全文获取类型
收费全文 | 4619篇 |
免费 | 162篇 |
国内免费 | 29篇 |
专业分类
化学 | 2573篇 |
晶体学 | 51篇 |
力学 | 181篇 |
数学 | 1131篇 |
物理学 | 874篇 |
出版年
2023年 | 42篇 |
2022年 | 125篇 |
2021年 | 137篇 |
2020年 | 127篇 |
2019年 | 157篇 |
2018年 | 155篇 |
2017年 | 144篇 |
2016年 | 194篇 |
2015年 | 150篇 |
2014年 | 205篇 |
2013年 | 337篇 |
2012年 | 309篇 |
2011年 | 324篇 |
2010年 | 177篇 |
2009年 | 196篇 |
2008年 | 236篇 |
2007年 | 205篇 |
2006年 | 156篇 |
2005年 | 126篇 |
2004年 | 129篇 |
2003年 | 95篇 |
2002年 | 89篇 |
2001年 | 77篇 |
2000年 | 58篇 |
1999年 | 39篇 |
1998年 | 30篇 |
1997年 | 38篇 |
1996年 | 52篇 |
1995年 | 43篇 |
1994年 | 34篇 |
1993年 | 43篇 |
1992年 | 36篇 |
1991年 | 37篇 |
1990年 | 31篇 |
1989年 | 23篇 |
1988年 | 28篇 |
1987年 | 37篇 |
1986年 | 39篇 |
1985年 | 35篇 |
1984年 | 27篇 |
1983年 | 25篇 |
1982年 | 32篇 |
1981年 | 29篇 |
1980年 | 22篇 |
1979年 | 37篇 |
1978年 | 28篇 |
1977年 | 21篇 |
1976年 | 23篇 |
1975年 | 20篇 |
1974年 | 14篇 |
排序方式: 共有4810条查询结果,搜索用时 15 毫秒
31.
E. Blasius K.-P. Janzen W. Adrian W. Klein H. Klotz H. Luxenburger E. Mernke V.B. Nguyen T. Nguyen-Tien R. Rausch J. Stockemer A. Toussaint 《Talanta》1980,27(2):127-141
Exchangers with cyclic polyethers as anchor groups have a large range of applications such as separations of cations with a common anion, of anions with a common cation, and of neutral organic compounds, and the determination of water by elution chromatography. Some crown ether monomers, especially 4- and 4,4′-alkyl-substituted benzo-derivatives are suitable for extractions and their adducts with heteropoly acids are used as liquid ion-exchangers. The exchangers are also applied in thin-layer chromatography and thin-layer electrophoresis. Furthermore the exchangers are successfully used in preparative chemistry, e.g., in salt conversions in order to isolate salts which are difficult to prepare by other means, in isolation and purification of organic compounds, and for anion activation in organic reactions. 相似文献
32.
A.Lahmam Bennani H.F. Wellenstein A. Duguet B. Nguyen A.D. Barlas 《Chemical physics letters》1976,41(3):470-473
We present a new experimental determination of the Compton profiles of CH4 and C2H4 molecules using high energy electron impact. The observable q range has been extended up to 10 au (6 au for C2H4). Good agreement is found with an earlier X-ray scattering experiment and with new theoretical calculations. 相似文献
33.
C. Hinnen C. Nguyen Van Huong A. Rousseau J.P. Dalbera 《Journal of Electroanalytical Chemistry》1979,95(2):131-146
The admittance and differential reflectivity of an electrode of polycrystalline gold in contact with aqueous 0.02 M NaF, KClO4, 0.01 M Na2SO4 and KCl have been measured in the range of potential where the electrode is ideally polarized (?0.7 V to 0.8 V NHE). In NaF and KClO4 evidence was obtained for the compression of the adsorbed layer of water. The increase of the number of water molecules, with respect to the number in the least original state (at?4μC cm?2), is 3% at +8 μC cm?2 and at?17 μC cm?2. At the potential of zero charge the water dipoles are oriented preferentially with the oxygen towards the metal. In KCl the optical measurements confirm the existence of two types of Au?Cl? interaction and the covalent character of the bond at the most positive charges. 相似文献
34.
The formation of 3-chloro-2-fluoroacrylates 2 and 2-fluoroacrylates 3 by hydrogenolysis of 3,3-dichloro-2-fluoroacrylates 1 was studied by using Bu3SnH, zinc, the sodium sulphite/sodium formate mixture or iron pentacarbonyl in the presence of a hydrogen donor (Et3SiH or CH3OH). The two last couples can be used to prepare the 3-chloro derivatives 2, whereas for the preparation of the 3,3-dihydro derivatives 3, zinc is the most appropriate reducing agent. Keywords: 2-Fluoroacrylate; 3-Chloro-2-fluoroacrylate; 3,3-Dichloro-2-fluoroacrylate; Tributyltin hydride; Zinc; Sodium sulphite; Sodium formate; Iron pentacarbonyl; NMR spectroscopy; IR spectroscopy 相似文献
35.
Gaseous CF(3)(+) interchanges F(+) for O with simple carbonyl compounds. CF(3)(+) reacts with propionaldehyde in the gas phase to produce (CH(3))(2)CF(+) via two competing pathways. Starting with 1-(13)C-propionaldehyde, the major pathway (80%) produces (CH(3))(2)CF(+) with the carbon label in one of the methyl groups. The minor pathway (20%) produces (CH(3))(2)CF(+) with the carbon label in the central position. The relative proportions of these two pathways are measured by (19)F NMR analysis of the neutral CH(3)CF=CH(2) produced by deprotonation of (CH(3))(2)CF(+) at <10(-)(3) Torr in an electron bombardment flow (EBFlow) reactor. Formation of alkene in which carbon is directly bonded to fluorine means that (in the minor product, at least) an F(+) for O transposition occurs via adduct formation followed by 1,3-atom transfer and then isomerization of CH(3)CH(2)CHF(+) to the more stable (CH(3))(2)CF(+). Use of CF(4) as a chemical ionization (CI) reagent gas leads to CF(3)(+) adduct ions for a variety of ketones, in addition to isoelectronic transposition of F(+) for O. Metastable ion decompositions of the adduct ions yield the metathesis products. Decompositions of fluorocycloalkyl cations formed in this manner give evidence for the same kinds of rearrangements as take place in CH(3)CH(2)CHF(+). Density functional calculations confirm that F(+) for O metathesis takes place via addition of CF(3)(+) to the carbonyl oxygen followed by transposition via a four-member cyclic transition state. A computational survey of the effects of different substituents in a series of aldehydes and acyclic ketones reveals no systematic variation of the energy of the transition state as a function of thermochemistry, but the Hammond postulate does appear to be obeyed in terms of progress along the reaction coordinate. Bond lengths corresponding to the central barrier correlate with overall thermochemistry of the F(+) for O interchange, but in a sense opposite to what might have been expected: the transition state becomes more product-like as the metathesis becomes increasingly exothermic. This reversal of the naive interpretation of the Hammond postulate is accounted for by the relative positions of the potential energy wells that precede and follow the central barrier. 相似文献
36.
Institute of Chemistry, Moldavian SSR Academy of Sciences, Kishinev. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 759–760, September–October, 1988. 相似文献
37.
38.
39.
40.
Conclusions The simple synthesis of optically active R,Z-14-methyl-8-hexadecenal (cis-trogodermal), the principal components of the aggregation pheromone ofTrogoderma granarium, was accomplished. The synthesis was based on the use of R-1-bromo-4-methylhexane and Z-4-chloro-2-buten-1-ol as the sources of the chiral and olefin fragments.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 906–910, April, 1987. 相似文献