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51.
Contrasts between beta relaxation in equilibrium viscous liquids and glasses are rationalized in terms of a double-well potential model with structure-dependent asymmetry, assuming structure is described by a single order parameter. The model is tested for tripropylene glycol where it accounts for the hysteresis of the dielectric beta loss peak frequency and magnitude during cooling and reheating through the glass transition. 相似文献
52.
[reaction: see text] Osmium tetroxide has been microencapsulated in a polyurea matrix using an in situ interfacial polymerization approach. These microcapsules have been effectively used as recoverable and reusable catalysts in the dihydroxylation of olefins 相似文献
53.
Atom‐Economic,Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes 下载免费PDF全文
Kun Xu Niels Thieme Prof. Dr. Bernhard Breit 《Angewandte Chemie (International ed. in English)》2014,53(8):2162-2165
New Rh‐ and Pd‐catalyzed regiodivergent and stereoselective intermolecular coupling reactions of imidazole derivatives with mono‐substituted allenes are herein reported. Using a RhI/Josiphos system, perfect regioselectivities and high enantiomeric excess were obtained, while a PdII/dppf system gave linear products with high regioselectivities and high E/Z selectivities. This method permits the atom economic synthesis of valuable branched and linear allylic imidazole derivatives. 相似文献
54.
We demonstrate theoretically that laser-induced coherent quantum interference control of asymptotic states of dissociating molecules is possible--even in the (one-photon) weak-field limit starting from a single vibrational eigenstate--when resonances are in play. This is illustrated for the NaI molecule, where it is shown that the probability of observing atomic fragments as well as the distribution of their relative momenta can be changed by a phase modulated pulse with a fixed bandwidth. This type of control is restricted to finite times during the indirect fragmentation. 相似文献
55.
Niels Vigand Pedersen 《Aequationes Mathematicae》1994,48(2-3):228-253
Summary For a simply connected solvable Lie group we specify the structure of the product, the inverse and the exponential map expressed in suitable coordinates (canonical coordinates of the second kind), and point out that in these coordinates the product and inverse are expressed entirely in terms of polynomials, exponential functions and trigonometric functions. We devise algorithms for computing the product, the inverse and the exponential map. 相似文献
56.
Niels van der Laan Ward Romeijnders Maarten H. van der Vlerk 《Computational Management Science》2018,15(3-4):325-349
We derive bounds on the expectation of a class of periodic functions using the total variations of higher-order derivatives of the underlying probability density function. These bounds are a strict improvement over those of Romeijnders et al. (Math Program 157:3–46, 2016b), and we use them to derive error bounds for convex approximations of simple integer recourse models. In fact, we obtain a hierarchy of error bounds that become tighter if the total variations of additional higher-order derivatives are taken into account. Moreover, each error bound decreases if these total variations become smaller. The improved bounds may be used to derive tighter error bounds for convex approximations of more general recourse models involving integer decision variables. 相似文献
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Evenson William E. Lu Jun Winz Michele W. Gardner John A. Zacate Matthew O. Lee Teresa Mommer Niels 《Hyperfine Interactions》1999,120(1-8):427-431
In order to explain PAC data for tetragonal zirconia at temperatures between 900 and 1300oC, we have developed a four-state
stochastic model. The model simulates vacancies which trap and detrap at a PAC probe nucleus. While trapped, the vacancies
hop around the probe in equivalent sites. The four states in this Winkler–Gerdau stochastic theory are three trapped states
with equivalent electric field gradients (EFGs) of different orientations and a detrapped state with a weaker EFG whose axis
of symmetry is oriented along the diagonal between the three trapped EFGs. There are three hopping rates in this model: w,
the rate a trapped vacancy hops around the probe, wD, the detrapping rate, and wt, the trapping rate. We report results of calculations for values of these hopping rates implied by our tetragonal zirconia
data, and we report heuristic fitting functions which summarize the computer results and can be used to fit data efficiently
for a wide range of parameters.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献