signal processes, and thus provides a tool for investigating statistical mechanics with partial observations. These allow entropy
reduction, illustrating Landauer’s Principle in a quantitative way.
The joint process comprising a signal and its nonlinear filter is irreversible in its invariant distribution, which therefore
corresponds to a non-equilibrium stationary state of the associated joint system. Macroscopic entropy and energy flows are identified for this state. Since these are driven by observations internal to the system, they do not cause entropy increase, and so the joint system makes statistical mechanical sense in reverse
time.
Time reversal yields a dual system in which the signal and filter exchange roles. Despite the structural similarity of the original and dual systems,
there is a substantial asymmetry in their complexities. This reveals the direction of time, despite the systems being in stationary
states that do not produce entropy.
This work was partially supported by Leverhulme Trust Research Fellowship 2003/0426, by MURI Grant F49620-02-1-0325 (Complex
Adaptive Networks for Co-operative Control), by ARO-MURI Grant DAAD19-00-1-0466 (Data Fusion in Large Arrays of Microsensors
(sensor web)) and by NSF-ITR Grant CCR-0325774 Collaborative Research: New Approaches to Experimental Design and Statistical
Analysis of Genomic and Structural Biological Data from Multiple Sources. 相似文献